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US4588520A Expired / Lapsed US ⏱️ 0.0 years remaining

Powder pressed thermoelectric materials and method of making same

Assignee: Energy Conversion Devices Inc
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Filing: 1982-09-03
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Granted: 1986-05-13
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Expires: 2002-09-03
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Abstract

Abstract New and improved compacted or powder pressed materials for thermoelectric applications include a body formed from compacted powder material including at least bismuth and tellurium and at least one highly electrically conductive phase. The materials are made in accordance with the general method of the present invention by forming a particulate mixture containing the constituent elements of a first compound including at least bismuth and tellurium and the constituent elements of a second compound capable of forming at least one highly electrically conductive phase, and thereafter, compressing at least a portion of said particulate mixture to form a compacted body of the material. In accordance with a first preferred embodiment, the first and second compounds are first separately prepared from their respective constituent elements. The first and second compounds are then combined and heated to form a melt. Thereafter, the melt is cooled to solid material form and then crushed to form the particulate mixture. In accordance with a second preferred embodiment, a melt is first formed from the second compound and the constituent elements of the first compound. The melt is then cooled to solid material form and then crushed to form the particulate mixture. In accordance with a further embodiment of the present invention, the first and second compounds are first separately prepared from their respective constituent elements and then separately crushed into particulate form prior to forming the particulate mixture.

Inventors

  • 👤 Tumkur S. Jayadev
  • 👤 On Van Nguyen
  • 👤 Jaime M. Reyes
  • 👤 Helen Davis
  • 👤 Michael W. Putty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:38
CPC Classifications
C; C22; C22C; C22C1/00; C22C1/04; H; H10; H10N; H10N10/00; H10N10/01; H10N10/80; H10N10/85; H10N10/851; H10N10/852

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 64 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and tellurium, at least one highly conductive phase consisting essentially of silver and tellurium, and tellurium iodide dopant, said material containing about 10 atomic percent bismuth, about 30 atomic percent antimony, about 60 atomic percent tellurium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent tellurium iodide.
Claim 2
Dependent Claim 64 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and tellurium, at least one highly conductive phase consisting essentially of silver and tellurium, and tellurium iodide dopant, said material containing about 10 atomic percent bismuth, about 30 atomic percent antimony, about 60 atomic percent tellurium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent tellurium iodide.
Claim 3
Dependent Claim 68 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and selenium, at least one highly conductive phase consisting essentially of silver and tellurium, and cadmium chloride dopant, said material containing about 40 atomic percent bismuth, about 42 to 54 atomic percent tellurium, and 18 to 6 atomic percent selenium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent cadmium chloride.
Claim 4
Dependent Claim 68 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and selenium, at least one highly conductive phase consisting essentially of silver and tellurium, and cadmium chloride dopant, said material containing about 40 atomic percent bismuth, about 42 to 54 atomic percent tellurium, and 18 to 6 atomic percent selenium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent cadmium chloride.
Claim 5
Dependent Claim 21 words
A material as defined in claim 2 wherein said body further includes antimony in an amount up to 1 atomic percent.
Claim 6
Dependent Claim 68 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and selenium, at least one highly conductive phase consisting essentially of silver and tellurium, and tellurium iodide depant, said material containing about 40 atomic percent bismuth, about 42 to 54 atomic percent tellurium, and 18 to 6 atomic percent selenium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent tellurium iodide.
Claim 7
Dependent Claim 68 words
A compacted powder material body for thermoelectric applications, said material comprising bismuth, tellurium, and selenium, at least one highly conductive phase consisting essentially of silver and tellurium, and tellurium iodide depant, said material containing about 40 atomic percent bismuth, about 42 to 54 atomic percent tellurium, and 18 to 6 atomic percent selenium, up to 1.0 atomic percent silver, and up to about 0.15 atomic percent tellurium iodide.
Claim 8
Dependent Claim 21 words
A material as defined in claim 4 wherein said body further includes antimony in an amount up to 1 atomic percent.

References Cited (Backward Citations)

US2957937A Cited
US2995613A Cited
US3310493A Cited
US3228805A Cited
US3414405A Cited
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US4178415A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-05-12 1989-11-11 1990-05-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-05-12 1993-11-11 1994-05-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-05-12 1997-11-11 1998-05-13 $7700.00 Window Closed / Lapsed

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