Photoconductive imaging member with stabilizer in charge transfer layer

Claim 2

An electrophotographic imaging member comprising a conductive layer, a charge generation layer and a charge transport layer, said charge transport layer comprising an aromatic amine charge transport molecule in a continuous polymeric binder phase and from about 0.01 percent by weight to about 5 percent by weight based on the total weight of said transport layer of a chemical stabilizer selected from the group consisting of I. a nitrone compound having the structural formula ##STR12## wherein R 1 is selected from the group consisting of a substituted and unsubstituted group selected from the group consisting of a phenyl group, a fused ring aromatic group and a heterocyclic group, and R 2 is selected from the group consisting of a substituted and unsubstituted group selected from the group consisting of a linear or branched alkyl group containing 1 to 20 carbon atoms, a phenyl group, a fused ring aromatic group and a heterocyclic group, II. an isobenzofuran compound having the structural formula ##STR13## wherein R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of substituted and unsubstituted alkyl groups containing 1 to 10 carbon atoms and substituted and unsubstituted phenyl groups, III. a hydroxyaromatic compound selected from the group consisting of A. fused hydroxyaromatic compounds having the structural formula ##STR14## wherein R 9 , R 10 , R 11 , and R 12 are independently selected from the groupm consisting of hydrogen, a hydroxyl group, a alkoxy group containing 1 to 6 carbon atoms, and an alkyl group containing 1 to 6 carbon atoms, wherein at least one of said R 9 , R 10 , R 11 , and R 12 is a hydroxyl group, and R 13 and R 14 are independently selected from the group consisting of hydrogen, an alkenyl group containing 2 to 40 carbon atoms, and an alkyl group containing 1 to 40 carbon atoms, and B. monomeric and polymeric phenolic compounds having the structural formula ##STR15## wherein R 15 , R 16 , R 17 , R 18 , and R 19 aare independently selected from the group conssisting of hydrogen, a hydroxyl group, and substituted and unsubstituted groups selected from the group consisting of a linear alkyl group containing 1 to 20 carbon atoms, a branched alkyl group containing 1 to 20 carbon atoms, an alkenyl group containing 1 to 20 carbon atoms, an ester group containing 1 to 20 carbon atoms, a phenyl group, a napthyl group, and C. substituted and unsubstituted naphthol compounds, and mixtures thereof.

Claim 3

An electrophotographic imaging member according to claim 1 wherein said stabilizer is t-butylphenylnitrone.

Claim 4

An electrophotographic imaging member according to claim 1 wherein said stabilizer is diphenylisobenzofuran.

Claim 5

An electrophotographic imaging member according to claim 1 wherein said fused hydroxyaromatic compound is alpha-tocopherol.

Claim 6

An electrophotographic imaging member according to claim 1 wherein said phenolic compound is selected from the group consisting of 2,6-di-tert-butylphenol, 2,6-di-tert-butyl-4-methoxyphenol, 2,6-di-tert-butyl-4-methylphenol, 2-tert-butyl-4-methoxyphenol, erythrityl tetrakis[beta-(4-hydroxy-3,5-di-tert-butylphenyl)propionate] and mixtures thereof.

Claim 7

An electrophotographic imaging member according to claim 1 wherein said transport layer comprises from about 0.05 percent by weight to about 2 percent by weight of the stabilizer based on the total weight of said transport layer.

Claim 8

An electrophotographic imaging member according to claim 1 wherein said aromatic amine charge transport molecule has the general formula: ##STR16## wherein R 21 and R 22 are an aromatic group selected from the group consisting of a substituted or unsubstituted phenyl group, naphthyl group, and polyphenyl group and R 23 is selected from the group consisting of a substituted or unsubstituted aryl group, alkyl group having from 1 to 18 carbon atoms and cycloaliphatic compounds having from 3 to 18 carbon atoms.

