Vinyl esters of polyepoxides of polyphenol cyanate mixture and polymaleimide co-oligomers

Claim 2

A mixture of vinyl ester resins comprising (A) from about 1 to about 99 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyepoxide of a co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide with (2) from about 0.75 to about 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (A-1) in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (A-1) and (A-2); and (B) from about 99 to about 1 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyglycidyl ether of an aromatic compound having an average of more than one phenolic hydroxyl group per molecule with (2) from about 0.75 to 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (B-1); in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (B-1) and (B-2).

Claim 3

A vinyl ester resin mixture of claim 1 wherein (i) component (A) comprises from about 5 to about 50 percent by weight; (ii) component (B) comprises from about 95 to about 50 percent by weight of the combined weight of components (A) and (B); (iii) in component (A), components (A-1) and (A-2) are present in an amount which provides a ratio of acid groups to epoxide groups of from about 0.9:1 to about 1:1; and (iv) in component (B), components (B-1) and (B-2) are present- in an amount which provides a ratio of acid groups to epoxide groups of from about 0.9:1 to about 1:1.

Claim 4

A vinyl ester resin of claim 2 wherein component (A-1) is (a) the polyepoxide resulting from epoxidation of the co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide, (b) the polyepoxide resulting from advancing a polyepoxide or mixture of polyepoxides with the co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide or (c) a mixture of (a) and (b).

Claim 5

A vinyl ester resin of claim 3 wherein in component (A-1), the polyphenol is a bisphenol and the polymaleimide is a bismaleimide prepared from maleic anhydride and an aromatic diamine and component (B-1) is ether of a bisphenol. A vinyl ester resin of claim wherein (a) in c (A-1), the polyphenol is bisphenol.

Claim 6

A vinyl ester resin of claim 4 wherein (a) in component (A-1), the polyphenol is bisphenol A and the polymaleimide is a bismaleimide prepared from maleic anhydride and methylenedianiline; (b) component (B-1) is a diglycidyl ether of bisphenol A and (c) components (A-2) and (B-2) are both methacrylic acid.

Claim 7

A composition which comprises (I) From about 1 to about 99 percent by weight of a mixture of vinyl ester resins comprising (A) from about 1 to about 99 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyepoxide of a co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide with (2) from about 0.75 to about 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (A-1); in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (A-1) and (A-2); and (B) from about 99 to about 1 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyglycidyl ether of an aromatic compound having an average of more than one phenolic hydroxyl group per molecule with (2) from about 0.75 to about 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (B-1); in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (B-1) and (B-2); and (II) from about 99 to about 1 percent by weight of at least one ethylenically unsaturated monomer copolymerizable with component (I).

Claim 8

A composition which comprises (I) From about 1 to about 99 percent by weight of a mixture of vinyl ester resins comprising (A) from about 1 to about 99 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyepoxide of a co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide with (2) from about 0.75 to about 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (A-1); in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (A-1) and (A-2); and (B) from about 99 to about 1 percent by weight of at least one vinyl ester resin prepared by reacting (1) at least one polyglycidyl ether of an aromatic compound having an average of more than one phenolic hydroxyl group per molecule with (2) from about 0.75 to about 1.2 moles of at least one monounsaturated monocarboxylic acid per epoxide group contained in component (B-1); in the presence of (3) a catalytic quantity of a suitable catalyst for effecting a reaction between components (B-1) and (B-2); and (II) from about 99 to about 1 percent by weight of at least one ethylenically unsaturated monomer copolymerizable with component (I).

Claim 9

A composition of claim 6 wherein (i) component (I) is present in an amount which provides from about 30 to about 70 percent by weight based on the combined weight of components (I) and (II); (ii) component (II) is present in an amount which provides from about 70 to about 30 percent by weight based on the combined weight of components (I) and (II); (iii) component (I-A) is present in an amount which provides from about 5 to about 50 percent by weight based on the combined weight of components (I-A) and (I-B); (iv) component (I-B) is present in an amount which provides from about 50 to about 95 percent by weight based on the combined weight of components (I-A) and (I-B); (v) components (I-A-1) and (I-A-2) are present in an amount which provides a ratio of acid groups per epoxide groups of from about 0.9:1 to about 1:1; and (vi) components (I-B-1) and (I-B-2) are present in an amount which provides a ratio of acid groups per epoxide groups of from about 0.9:1 to about 1:1.

Claim 10

A composition of claim 7 wherein (i) component (I-A-1) is (a) the polyepoxide resulting from epoxidation of the co oligomerization product of a mixed cyanate of a polyphenol and a poly maleimide, (b) the polyepoxide resulting from advancing a polyepoxide or mixture of polyepoxides with the co-oligomerization product of a mixed cyanate of a polyphenol and a polymaleimide or (c) a mixture of (a) and (b); (ii) component (I-B-1) is a diglycidyl ether of a bisphenol; and (iii) component (II) is an unsaturated aromatic hydrocarbon or an ester of an unsaturated monocarboxylic acid.

Claim 11

A composition of claim 8 wherein (i) in component (I-A-1), the polyphenol is bisphenol A and the polymaleimide is a bismaleimide prepared from maleic anhydride and methylenedianiline; (ii) component (I-A-2) is methacrylic acid; (iii) component (I-B-1) is a diglycidyl ether of bisphenol A; (iv) component (I-B-2) is methacrylic acid; and (v) component (II) is styrene.

Claim 12

A product resulting from curing a vinyl ester resin or composition of claims 1, 2, 3, 4, 5, 6, 7, 8 or 9 with a curing quantity of a suitAble curing agent therefor in the absence or presence of an effective quantity of a suitable curing accelerator therefor.

Claim 13

A product of claim 10 wherein said curing agent is one or more organioc peroxide compounds and any such curing accelerator is an aromatic amine or a metal carboxylate.

Claim 14

A product of claim 11 wherein said curing agent is benzoyl peroxide, methyl ethyl ketone peroxide, or a combination thereof; and said curing accelerator is cobalt naphthenate, N,N-dimethylaniline, or a combination thereof.