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US4611042A Expired / Lapsed US ⏱️ 0.0 years remaining

Resinous copolymeric siloxanes containing alkenyldimethylsiloxanes

Assignee: Dow Silicones Corp
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Filing: 1985-10-03
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Granted: 1986-09-09
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Expires: 2005-10-03
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Abstract

Abstract A xylene-soluble, resinous copolymer containing SiO 2 units, trimethylsiloxane units, and alkenyldimethylsiloxane units such as 5-hexenyldimethylsiloxane units is disclosed. The resinous copolymer is useful as a component in silicone coatings, especially silicone release coatings, to provide intermediate range release forces against adhesives. The higher alkenyl functionality provides faster reaction with other coating components and reduced odor during cure of UV curable mercaptosilicone compositions.

Inventors

  • 👤 Stacia A. Rivers-Farrell
  • 👤 Antony P. Wright

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 18:07
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/20

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 114 words
A xylene-soluble copolymer consisting essentially of trimethylsiloxane units, alkenyldimethylsiloxane units, and SiO 2 units, the mole ratio of alkenyldimethylsiloxane units to trimethylsiloxane units being from 0.02:1 to 0.5:1, the mole ratio of the sum of trimethylsiloxane units and alkenyldimethylsiloxane units to SiO 2 units being from 0.6:1 to 1.2:1, and the silicon bonded hydroxyl content of the copolymer being no more than four weight percent, the alkenyldimethylsiloxane units are represented by the formula ##STR5## wherein R denotes --(CH 2 )n-- or --CH═CH(CH 2 ) p -- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.
Claim 2
Dependent Claim 114 words
A xylene-soluble copolymer consisting essentially of trimethylsiloxane units, alkenyldimethylsiloxane units, and SiO 2 units, the mole ratio of alkenyldimethylsiloxane units to trimethylsiloxane units being from 0.02:1 to 0.5:1, the mole ratio of the sum of trimethylsiloxane units and alkenyldimethylsiloxane units to SiO 2 units being from 0.6:1 to 1.2:1, and the silicon bonded hydroxyl content of the copolymer being no more than four weight percent, the alkenyldimethylsiloxane units are represented by the formula ##STR5## wherein R denotes --(CH 2 )n-- or --CH═CH(CH 2 ) p -- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.
Claim 3
Dependent Claim 36 words
The copolymer of claim 1 wherein the silicon bonded hydroxyl content of the copolymer is no more than 3.5 weight percent and the mole ratio of alkenyldimethylsiloxane units to trimethylsiloxane units is from 0.1:1 to 0.3:1.
Claim 4
Dependent Claim 25 words
The copolymer of claim 2 wherein the alkenyl radicals in the alkenyldimethylsiloxane units are selected from the group consisting of 5-hexenyl, 7-octenyl, 9-decenyl, and 5,9-decadienyl.
Claim 5
Dependent Claim 13 words
The copolymer of claim 2 wherein R denotes --(CH 2 ) n --.
Claim 6
Dependent Claim 11 words
The copolymer of claim 4 wherein the alkenyldimethylsiloxane unit is 5-hexenyldimethylsiloxane.

References Cited (Backward Citations)

US3527659A Cited
US4064027A Cited
US3873499A Cited
US4123604A Cited
US4052529A Cited
GB1569681A Cited
US4107390A Cited
US4535141A Cited
US4555529A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-08 1990-03-10 1990-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-08 1994-03-10 1994-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-08 1998-03-10 1998-09-09 $7700.00 Window Closed / Lapsed

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