US4634729A
Expired / Lapsed
US
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Terpene-based ester tackifiers
Assignee: Union Camp Corp
•
Filing: 1985-09-23
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Granted: 1987-01-06
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Expires: 2005-09-23
Abstract
Abstract Terpene-based esters are found to be advantageous tackifiers in polymeric resin based adhesives.
Inventors
- 👤 Mark S. Pavlin
- 👤 Richard L. Veazey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 09:31
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J157/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/28; C08L2666/34
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
85 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (R).sub.n AP wherein R is the residue of a conjugated diene terpene compound following Diels-Alder reaction with an acrylate-polyol ester; AP represents the reaction residue of a acrylatepolyol ester; and n is a whole number integer equal to the number of reacted acrylate groups in the acrylate-polyol ester.
Claim 2
Dependent Claim
85 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (R).sub.n AP wherein R is the residue of a conjugated diene terpene compound following Diels-Alder reaction with an acrylate-polyol ester; AP represents the reaction residue of a acrylatepolyol ester; and n is a whole number integer equal to the number of reacted acrylate groups in the acrylate-polyol ester.
Claim 3
Dependent Claim
41 words
The composition of claim 1 wherein the resin is an elastomer selected from the group consisting of styrenebutadiene copolymers, carboxylated styrene-butadiene polymers, styrene-isoprene-styrene copolymers, hydrogenated styrene-ethylene-butadiene styrene polymers, natural rubber or isoprene elastomers, ethylene vinyl acetate copolymers, and acrylate-polyol ester elastomers.
Claim 4
Dependent Claim
85 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (R').sub.n AP wherein R' is the residue of a conjugated triene terpene compound following Diels-Alder reaction with an acrylate-polyol ester; AP represents the reaction residue of the acrylate-polyol ester; and n is a whole number integer equal to the number of reacted acrylate groups in the acrylate-polyol ester.
Claim 5
Dependent Claim
85 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (R').sub.n AP wherein R' is the residue of a conjugated triene terpene compound following Diels-Alder reaction with an acrylate-polyol ester; AP represents the reaction residue of the acrylate-polyol ester; and n is a whole number integer equal to the number of reacted acrylate groups in the acrylate-polyol ester.
Claim 6
Dependent Claim
93 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (RA).sub.n P wherein RA is the residue of the Diels-Alder adduct of a terpene diene compound and acrylic acid, methacrylic acid, or crotonic acid following esterification with a polyol; P represents the esterification reaction residue of the polyol; and n is a whole number integer equal to the number of reacted alcohol groups in the polyol.
Claim 7
Dependent Claim
93 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (RA).sub.n P wherein RA is the residue of the Diels-Alder adduct of a terpene diene compound and acrylic acid, methacrylic acid, or crotonic acid following esterification with a polyol; P represents the esterification reaction residue of the polyol; and n is a whole number integer equal to the number of reacted alcohol groups in the polyol.
Claim 8
Dependent Claim
93 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (RA').sub.n P wherein RA' is the residue of the Diels-Alder adduct of a terpene triene compound and acrylic acid, methacrylic acid, or crotonic acid following esterification with a polyol; P represents the esterification reaction residue of the polyol; and n is a whole number integer equal to the number of reacted alcohol groups in the polyol.
Claim 9
Dependent Claim
93 words
In an adhesive formulation comprising a polymeric resin and a tackifying proportion of a tackifier compound, the improvement, which comprises; the presence of a terpene-based ester as a tackifier ingredient, said terpene-based ester being of the formula: (RA').sub.n P wherein RA' is the residue of the Diels-Alder adduct of a terpene triene compound and acrylic acid, methacrylic acid, or crotonic acid following esterification with a polyol; P represents the esterification reaction residue of the polyol; and n is a whole number integer equal to the number of reacted alcohol groups in the polyol.
Claim 10
Dependent Claim
21 words
The compositions of claims 1, 3, 4, and 5 wherein the terpene-based esters have molecular weights of from 300 to 1000.
Claim 11
Dependent Claim
19 words
The compositions of claims 1 and 4 wherein the terpene-based esters are prepared from trimethylolpropane, alpha-terpinene, and acrylic acid.
Claim 12
Dependent Claim
19 words
The compositions of claims 1 and 4 wherein the terpene-based esters are prepared from pentaerythritol, alpha-terpinene, and acrylic acid.
Claim 13
Dependent Claim
19 words
The compositions of claims 3 and 5 wherein the terpene-based esters are prepared from trimethylolpropane, alloocimene, and acrylic acid.
Claim 14
Dependent Claim
19 words
The compositions of claims 3 and 5 wherein the terpene-based esters are prepared from trimethylolpropane, myrcene, and acrylic acid.
Claim 15
Dependent Claim
19 words
The compositions of claims 3 and 5 wherein the terpene-based esters are prepared from pentaerythritol, alloocimene, and acrylic acid.
Claim 16
Dependent Claim
41 words
The composition of claim 3 wherein the resin is an elastomer selected from the group consisting of styrene-butadiene copolymers, carboxylated styrene-butadiene polymers, styrene-isoprene-styrene copolymers, hydrogenated styrene-ethylene-butadiene styrene polymers, natural rubber or isoprene elastomers, ethylene vinyl acetate copolymers, and acrylate-polyol ester elastomers.
Claim 17
Dependent Claim
41 words
The composition of claim 4 wherein the resin is an elastomer selected from the group consisting of styrene-butadiene copolymers, carboxylated styrene-butadiene polymers, styrene-isoprene-styrene copolymers, hydrogenated styrene-ethylene-butadiene styrene polymers, natural rubber or isoprene elastomers, ethylene vinyl acetate copolymers, and acrylate-polyol ester elastomers.
Claim 18
Dependent Claim
41 words
The composition of claim 5 wherein the resin is an elastomer selected from the group consisting of styrene-butadiene copolymers, carboxylated styrene-butadiene polymers, styrene-isoprene-styrene copolymers, hydrogenated styrene-ethylene-butadiene styrene polymers, natural rubber or isoprene elastomers, ethylene vinyl acetate copolymers, and acrylate-polyol ester elastomers.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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