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US4093521A Expired / Lapsed US ⏱️ 0.0 years remaining

Chromium electroplating

Assignee: Individual
•
Filing: 1977-06-28
•
Granted: 1978-06-06
•
Expires: 1997-06-28
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Abstract

Abstract Improved trivalent chromium electroplating baths containing from about 30 to about 150 parts per million of iron or nickel content, or from about 30 to about 150 parts per million of iron plus nickel with the nickel in an amount up to about 100 parts per million.

Inventors

  • 👤 Stanley Renton
  • 👤 John Cooper Crowther

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 06:36
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/04; C25D3/06; C25D3/56

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 95 words
In a trivalent chromium electroplating bath of the type which consists essentially of an acidic aqueous solution of trivalent chromium, a carboxylate selected from formate, acetate and mixtures thereof, a bromide and ammonium the improvement which consists in maintaining in said bath an amount of metal ion selected from (i) iron or nickel in the amount of between 30 and 150 parts per million of the solution by weight, or (ii) iron plus nickel in the amount of between 30 and 150 ppm with the nickel being in an amount up to about 100 ppm.
Claim 2
Dependent Claim 95 words
In a trivalent chromium electroplating bath of the type which consists essentially of an acidic aqueous solution of trivalent chromium, a carboxylate selected from formate, acetate and mixtures thereof, a bromide and ammonium the improvement which consists in maintaining in said bath an amount of metal ion selected from (i) iron or nickel in the amount of between 30 and 150 parts per million of the solution by weight, or (ii) iron plus nickel in the amount of between 30 and 150 ppm with the nickel being in an amount up to about 100 ppm.
Claim 3
Dependent Claim 104 words
The bath of claim 1 consisting essentially of: a. from 0.1 to 1.2 molar trivalent chromium; b. from 0.05 to 0.5 molar bromide; c. from 0.5 to 3 moles of a carboxylate selected from formate and mixtures thereof with acetate; d. from 0.2 molar to saturation of ammonium ion; e. from 0.1 molar to saturation of borate; f. at least one ion selected from chloride and sulphate in a concentration of from 1 molar to saturation; g. said metal ion; h. from 0.5 molar to saturation of ion selected from sodium and potassium; i. said bath having a pH of between 1 and 4.
Claim 4
Dependent Claim 15 words
The bath of claim 2 containing from 30 to 150 parts per million of iron.
Claim 5
Dependent Claim 15 words
The bath of claim 2 containing from 30 to 150 parts per million of nickel.
Claim 6
Dependent Claim 30 words
The bath of claim 2 containing from 30 to 150 parts per million of iron plus nickel with nickel being in an amount up to about 100 parts per million.
Claim 7
Dependent Claim 18 words
The bath of claim 2 containing from about 40 to 100 parts per million of iron plus nickel.
Claim 8
Dependent Claim 16 words
The bath of claim 2 containing from about 40 to 100 parts per million of iron.

References Cited (Backward Citations)

US2693444A Cited
US2990343A Cited
US2822326A Cited
US2927066A Cited
US3111464A Cited
US3954574A Cited
US4054494A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-05 1981-12-05 1982-06-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-05 1985-12-05 1986-06-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-05 1989-12-05 1990-06-06 $7700.00 Window Closed / Lapsed

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