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US4640868A Expired / Lapsed US ⏱️ 0.0 years remaining

Clear, weather resistant adherent coating

Assignee: ATK Launch Systems LLC
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Filing: 1986-02-10
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Granted: 1987-02-03
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Expires: 2006-02-10
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Abstract

Abstract A composition capable of providing, upon hydrolyzing and curing, a protective coating for substrates such as, for example, a plastic substrate having a vacuum metallized or vacuum sputtered surface comprises the reaction product of: (a) an isocyanurate polyisocyanate having the following formula: <IMAGE> wherein R4 is a substituted or unsubstituted aliphatic or cycloaliphatic group having from 1 to 12 carbon atoms or an aryl group and (b) an amino disilane having the formula: <IMAGE> wherein R is a lower alkyl having 1 to about 6 carbon atoms; R1 is a lower alkyl having 1 to about 4 carbon atoms; R2 and R3, which may be the same or different, are each substituted or unsubstituted alkylene radicals having 2 to 18 carbon atoms or arylene radicals having 6 to 18 carbon atoms; and a is an integer having values of 0 to 2, the protective coating adhering particularly well to such surfaces and having especially superior resistance to ultraviolet light, humidity, air and heat.

Inventors

  • 👤 Howard I. Penn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:58
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/2805; C08G18/288; C08G18/289; C08G18/70; C08G18/72; C08G18/77; C08G18/78; C08G18/79; C08G18/791; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 128 words
A composition, upon hydrolysis and curing, providing a protective coating comprising the reaction product of: (a) an isocyanurate polyisocyanate having the following formula: ##STR7## wherein R 4 is a substituted or unsubstituted aliphatic or cycloaliphatic group having from 1 to 12 carbon atoms or an aryl group, and (b) an amino disilane having the formula: ##STR8## wherein R is a lower alkyl having 1 to about 6 carbon atoms; R 1 is a lower alkyl having 1 to about 4 carbon atoms; R 2 and R 3 , which may be the same or different, are each substituted or unsubstituted alkylene radicals having 2 to 18 carbon atoms or arylene radicals having 6 to 18 carbon atoms; and a is an integer having values of 0 to 2.
Claim 2
Dependent Claim 128 words
A composition, upon hydrolysis and curing, providing a protective coating comprising the reaction product of: (a) an isocyanurate polyisocyanate having the following formula: ##STR7## wherein R 4 is a substituted or unsubstituted aliphatic or cycloaliphatic group having from 1 to 12 carbon atoms or an aryl group, and (b) an amino disilane having the formula: ##STR8## wherein R is a lower alkyl having 1 to about 6 carbon atoms; R 1 is a lower alkyl having 1 to about 4 carbon atoms; R 2 and R 3 , which may be the same or different, are each substituted or unsubstituted alkylene radicals having 2 to 18 carbon atoms or arylene radicals having 6 to 18 carbon atoms; and a is an integer having values of 0 to 2.
Claim 3
Dependent Claim 12 words
The composition of claim 1 wherein R 4 is an isophorone moiety.
Claim 4
Dependent Claim 12 words
The composition of claim 1 wherein R 4 is a hexamethylene moiety.
Claim 5
Dependent Claim 9 words
The composition of claim 1 wherein a is zero.
Claim 6
Dependent Claim 9 words
The composition of claim 1 wherein R is methyl.
Claim 7
Dependent Claim 20 words
The composition of claim 1 wherein R is methyl, R 2 and R 3 are propyl and a is zero.
Claim 8
Dependent Claim 21 words
The composition of claim 1 wherein the isocyanurate polyisocyanate and the amino disilane are reacted in essentially a stoichiometric molar ratio.
Claim 9
Dependent Claim 24 words
A coated member comprising (a) a substrate and (b) a protective coating on said substrate comprising the hydrolyzed and cured composition of claim 1.
Claim 10
Dependent Claim 21 words
The coated member of claim 8 wherein the substrate comprises a plastic member having a vacuum metallized or vacuum sputtered surface.
Claim 11
Dependent Claim 16 words
The coated member of claim 9 wherein the vacuum metallized surface is opaquely deposited (vaporized) aluminum.
Claim 12
Dependent Claim 16 words
The coated member of claim 9 wherein the vacuum sputtered surface is translucent sputtered stainless steel.
Claim 13
Dependent Claim 15 words
The coated member of claim 9 wherein the vacuum sputtered surface is translucent sputtered titanium.
Claim 14
Dependent Claim 13 words
The coated member of claim 8 wherein R 4 is an isophorone moiety.
Claim 15
Dependent Claim 13 words
The coated member of claim 8 wherein R 4 is a hexamethylene moiety.
Claim 16
Dependent Claim 10 words
The coated member of claim 8 wherein a is zero.
Claim 17
Dependent Claim 10 words
The coated member of claim 8 wherein R is methyl.
Claim 18
Dependent Claim 21 words
The coated member of claim 8 wherein R is methyl, R 2 and R 3 are propyl and a is zero.
Claim 19
Dependent Claim 22 words
The coated member of claim 8 wherein the isocyanate polyisocyanate and the amino disilane are reacted in essentially a stoichiometric molar ratio.
Claim 20
Dependent Claim 14 words
The coated member of claim 9 wherein the vacuum sputtered surface is indium-tin oxide.
Claim 21
Dependent Claim 21 words
A reflector for increasing the amount of useful light delivered from a fluorescent lamp, comprising the coated member of claim 9.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-02 1990-08-04 1991-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-02 1994-08-04 1995-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-02 1998-08-04 1999-02-03 $7700.00 Window Closed / Lapsed

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