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Polycarbonate molded articles having excellent weather resistance and abrasion resistance and a process for the preparation thereof

Assignee: Dainippon Plastics Co Ltd
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Filing: 1985-03-13
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Granted: 1987-05-26
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Expires: 2005-03-13
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Abstract

Abstract Polycarbonate molded articles having excellent weather resistance and excellent abrasion resistance in which polycarbonate molded object is coated with an abrasion resistant cured layer comprising an ultraviolet ray setting paint, through a primer layer comprising a thermoplastic acrylic (or methacrylic) polymer containing 4-8% by weight of an ultraviolet ray absorbing agent, which are substantially transparent and particularly useful as wall materials for greenhouse, ceiling materials, partition wall materials, wall materials for sunroom, substitutes for windbreak glass and the like.

Inventors

  • 👤 Yoshio Kishima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:05
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/04; C08J7/043; C08J7/0427; C08J7/046; C08J2369/00; C08J2433/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31551

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 54 words
A polycarbonate molded article having excellent weather resistance and excellent abrasion resistance in which polycarbonate molded object is coated with an abrasion resistant cured layer comprising an ultraviolet ray setting paint, through a primer layer consisting essentially of a thermoplastic acrylic or methacrylic polymer and 4-8% by weight of an ultraviolet ray absorbing agent.
Claim 2
Dependent Claim 54 words
A polycarbonate molded article having excellent weather resistance and excellent abrasion resistance in which polycarbonate molded object is coated with an abrasion resistant cured layer comprising an ultraviolet ray setting paint, through a primer layer consisting essentially of a thermoplastic acrylic or methacrylic polymer and 4-8% by weight of an ultraviolet ray absorbing agent.
Claim 3
Dependent Claim 21 words
A molded article as claimed in claim 1, wherein the primer layer has a thickness of about 10 μm or less.
Claim 4
Dependent Claim 54 words
A molded article as claimed in claim 1, wherein the thermoplastic acrylic or methacrylic polymer is selected from the following group; a polyalkyl acrylate such as polymethyl acrylate, polyethyl methacrylate, polybutyl methacrylate; or its copolymer such as methyl methacrylate/methyl acrylate copolymer, methyl methacrylate/ethyl acrylate copolymer, methyl methacrylate/butyl acrylate copolymer and methyl methacrylate/butyl acrylate/syrene copolymer.
Claim 5
Dependent Claim 53 words
A molded article as claimed in claim 1, wherein the ultraviolet ray absorbing agent is a benzophenone selected from the group consisting of 2-hydroxy-4-methoxybenzophenone and 2-hydroxy-4-octoxybenzophenone; a triazole selected from the group consisting of 2-(2'-hydroxy-5'-methylphenyl)benxotriazole, and 2-(2'hydroxy-5'-t-octcylphenyl)benzotriazole; or a salicylic acid ester selected from the group consisting of phenyl salicylate and 4-t-butylphenyl salicylate.
Claim 6
Dependent Claim 25 words
A molded article as claimed in claim 1, wherein the thermoplastic acrylic or methacrylic polymer contains 5-7% by weight of the ultraviolet ray absorbing agent.
Claim 7
Dependent Claim 19 words
A molded article as claimed in claim 1, wherein the cured layer has a thickness of about 5-10 μm.
Claim 8
Dependent Claim 29 words
A molded article as claimed in claim 1, wherein the ultraviolet ray setting paint comprises a polyfunctional acrylic oligomer, a photoesensitizer, a monomer a leveling agent and a solvent.
Claim 9
Dependent Claim 36 words
A molded article as claimed in claim 7, wherein the polyfunctional acrylic oligomer is selected from the following group a polyester acrylate oligomer, polyurethane acrylate oligomer, epoxy acrylate oligomer, polyol acrylate oligomer and polyether acrylate oligomer.
Claim 10
Dependent Claim 12 words
A molded article as claimed in claim 1, which is substantially transparent.
Claim 11
Dependent Claim 37 words
A molded article as claimed in claim 1, wherein the polycarbonate molded object is in the form of sheet and its one or both surface is coated with the abrasion resistant cured layer through the primer layer.
Claim 12
Dependent Claim 85 words
A process for the preparation of polycarbonate molded articles having excellent weather resistance and abrasion resistance, in which a solution in an organic solvent of a thermoplastic acrylic or methacrylic polymer containing and 4-8% by weight of an ultraviolet ray absorbing agent is applied on the surface of a polycarbonate molded object and dried to form a primer layer, an ultraviolet ray setting paint is applied on the primer layer and dried, and then ultraviolet ray irradiation is effected to forman abrasion resistant cured layer.
Claim 13
Dependent Claim 85 words
A process for the preparation of polycarbonate molded articles having excellent weather resistance and abrasion resistance, in which a solution in an organic solvent of a thermoplastic acrylic or methacrylic polymer containing and 4-8% by weight of an ultraviolet ray absorbing agent is applied on the surface of a polycarbonate molded object and dried to form a primer layer, an ultraviolet ray setting paint is applied on the primer layer and dried, and then ultraviolet ray irradiation is effected to forman abrasion resistant cured layer.
Claim 14
Dependent Claim 20 words
A process as claimed in claim 11, wherein the primer layer has a thickness of about 10 μm or less.
Claim 15
Dependent Claim 19 words
A process as claimed in claim 11, wherein the cured layer applied has a thickness of about 5-10 μm.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-05-25 1990-11-24 1991-05-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-05-25 1994-11-24 1995-05-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-05-25 1998-11-24 1999-05-26 $7700.00 Window Closed / Lapsed

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