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US4593052A
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Polymerizable compositions containing diphenyliodosyl salts
Assignee: Novartis Corp
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Filing: 1984-11-19
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Granted: 1986-06-03
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Expires: 2004-11-19
Abstract
Abstract Polymerizable compositions contain (A) a cationically polymerizable material, such as an epoxide resin, a phenoplast or a cyclic vinyl ether, (B) a hydroxy compound such as styreneallyl alcohol copolymer, and (c) an aromatic iodosyl salt of formula ##STR1## where R 3 and R 4 , which may be the same or different, each represent a monovalent aromatic radical having from 4 to 25 carbon atoms, x denotes 1, 2 or 3, and Z x- denotes an x-valent anion of a protic acid. Suitable salts of formula II include diphenyliodosyl hexafluorophosphate and tetrafluoroborate. The compositions may be photopolymerized or they may be thermally polymerized in the presence, as catalyst for the iodosyl salt, of a salt or complex of a d-block transition metal, a stannous salt, an organic peroxide or an activated α-hydroxy compound. The compositions may be used as surface coatings and adhesives, and in the preparation of printing plates, printed circuits and reinforced composites.
Inventors
- 👤 Edward Irving
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:08
CPC Classifications
C; C08; C08G; C08G85/00; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
151 words
A polymerizable composition comprising (A) a cationically polymerizable material, (B) an epoxide-free organic hydroxy compound having at least one alcoholic hydroxyl group and having a molecular weight of more than 500, which is a polyoxyalkylene glycol or triol, a polyepichlorohydrin, a hydroxyl-terminated polycaprolactone, a polymer of a hydroxyalkyl acrylate or a hydroxyalkyl methacrylate, a copolymer of allyl alcohol with a vinyl monomer, a polyvinyl alcohol, a hydroxypropylcellulose, a hydroxyl-containing polyvinyl acetal, a resin obtained by reacting an epoxide resin with an excess of a compound containing one or more groups reactive with epoxide groups, or a phenolic resol, and (C) an aromatic iodosyl salt of formula ##STR11## where R 3 and R 4 , which may be the same or different, each represent a monovalent aromatic radical having from 4 to 25 carbon atoms, x denotes 1, 2 or 3, and Z x- denotes an x-valent anion of a protic acid.
Claim 2
Dependent Claim
151 words
A polymerizable composition comprising (A) a cationically polymerizable material, (B) an epoxide-free organic hydroxy compound having at least one alcoholic hydroxyl group and having a molecular weight of more than 500, which is a polyoxyalkylene glycol or triol, a polyepichlorohydrin, a hydroxyl-terminated polycaprolactone, a polymer of a hydroxyalkyl acrylate or a hydroxyalkyl methacrylate, a copolymer of allyl alcohol with a vinyl monomer, a polyvinyl alcohol, a hydroxypropylcellulose, a hydroxyl-containing polyvinyl acetal, a resin obtained by reacting an epoxide resin with an excess of a compound containing one or more groups reactive with epoxide groups, or a phenolic resol, and (C) an aromatic iodosyl salt of formula ##STR11## where R 3 and R 4 , which may be the same or different, each represent a monovalent aromatic radical having from 4 to 25 carbon atoms, x denotes 1, 2 or 3, and Z x- denotes an x-valent anion of a protic acid.
Claim 3
Dependent Claim
21 words
A composition according to claim 1, in which (A) is a 1,2-epoxide, a phenoplast, an aminoplast, or a cyclic vinyl ether.
Claim 4
Dependent Claim
57 words
A composition according to claim 2, in which (A) is a cycloaliphatic epoxide resin, a polyglycidyl ether of a polyhydric alcohol or polyhydric phenol, a cyclic vinyl ether containing a dihydropyran residue, or a phenol-formaldehyde resol, with the proviso that when (A) and (B) are each a phenol-formaldehyde resol, (A) is not the same resol as (B).
Claim 5
Dependent Claim
40 words
A composition according to claim 1, in which (B) is a copolymer of styrene and allyl alcohol, a phenol-formaldehyde resol, or a resin made by reacting a diglycidyl ether of 2,2-bis(4-hydroxyphenyl)propane with an excess of a monohydric or dihydric phenol.
Claim 6
Dependent Claim
31 words
A composition according to claim 1, in which (B) is present in an amount to provide from 0.001 to 10 equivalents of hydroxy compound per equivalent of cationically polymerizable material (A).
Claim 7
Dependent Claim
19 words
A composition according to claim 1, in which R 3 and R 4 in formula II are the same.
Claim 8
Dependent Claim
20 words
A composition according to claim 1, in which the groups R 3 and R 4 are optionally substituted phenyl groups.
Claim 9
Dependent Claim
52 words
A composition according to claim 1, in which the anion Z x- is derived from an organic carboxylic acid, an organic sulfonic acid Y--SO 3 H, where Y denotes an aliphatic, aromatic or aliphatic-substituted aromatic group, any of which may be substituted by one or more halogen atoms or an inorganic acid.
Claim 10
Dependent Claim
33 words
A composition according to claim 8, in which the anion Z x- is an acetate, trifluoroacetate, methanesulfonate, benzenesulfonate, toluene-p-sulfonate, trifluoromethanesulfonate, fluoride, chloride, bromide, iodate, perchlorate, nitrate, sulfate, hydrogen sulfate, phosphate, or hydrogen phosphate.
Claim 11
Dependent Claim
57 words
A composition according to claim 8, in which the anion Z x- is a pentafluorohydroxoantimonate or is an anion of formula MQ - where M represents an atom of a metal or metalloid, Q represents a halogen atom, and w is an integer of from 4 to 6 and is one more than the valency of M.
Claim 12
Dependent Claim
23 words
A composition according to claim 10, in which the anion Z x- is a hexafluoroantimonate, hexachloroantimonate, hexafluoroarsenate, pentachlorobismuthate, tetrachloroferrate, hexachlorostannate, tetrafluoroborate, or hexafluorophosphate.
Claim 13
Dependent Claim
29 words
A composition according to claim 1, which contains from 0.01% to 10% of the iodosyl salt of formula II, calculated on the weight of the cationically polymerizable material (A).
Claim 14
Dependent Claim
32 words
A photopolymerizable composition according to claim 1, which also contains a photochemical free radical generator, a photosensitizer or a dye which renders the composition more responsive to visible regions of the spectrum.
Claim 15
Dependent Claim
49 words
A heat-polymerizable composition according to claim 1, which also contains, as catalyst for the iodosyl salt, (D) a salt or complex of a d-block transition metal, a stannous salt, an organic peroxide, or an activated alpha-hydroxy compound which forms free radicals on heating to a temperature above 50° C.
Claim 16
Dependent Claim
30 words
A composition according to claim 14, in which (D) is dicumyl peroxide, tert.butyl perbenzoate, tert.butyl peroxide, benzoyl peroxide, or a salt or complex of zinc, cobalt, chromium, iron or copper.
Claim 17
Dependent Claim
15 words
A polymerized composition which is a polymerized product of a composition according to claim 1.
Claim 18
Dependent Claim
84 words
A process for the preparation of polymeric material which comprisies (i) subjecting a composition according to claim 1 to radiation of wavelength such as to activate the iodosyl salt, and/or (ii) subjecting the composition to heat in the presence, as catalyst for the iodosyl salt, of (D) a salt or complex of a d-block transition metal, a stannous salt, an organic peroxide or an activated alpha-hydroxy compound which forms free radicals on heating at a temperature above 50° C. until the composition is polymerized.
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