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US4589999A
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US
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Electrically conductive coating composition of a glycidyl acrylic polymer and a reactive polysiloxane
Assignee: EIDP Inc
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Filing: 1984-12-28
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Granted: 1986-05-20
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Expires: 2004-12-28
Abstract
Abstract A coating composition having a liquid carrier and a binder of a blend of a. an acrylic polymer containing glycidyl groups and b. a crosslinkable polysiloxane having attached to the silicone atoms of its backbone alkyl groups, phenyl groups and hydroxyl groups; the composition contains electrically conductive pigments such as carbon black and graphite to provide an electrically conductive dry film; the composition is used on lead alloy grids of lead acid storage batteries to prolong the life of the battery or to reduce a size and weight of the battery.
Inventors
- 👤 Joseph A. Vasta
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 07:33
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/64; H01M4/66; H01M4/68; C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/068; H01B; H01B1/00; H01B1/20; H01B1/24; H01M4/668; C08; C08L; C08L83/00; C08L83/04; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
219 words
A coating composition comprising about 10-80% by weight of a film forming binder and 20-90% by weight of a liquid carrier, wherein the binder consists essentially of a blend of about a. 20-90% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of about 10-50% by weight, based on the weight of the acrylic polymer, of polymerized glycidyl methacrylate or glycidyl acrylate and 50-90% by weight of polymerized ethylenically unsaturated monomers selected from the group consisting of an alkyl methacrylate having 1-12 carbon atoms, an alkyl acrylate having 1-12 carbon atoms, styrene, alkyl substituted styrenes and mixtures thereof, wherein the acrylic polymer has a weight average molecular weight of about 10,000-100,000, and b. 10-80% by weight, based on the weight of the binder, of a crosslinkable polysiloxane having the following units: ##STR2## where R and R 1 are individually selected from the group consisting of alkyl group having 1-6 carbon atoms, hydroxyl groups and phenyl group and contains a sufficient number of hydroxyl groups to provide a silanol content of about 0.5-7% by weight; wherein the coating composition contains electrically conductive pigments in a pigment to binder weight ratio of about 50/100 to 300/100 and a dry film of the coating composition 25 microns thick has an electrical resistance of about 1-50 ohms.
Claim 2
Dependent Claim
219 words
A coating composition comprising about 10-80% by weight of a film forming binder and 20-90% by weight of a liquid carrier, wherein the binder consists essentially of a blend of about a. 20-90% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of about 10-50% by weight, based on the weight of the acrylic polymer, of polymerized glycidyl methacrylate or glycidyl acrylate and 50-90% by weight of polymerized ethylenically unsaturated monomers selected from the group consisting of an alkyl methacrylate having 1-12 carbon atoms, an alkyl acrylate having 1-12 carbon atoms, styrene, alkyl substituted styrenes and mixtures thereof, wherein the acrylic polymer has a weight average molecular weight of about 10,000-100,000, and b. 10-80% by weight, based on the weight of the binder, of a crosslinkable polysiloxane having the following units: ##STR2## where R and R 1 are individually selected from the group consisting of alkyl group having 1-6 carbon atoms, hydroxyl groups and phenyl group and contains a sufficient number of hydroxyl groups to provide a silanol content of about 0.5-7% by weight; wherein the coating composition contains electrically conductive pigments in a pigment to binder weight ratio of about 50/100 to 300/100 and a dry film of the coating composition 25 microns thick has an electrical resistance of about 1-50 ohms.
Claim 3
Dependent Claim
22 words
Coating composition of claim 1 in which the electrically conductive pigments are a mixture of carbon black pigment and finely divided graphite.
Claim 4
Dependent Claim
38 words
The coating composition of claim 2 in which the acrylic polymer consists essentially of about 10-30% by weight of glycidyl methacrylate, 10-20% by weight of styrene, 50-60% by weight of butyl methacrylate, 5-20% by weight of butyl acrylate.
Claim 5
Dependent Claim
36 words
The coating composiion of claim 3 in which the acrylic polymer consists of 20% by weight of glycidyl methacrylate, 15% by weight styrene, 55% by weight of butyl methacrylate and 10% by weight of butyl acrylate.
Claim 6
Dependent Claim
21 words
The coating composition of claim 2 containing about 0.75-3% by weight, based on the weight of the composition of acetyl acetone.
Claim 7
Dependent Claim
205 words
The coating composition of claim 1 which comprises about 40-70% by weight of a film forming binder and 30-60% by weight of an organic solvent for the binder; in which the binder consists essentially of about a. 50-75% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of about (1) 10-30% by weight, based on the weight of the acrylic polymer, of glycidyl methacrylate, (2) 10-20% by weight, based on the weight of the acrylic polymer, of styrene, (3) 50-60% by weight, based on the weight of the acrylic polymer, of butyl methacrylate and (4) 5-20% by weight, based on the weight of the acrylic polymer of butyl acrylate and b. 25-50% by weight, based on the weight of the binder, of a polysiloxane having the following units: ##STR3## where R and R 1 are individually selected from the group consisting of methyl, propyl, amyl, hydroxyl and phenyl and the polysiloxane contains a sufficient number of hydroxyl groups to provide a silanol content of about 1.9-3.0% wherein the electrically conductive pigments comprise a blend of carbon black pigment and finely divided graphite and a dry film of the coating 25 microns thick has an electrical resistance of 5-20 ohms.
Claim 8
Dependent Claim
33 words
An improved lead acid storage battery having lead alloy grids wherein the improvement comprises having the grids coated with a 10-200 micron thick layer of the dried and cured composition of claim 1.
Claim 9
Dependent Claim
51 words
A process for coating lead alloy grids for use in lead-acid electric storage batteries which comprises (1) applying a thin coating of an amino silane to the grid and (2) applying a coating of the composition of claim 1 and drying the composition to provide a film about 10-150 microns thick.
Claim 10
Dependent Claim
22 words
The process of claim 8 in which the lead alloy grid is of an antimony lead alloy or a calcium lead alloy.
Claim 11
Dependent Claim
14 words
The process of claim 9 in which the amino silane is gamma aminopropyl trimethoxysilane.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-05-19 | 1989-11-18 | 1990-05-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-05-19 | 1993-11-18 | 1994-05-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-05-19 | 1997-11-18 | 1998-05-20 | $7700.00 | Window Closed / Lapsed |