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US4605849A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive devices having enhanced blue light response

Assignee: Polaroid Corp
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Filing: 1984-10-31
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Granted: 1986-08-12
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Expires: 2004-10-31
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Abstract

Abstract The blue light response of solid state photosensitive devices such as silicon based charge-coupled devices (CCDs), charged-injection devices, photovoltaic devices and the like is enhanced by applying to the surface thereof a thin layer which includes a first, or donor, dye which absorbs efficiently in the blue region of the spectrum and a second, or acceptor, dye which absorbs efficiently in the green region of the spectrum, there being substantial overlap between the emission spectrum of the donor and the absorption spectrum of the acceptor. The relative concentrations of the dyes are controlled such that the donor dye transfers energy nonradiatively to the acceptor dye which is caused to fluoresce thereby emitting light in the region where the device has substantial photoresponse.

Inventors

  • 👤 Peter O. Kliem
  • 👤 Alan B. Fischer
  • 👤 Shai Inbar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 15:22
CPC Classifications
H; H10; H10F; H10F77/00; H10F77/30; H10F77/306

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 123 words
A photosensitive element having enhanced blue light photoresponse comprising a solid state photosensitive device carrying on a surface thereof a thin layer comprising a donor dye and an acceptor dye uniformly dispersed in an optically transparent polymeric binder material, wherein said donor dye absorbs light in the blue region of the spectrum and said acceptor dye absorbs light in the green region of the spectrum, there is substantial overlap between the fluorescence emission spectrum of the donor dye and the absorption spectrum of the acceptor dye, said donor and acceptor dyes being present in relative amounts such that said donor dye is adapted to transfer at least a substantial portion of the energy from its singlet excited state nonradiatively to said acceptor dye.
Claim 2
Dependent Claim 123 words
A photosensitive element having enhanced blue light photoresponse comprising a solid state photosensitive device carrying on a surface thereof a thin layer comprising a donor dye and an acceptor dye uniformly dispersed in an optically transparent polymeric binder material, wherein said donor dye absorbs light in the blue region of the spectrum and said acceptor dye absorbs light in the green region of the spectrum, there is substantial overlap between the fluorescence emission spectrum of the donor dye and the absorption spectrum of the acceptor dye, said donor and acceptor dyes being present in relative amounts such that said donor dye is adapted to transfer at least a substantial portion of the energy from its singlet excited state nonradiatively to said acceptor dye.
Claim 3
Dependent Claim 18 words
The photosensitive element as defined in claim 1 wherein said photosensitive device comprises a silicon based charge-coupled device.
Claim 4
Dependent Claim 35 words
The photosensitive element as defined in claim 2 wherein said donor dye has λ max of about 450 nm and said acceptor dye has λ max of from about 500 nm to about 600 nm.
Claim 5
Dependent Claim 22 words
The photosensitive element as defined in claim 3 wherein said acceptor dye has a quantum fluorescence yield of at least about 0.9.
Claim 6
Dependent Claim 21 words
The photosensitive element as defined in claim 2 wherein said dye layer has a thickness of about 1 micron or less.
Claim 7
Dependent Claim 9 words
The photosensitive element as defined in polymethylmethacrylate or trifluoropolyvinylalcohol.
Claim 8
Dependent Claim 9 words
The photosensitive element as defined in polymethylmethacrylate or trifluoropolyvinylalcohol.

References Cited (Backward Citations)

US3622316A Cited
US3730714A Cited
US3622317A Cited
US3799783A Cited
US3912931A Cited
US3887271A Cited
US4088508A Cited
US4051374A Cited
US4367930A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-08-11 1990-02-10 1990-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-08-11 1994-02-10 1994-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-08-11 1998-02-10 1998-08-12 $7700.00 Window Closed / Lapsed

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