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US4098967A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochemical system using conductive plastic

Assignee: GNB Inc
•
Filing: 1975-01-20
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Granted: 1978-07-04
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Expires: 1995-01-20
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Abstract

Abstract In a conductor-electrolyte-active material electrochemical environment, the conductor is protected against corrosion by that portion of the conductor in contact with the electrolyte and active material being formed of plastic filled with vitreous carbon. Adequate conductivity is obtained by finely dividing the vitreous carbon and loading the plastic with 40%-80% carbon by volume. The filled plastic is particularly effective as a bipolar plate substrate. A layer of lead-antimony foil bonded to the carbon-filled plastic provides a good surface for adhering active materials. A lead sheet can be bonded to the substrate to define a low resistance terminal. Forming the edges of the substrate of thicker sections of unfilled -- hence nonconductive -- plastic allows the plates to be stacked to define a battery.

Inventors

  • 👤 Royce E. Biddick
  • 👤 Richard J. Rubischko

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 11:11
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/42; H01M6/46; H01M6/48; H01M10/00; H01M10/06; H01M10/18; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 117 words
A bipolar electrode-container plate for use in storage batteries comprising, in combination, a planar central substrate surrounded by border portions, said substrate and said border portions being formed of a thermoplastic resistant to electrolyte and capable of being filled, said substrate being filled with electrically conductive material leaving said border portions nonconductive, an active electrode material overlying, supported by and in electrical contact with said substrate within said border portions, a layer of metal foil bonded to said substrate and interposed between said substrate and said active material, and said border portions being proportioned so as to interfit with other similar plates leaving space for separators and electrolyte within the container periphery defined by the border portions.
Claim 2
Dependent Claim 117 words
A bipolar electrode-container plate for use in storage batteries comprising, in combination, a planar central substrate surrounded by border portions, said substrate and said border portions being formed of a thermoplastic resistant to electrolyte and capable of being filled, said substrate being filled with electrically conductive material leaving said border portions nonconductive, an active electrode material overlying, supported by and in electrical contact with said substrate within said border portions, a layer of metal foil bonded to said substrate and interposed between said substrate and said active material, and said border portions being proportioned so as to interfit with other similar plates leaving space for separators and electrolyte within the container periphery defined by the border portions.
Claim 3
Dependent Claim 14 words
The combination of claim 1 in which said foil layer is a lead-antimony alloy.
Claim 4
Dependent Claim 19 words
The combination of claim 2 in which the content of antimony in said alloy is about 0.2% by weight.
Claim 5
Dependent Claim 104 words
A bipolar electrode-container plate for use in storage batteries comprising, in combination, a planar central substrate surrounded by border portions, said substrate and said border portions being formed of a thermoplastic resistant to electrolyte and capable of being filled, said substrate being filled with electrically conductive material formed of finely divided vitreous carbon leaving said border portions nonconductive, an active electrode material overlying, supported by and in electrical contact with said substrate within said border portions, said border portions being proportioned so as to interfit with other similar plates leaving space for separators and electrolyte within the container periphery defined by the border portions.
Claim 6
Dependent Claim 104 words
A bipolar electrode-container plate for use in storage batteries comprising, in combination, a planar central substrate surrounded by border portions, said substrate and said border portions being formed of a thermoplastic resistant to electrolyte and capable of being filled, said substrate being filled with electrically conductive material formed of finely divided vitreous carbon leaving said border portions nonconductive, an active electrode material overlying, supported by and in electrical contact with said substrate within said border portions, said border portions being proportioned so as to interfit with other similar plates leaving space for separators and electrolyte within the container periphery defined by the border portions.
Claim 7
Dependent Claim 30 words
The combination of claim 4 in which said vitreous carbon consists of particles sized from submicron up to -60 mesh, and the filled thermoplastic is from 40% to 60% carbon.
Claim 8
Dependent Claim 21 words
The combination of claim 4 in which said thermoplastic is selected from the group consisting of polyvinylidene fluoride and polyphenylene oxide.