Claim 9

An electrophotographic imaging process comprising providing an electrophotographic imaging member comprising a conductive layer, a charge generation layer and a charge transport layer, said charge transport layer comprising an aromatic amine charge transport molecule in a continuous polymeric binder phase and from about 0.01 percent by weight to about 5 percent by weight based on the total weight of said transport layer of a chemical stabilizer selected from the group consisting of I. a nitrone compound having the structural formula ##STR17## wherein R 1 is selected from the group consisting of a substituted and unsubstituted group selected from the group consisting of a phenyl group, a fused ring aromatic group and a heterocyclic group, and R 2 is selectes from the group consisting of a substituted and unsubstituted group selected from the group consisting of a linear or branched alkyl group containing 1 to 20 carbon atoms, a phenyl group, a fused ring aromatic group and a heterocyclic group, II. an isobenzofuran compound having the structural formula ##STR18## wherein R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of substituted and unsubstituted alkyl groups containing 1 to 10 carbon atoms and substituted and unsubstituted phenyl groups, III. a hydroxyaromatic compound selected from the group consisting of A. fused hydroxyaromatic compounds having the structural formula ##STR19## wherein R 9 , R 10 , R 11 , and R 12 are independently selected from the groupm consisting of hydrogen, a hydroxyl group, an alkoxy group containing 1 to 6 carbon atoms, and an alkyl group containing 1 to 6 carbon atoms, wherein at least one of said R 9 , R 10 , R 11 , and R 12 is a hydroxyl group, and R 13 and R 14 are independently selected from the group consisting of hydrogen, an alkenyl group containing 2 to 40 carbon atoms, and an alkyl group containing 1 to 40 carbon atoms, and B. monomeric and polymeric phenolic compounds having the structural formula ##STR20## wherein R 15 , R 16 , R 17 , R 18 , and R 19 are independently selected from the group conssisting of hydrogen, a hydroxyl group, and substituted and unsubstituted groups selected from the group consisting of a linear alkyl group containing 1 to 20 carbon atoms, a branched alkyl group containing 1 to 20 carbon atoms, an alkenyl group containing 1 to 20 carbon atoms, an ester group containing 1 to 20 carbon atoms, a phenyl group, a napthyl group, an ester group, and an alkoxy group containing 1 to 20 carbon atoms, and C. substituted and unsubstituted naphthol compounds, and mixtures thereof, forming an electrostatic latent image on said electrophotographic imaging member, contacting said electrostatic latent image with electrostatically attractable toner particles to form a deposited toner image in image configuration and transfering said toner image to a receiving member.

Claim 10

An electrophotographic imaging process comprising providing an electrophotographic imaging member comprising a conductive layer, a charge generation layer and a charge transport layer, said charge transport layer comprising an aromatic amine charge transport molecule in a continuous polymeric binder phase and from about 0.01 percent by weight to about 5 percent by weight based on the total weight of said transport layer of a chemical stabilizer selected from the group consisting of I. a nitrone compound having the structural formula ##STR17## wherein R 1 is selected from the group consisting of a substituted and unsubstituted group selected from the group consisting of a phenyl group, a fused ring aromatic group and a heterocyclic group, and R 2 is selectes from the group consisting of a substituted and unsubstituted group selected from the group consisting of a linear or branched alkyl group containing 1 to 20 carbon atoms, a phenyl group, a fused ring aromatic group and a heterocyclic group, II. an isobenzofuran compound having the structural formula ##STR18## wherein R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of substituted and unsubstituted alkyl groups containing 1 to 10 carbon atoms and substituted and unsubstituted phenyl groups, III. a hydroxyaromatic compound selected from the group consisting of A. fused hydroxyaromatic compounds having the structural formula ##STR19## wherein R 9 , R 10 , R 11 , and R 12 are independently selected from the groupm consisting of hydrogen, a hydroxyl group, an alkoxy group containing 1 to 6 carbon atoms, and an alkyl group containing 1 to 6 carbon atoms, wherein at least one of said R 9 , R 10 , R 11 , and R 12 is a hydroxyl group, and R 13 and R 14 are independently selected from the group consisting of hydrogen, an alkenyl group containing 2 to 40 carbon atoms, and an alkyl group containing 1 to 40 carbon atoms, and B. monomeric and polymeric phenolic compounds having the structural formula ##STR20## wherein R 15 , R 16 , R 17 , R 18 , and R 19 are independently selected from the group conssisting of hydrogen, a hydroxyl group, and substituted and unsubstituted groups selected from the group consisting of a linear alkyl group containing 1 to 20 carbon atoms, a branched alkyl group containing 1 to 20 carbon atoms, an alkenyl group containing 1 to 20 carbon atoms, an ester group containing 1 to 20 carbon atoms, a phenyl group, a napthyl group, an ester group, and an alkoxy group containing 1 to 20 carbon atoms, and C. substituted and unsubstituted naphthol compounds, and mixtures thereof, forming an electrostatic latent image on said electrophotographic imaging member, contacting said electrostatic latent image with electrostatically attractable toner particles to form a deposited toner image in image configuration and transfering said toner image to a receiving member.

Claim 11

An electrophotographic imaging process according to claim 8 comprising repeating said electrostatic latent image forming, toner particles contacting, and toner image transfering steps in a corona generated species rich environment.