Patent US4647546A successfully refreshed from Google Patents.
US4647546A
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Polycrystalline cubic boron nitride compact
Assignee: Industrielle de Combustible Nucleaire Ste
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Filing: 1984-10-30
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Granted: 1987-03-03
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Expires: 2004-10-30
Abstract
Abstract The invention is a process for preparing a sintered polycrystalline compact of cubic boron nitride, the compact produced by the process, and articles comprising the compact. A mixture is formed of cubic boron nitride grains and from 5 to 20 volume percent of binder material, or sintering aid, consisting essentially of silicon and an aluminum-containing material selected from the group consisting of aluminum, aluminum nitride, aluminum diboride, and mixtures thereof. The mixture is subjected to elevated pressure and temperature conditions sufficient to melt the binder material and at which the boron nitride is thermodynamically stable. The elevated pressure and temperature conditions are maintained for a time sufficient to sinter the compact. The compact is characterized by substantial intergranular CBN-CBN bonding, and has superior wear and impact resistance, thermal conductivity and stability.
Inventors
- 👤 H. Tracy Hall, Jr.
- 👤 Jean-Michel Cerceau
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 03:11
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/583; C04B35/5831
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
124 words
A process for preparing a sintered polycrystalline compact with substantial intercrystalline bonding from high pressure boron nitride which comprises: (a) forming a mixture consisting essentially of grains of high pressure boron nitride with a minor amount of a binder material consisting essentially of silicon, and an aluminum-containing material selected from the group consisting of aluminum alone, aluminum with aluminum nitride, aluminum with aluminum diboride, or aluminum with aluminum nitride and aluminum diboride; (b) subjecting the mixture to elevated temperature and pressure conditions sufficient to melt substantially all of the binder material and at which condition the high pressure boron nitride is thermodynamically stable; and (c) maintaining the elevated conditions for a time sufficient to allow for substantial intercrystalline bonding to thereby sinter the compact.
Claim 2
Dependent Claim
124 words
A process for preparing a sintered polycrystalline compact with substantial intercrystalline bonding from high pressure boron nitride which comprises: (a) forming a mixture consisting essentially of grains of high pressure boron nitride with a minor amount of a binder material consisting essentially of silicon, and an aluminum-containing material selected from the group consisting of aluminum alone, aluminum with aluminum nitride, aluminum with aluminum diboride, or aluminum with aluminum nitride and aluminum diboride; (b) subjecting the mixture to elevated temperature and pressure conditions sufficient to melt substantially all of the binder material and at which condition the high pressure boron nitride is thermodynamically stable; and (c) maintaining the elevated conditions for a time sufficient to allow for substantial intercrystalline bonding to thereby sinter the compact.
Claim 3
Dependent Claim
15 words
The process of claim 1, wherein the high pressure boron nitride is cubic boron nitride.
Claim 4
Dependent Claim
41 words
The process of claim 1 or 2, wherein the binder material is selected from the group consisting of a mixture of powders of silicon and the aluminum-containing material, powders of an alloy of aluminum and silicon, or a powdered mixture thereof.
Claim 5
Dependent Claim
55 words
The process of claim 3, wherein prior to subjecting the mixture to elevated temperature and pressure conditions at which the high pressure boron nitride is thermodynamically stable, the mixture is placed in a non-oxidizing atmosphere and subjected to an initial elevated temperature sufficient to cause reaction between the aluminum and the high pressure boron nitride.
Claim 6
Dependent Claim
21 words
the process of claim 4, wherein said initial elevated temperature is with in the range of 600° C. to 1200° C.
Claim 7
Dependent Claim
18 words
The process of claim 3, wherein the binder contains between about 5 to 50 percent by weight aluminum.
Claim 8
Dependent Claim
19 words
The process of claim 3, wherein the binder contains between about 15 to about 30 percent by weight aluminum.
Claim 9
Dependent Claim
17 words
The process of claim 3, wherein the mixture contains between about 5 to 20 volume percent binder.
Claim 10
Dependent Claim
20 words
The process of claim 2 wherein the binder material is a mixture of powders of silicon and the aluminum-containing material.
Claim 11
Dependent Claim
17 words
The process of claim 9, wherein the mixture contains between about 5 and 20 volume percent binder.
Claim 12
Dependent Claim
18 words
The process of claim 9, wherein the binder contains between about 5 to 50 percent by weight aluminum.
Claim 13
Dependent Claim
21 words
The process of claim 3, wherein the pressure is at least 45 kbar and the temperature is at least 1200° C.
Claim 14
Dependent Claim
145 words
A process for preparing a sintered polycrystalline compact from high pressure boron nitride comprising the steps of: (a) placing immediately adjacent to a mass consisting essentially of high pressure boron nitride grains a mass of a binder material consisting essentially of a mixture of silicon and a aluminum-containing material selected from the group consisting of aluminum alone, aluminum with aluminum nitride, aluminum with aluminum diboride, or aluminum with aluminum nitride and a aluminum diboride; (b) subjecting the boron nitride grains and binder material to elevated temperature and pressure conditions sufficient to melt substantially all of the binder materials and at which the high pressure boron nitride is thermodynamically stable, wherein substantially all of the silicon and aluminum infiltrates the mass of boron nitride crystals; and (c) maintaining the elevated conditions for a time sufficient to allow for substantial intercrystalline bonding to thereby sinter the compact.
Claim 15
Dependent Claim
145 words
A process for preparing a sintered polycrystalline compact from high pressure boron nitride comprising the steps of: (a) placing immediately adjacent to a mass consisting essentially of high pressure boron nitride grains a mass of a binder material consisting essentially of a mixture of silicon and a aluminum-containing material selected from the group consisting of aluminum alone, aluminum with aluminum nitride, aluminum with aluminum diboride, or aluminum with aluminum nitride and a aluminum diboride; (b) subjecting the boron nitride grains and binder material to elevated temperature and pressure conditions sufficient to melt substantially all of the binder materials and at which the high pressure boron nitride is thermodynamically stable, wherein substantially all of the silicon and aluminum infiltrates the mass of boron nitride crystals; and (c) maintaining the elevated conditions for a time sufficient to allow for substantial intercrystalline bonding to thereby sinter the compact.
Claim 16
Dependent Claim
15 words
The process of claim 13, wherein the high pressure boron nitride is cubic boron nitride.
Claim 17
Dependent Claim
41 words
The process of claim 13 or 14, wherein the binder material is selected from the group consisting of a mixture of powders of silicon and the aluminum-containing material, powders of an alloy of aluminum and silicon, or a powdered mixture thereof.
Claim 18
Dependent Claim
18 words
The process of claim 15, wherein the binder contains between about 5 to 20 percent by weight aluminum.
Claim 19
Dependent Claim
17 words
The process of claim 15, wherein the compact contains between about 5 to 20 volume percent binder.
Claim 20
Dependent Claim
21 words
The process of claim 15, wherein the pressure is at least 45 kbar and the temperature is at least 1200° C.
Claim 21
Dependent Claim
18 words
The compact produced according to the process of claims 1, 2, 9, 10, 11, 12, 13 or 14.
Claim 22
Dependent Claim
10 words
The compact produced according to the process of claim 3.
Claim 23
Dependent Claim
10 words
The compact produced according to the process of claim 4.
Claim 24
Dependent Claim
10 words
The compact produced according to the process of claim 15.
Claim 25
Dependent Claim
12 words
An article comprising the compact of claims 19, 20, 21 or 22.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-02 | 1990-09-01 | 1991-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-02 | 1994-09-01 | 1995-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-02 | 1998-09-01 | 1999-03-03 | $7700.00 | Window Closed / Lapsed |