Claim 9
Dependent Claim 155 words
A secondary storage battery comprising, in combination, a plurality of bipolar electrode-container plates stacked side-by-side, a plurality of separators with one separator being sandwiched between adjacent ones of each of said plates, electrolyte contained between adjacent ones of said plates and surrounding said separators, each of said plates having a planar electrically conductive substrate surrounded by nonconductive border portions, said border portions of said plates being joined to define a container for the battery with regions between said substrate and within said border portions containing said electrolyte and said separators, an active electrode material overlying, supported by and in electrical contact with said substrates of the plates, a layer of metal foil bonded to said substrate and interposed between said substrate and said active material, the border portions and substrate of said plates being integrally formed of thermoplastic, and the substrate of said plates being filled with electrically conductive material leaving said border portions nonconductive.
Claim 10
Dependent Claim 155 words
A secondary storage battery comprising, in combination, a plurality of bipolar electrode-container plates stacked side-by-side, a plurality of separators with one separator being sandwiched between adjacent ones of each of said plates, electrolyte contained between adjacent ones of said plates and surrounding said separators, each of said plates having a planar electrically conductive substrate surrounded by nonconductive border portions, said border portions of said plates being joined to define a container for the battery with regions between said substrate and within said border portions containing said electrolyte and said separators, an active electrode material overlying, supported by and in electrical contact with said substrates of the plates, a layer of metal foil bonded to said substrate and interposed between said substrate and said active material, the border portions and substrate of said plates being integrally formed of thermoplastic, and the substrate of said plates being filled with electrically conductive material leaving said border portions nonconductive.
Claim 11
Dependent Claim 14 words
The combination of claim 7 in which said foil layer is a lead-antimony alloy.
Claim 12
Dependent Claim 19 words
The combination of claim 8 in which the content of antimony is said alloy is about 0.2% by weight.
Claim 13
Dependent Claim 143 words
A secondary storage battery comprising, in combination, a plurality or bipolor electrode-container plates stacked side-by-side, a plurality of separators with one separator being sandwiched between adjacent ones of each of said plates, electrolyte contained between adjacent ones of said plates and surrounding said separators, each of said plates having a planar electrically conductive substrate surrounded by nonconductive border portions, said border portions of said plates being joined to define a container for the battery with regions between said substrate and within said border portions containing said electrolyte and said separators, an active electrode material overlying, supported by and in electrical contact with said substrates of the plates, the border portions and substrate of said plates being integrally formed of thermoplastic, and the substrate of said plates being filled with electrically conductive material formed of finely divided vitreous carbon leaving said border portions nonconductive.
Claim 14
Dependent Claim 143 words
A secondary storage battery comprising, in combination, a plurality or bipolor electrode-container plates stacked side-by-side, a plurality of separators with one separator being sandwiched between adjacent ones of each of said plates, electrolyte contained between adjacent ones of said plates and surrounding said separators, each of said plates having a planar electrically conductive substrate surrounded by nonconductive border portions, said border portions of said plates being joined to define a container for the battery with regions between said substrate and within said border portions containing said electrolyte and said separators, an active electrode material overlying, supported by and in electrical contact with said substrates of the plates, the border portions and substrate of said plates being integrally formed of thermoplastic, and the substrate of said plates being filled with electrically conductive material formed of finely divided vitreous carbon leaving said border portions nonconductive.
Claim 15
Dependent Claim 30 words
The combination of claim 10 in which said vitreous carbon consists of particles sized from submicron up to -60 mesh, and the filled thermoplastic is from 40% to 60% carbon.
Claim 16
Dependent Claim 21 words
The combination of claim 10 in which said thermoplastic is selected from the group consisting of polyvinylidene fluoride and polyphenylene oxide.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-03 1982-01-02 1982-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-03 1986-01-02 1986-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-03 1990-01-02 1990-07-04 $7700.00 Window Closed / Lapsed

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