Reversal photographic elements containing tabular grain emulsions

Claim 2

A photographic element capable of forming a reversal image comprising a support and, coated on said support, at least one image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver haloiodide grains having a thickness of less than 0.5 μm and an average aspect ratio of greater than 8:1 accounting for at least 35 percent of the total grain projected area of said emulsion layer and a second grain population present in a concentration sufficient to increase speed and contrast, said second grain population being incapable of forming a latent image extending the exposure latitude imparted to said emulsion layer by said tabular grains, having an average diameter less than that of said tabular grains and less than 0.5 μm, consisting essentially of a silver salt more soluble than silver iodide, and containing less iodide than said tabular grains.

Claim 3

A photographic element capable of forming a reversal image according to claim 1 wherein said radiation sensitive tabular silver haloiodide grains having a thickness of less than 0.3 μm and an average aspect ratio of greater than 8:1 account for at least 50 percent of the total grain projected area of said emulsion layer.

Claim 4

A photographic element capable of forming a reversal image according to claim 2 wherein said radiation sensitive tabular silver haloiodide grains having a thickness of less than 0.2 μm and an average aspect ratio of greater than 8:1 account for at least 70 percent of the total grain projected area of said emulsion layer.

Claim 5

A photographic element capable of forming a reversal image according to claim 1 wherein said tabular silver haloiodide grains contain less than 8 mole percent iodide. based on silver.

Claim 6

A photographic element capable of forming a reversal image according to claim 1 wherein said second grain population consists essentially of a silver salt having a solubility product constant less than 16 at 20° C.

Claim 7

A photographic element capable of forming a reversal image according to claim 4 wherein said second grain population consists essentially of a silver salt having a solubility equal to or greater than that of silver bromide.

Claim 8

A photographic element capable of forming a reversal image according to claim 1 wherein said second grain population is present in a concentration of at least 0.5 mole percent, based on total silver present in said image recording emulsion layer.

Claim 9

A photographic element capable of forming a reversal image according to claim 1 wherein said photographic element contains a dye image forming coupler.

Claim 10

A multicolor photographic element capable of forming a viewable reversal dye image comprising a support and, coated on said support, a blue recording yellow dye image forming layer unit, a green recording magenta dye image forming layer unit, and a red recording cyan dye image forming layer unit, at least one of said dye image forming layer units being comprised of an image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver bromoiodide grains containing less than 8 mole percent iodide having a thickness of less than 0.3 μm and an average aspect ratio of greater than 8:1 accounting for at least 50 percent of the total grain projected area of said emulsion layer and a second grain population which is incapable of forming a latent image extending the exposure latitude imparted to said emulsion layer by said tabular grains, is present in a concentration of from 0.5 to 50 mole percent, based on total silver in said image recording emulsion layer, has an average diameter less than that of said tabular grains and less than 0.5 μm, consists essentially of a silver salt having a solubility product constant of 15.5, and contains less iodide than said tabular grains.

Claim 11

A multicolor photographic element capable of forming a viewable reversal dye image comprising a support and, coated on said support, a blue recording yellow dye image forming layer unit, a green recording magenta dye image forming layer unit, and a red recording cyan dye image forming layer unit, at least one of said dye image forming layer units being comprised of an image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver bromoiodide grains containing less than 8 mole percent iodide having a thickness of less than 0.3 μm and an average aspect ratio of greater than 8:1 accounting for at least 50 percent of the total grain projected area of said emulsion layer and a second grain population which is incapable of forming a latent image extending the exposure latitude imparted to said emulsion layer by said tabular grains, is present in a concentration of from 0.5 to 50 mole percent, based on total silver in said image recording emulsion layer, has an average diameter less than that of said tabular grains and less than 0.5 μm, consists essentially of a silver salt having a solubility product constant of 15.5, and contains less iodide than said tabular grains.

Claim 12

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 9 wherein said green and red recording dye image forming layer units each contain an image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver haloiodide grains containing less than 8 mole percent iodide, having a thickness of less than 0.3 μm and an average aspect ratio of greater than 8:1 accounting for at least 50 percent of the total grain projected area of said emulsion layer and a second grain population which is incapable of forming a latent image extending the exposure latitude imparted to said emulsion layer by said tabular grains, is present in a concentration of from 0.5 to 50 mole percent, based on total silver in said image recording emulsion layer, has an average diameter less than that of said tabular grains and less than 0.5 μm, consists essentially of a silver salt having a solubility product constant of 15.5, and contains less iodide than said tabular grains.

Claim 13

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 9 wherein said tabular grains have an average aspect ratio of at least 12:1.

Claim 14

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 9 wherein said tabular grains contain from 1 to 7 mole percent iodide, based on silver.

Claim 15

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 12 wherein said tabular grains contain from 2 to 6 mole percent iodide, based on silver.

Claim 16

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 9 wherein said grains having a solubility product constant of 15.5 or less have an average diameter of less than 0.3 μm.

Claim 17

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 14 wherein said grains having an average diameter of less than 0.3 μm have a solubility product constant at 20° C. in the range of from 11 to 13.

Claim 18

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 15 wherein said grains having an average diameter of less than 0.3 μm are present in a concentration of at least 1 mole percent. based on total silver present in said image recording emulsion layer.

Claim 19

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 16 wherein said grains having an average diameter of less than 0.3 μm are present in a concentration in the range of from 5 to 50 mole percent, based on total silver present in said image recording emulsion layer.

Claim 20

A multicolor photographic element capable of forming a viewable reversal dye image comprising a support and, coated on said support, a blue recording yellow dye image forming layer unit, a green recording magenta dye image forming layer unit, and a red recording cyan dye image forming layer unit, at least one of said dye image forming layer units being comprised of an image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver bromoiodide grains containing less than 8 mole percent iodide having a thickness of less than 0.3, a diameter of at least 0.6 μm, and an average aspect ratio of greater than 8:1 accounting for at least 50 percent of the total grain projected area of said emulsion layer and grains having an average diameter of less than 0.3 μm consisting essentially of silver thiocyanate present in a concentratin of from 0.5 to 50mole percent, based on total silver in said image recording layer.

Claim 21

A multicolor photographic element capable of forming a viewable reversal dye image comprising a support and, coated on said support, a blue recording yellow dye image forming layer unit, a green recording magenta dye image forming layer unit, and a red recording cyan dye image forming layer unit, at least one of said dye image forming layer units being comprised of an image recording emulsion layer comprised of a dispersing medium and a blend of radiation sensitive tabular silver bromoiodide grains containing less than 8 mole percent iodide having a thickness of less than 0.3, a diameter of at least 0.6 μm, and an average aspect ratio of greater than 8:1 accounting for at least 50 percent of the total grain projected area of said emulsion layer and grains having an average diameter of less than 0.3 μm consisting essentially of silver thiocyanate present in a concentratin of from 0.5 to 50mole percent, based on total silver in said image recording layer.

Claim 22

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 15 wherein said grains having a solubility product constant in the range of from 11 to 13 have an average diameter of less than 0.1 μm.

Claim 23

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 19 wherein said grains having an average diameter of less than 0.1 μm consist essentially of at least one of silver bromide and silver chloride.

Claim 24

A multicolor photographic element capable of forming a viewable reversal dye image according to claim 20 wherein said grains having an average diameter of less than 0.1 μm consist essentially of silver bromide.