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Dielectric compositions

Assignee: CERAMIC DIELECTRICS Inc A CORP OF
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Filing: 1985-03-18
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Granted: 1986-04-15
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Expires: 2005-03-18
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Abstract

Abstract A composition for forming a densified dielectric body at low firing temperatures comprising a mixture of particles consisting essentially of (a) 95.5-99.4% finely divided wt. of a mixture of metal oxides, metal oxide precursors or polynary oxide reaction products thereof in molar proportions corresponding to the formula (Sr.sub.x Pb.sub.1-x TiO.sub.3).sub.a (PbMg.sub.r W.sub.s O.sub.3).sub.b, and (b) 4.5-0.6% wt. of a mixture of metal oxides or precursors thereof consisting essentially of (1) a binary oxide of a transition metal selected from the group consisting of Co, Ni, Cr, Mn and mixtures thereof, (2) Cd titanate, Zn titanate or mixtures thereof, and (3) a polynary oxide selected from the group consisting of Cd zirconate, Zn zirconate, Cd stannate, Zn stannate and mixtures thereof.

Inventors

  • 👤 Gene L. Thomas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:47
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1218; C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/47; C04B35/495; C04B35/497; C04B35/499; H01G4/1254

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 183 words
A composition for forming a densified dielectric body at low firing temperatures comprising a mixture of finely divided particles consisting essentially of (a) 95.5-99.4% wt. of a mixture of metal oxide, metal oxide precursors of polynary oxide reaction products thereof in molar proportions corresponding to the formula: ______________________________________ (Sr.sub.x Pb.sub.1-x TiO.sub.3).sub.a (PbMg.sub.r W.sub.s O.sub.3).sub.b, wherein x = 0-0.3 r = 0.45-0.55 a = 0.45-0.6 s = 0.55-0.45 and b = 1.55-0.4 and Σ(r + s) = 1, and Σ(a + b) = 1. ______________________________________ (b) 4.5-0.6% wt. of a mixture of metal oxides or precursors thereof consisting essentially of (1) 0.1-1.0% wt. of a binary oxide of a transition metal selected from the group consisting of Co, Ni, Cr, Mn and mixtures thereof, (2) 0.25-1.5% wt. of Cd titanate, Zn titanate or mixtures thereof, and (3) 0.25-2.0% wt. of a polynary oxide selected from the group consisting of Cd zirconate, Zn zirconate, Cd stannate, Zn stannate and mixtures thereof, substantially all the partices being less than 10 μm in largest dimension and having a surface area of at least 0.5 m 2 /g.
Claim 2
Dependent Claim 183 words
A composition for forming a densified dielectric body at low firing temperatures comprising a mixture of finely divided particles consisting essentially of (a) 95.5-99.4% wt. of a mixture of metal oxide, metal oxide precursors of polynary oxide reaction products thereof in molar proportions corresponding to the formula: ______________________________________ (Sr.sub.x Pb.sub.1-x TiO.sub.3).sub.a (PbMg.sub.r W.sub.s O.sub.3).sub.b, wherein x = 0-0.3 r = 0.45-0.55 a = 0.45-0.6 s = 0.55-0.45 and b = 1.55-0.4 and Σ(r + s) = 1, and Σ(a + b) = 1. ______________________________________ (b) 4.5-0.6% wt. of a mixture of metal oxides or precursors thereof consisting essentially of (1) 0.1-1.0% wt. of a binary oxide of a transition metal selected from the group consisting of Co, Ni, Cr, Mn and mixtures thereof, (2) 0.25-1.5% wt. of Cd titanate, Zn titanate or mixtures thereof, and (3) 0.25-2.0% wt. of a polynary oxide selected from the group consisting of Cd zirconate, Zn zirconate, Cd stannate, Zn stannate and mixtures thereof, substantially all the partices being less than 10 μm in largest dimension and having a surface area of at least 0.5 m 2 /g.
Claim 3
Dependent Claim 16 words
The composition of claim 1 in which a major proportion of the components have been calcined.
Claim 4
Dependent Claim 15 words
The composition of claim 2 in which the (a) components have been calcined in air.
Claim 5
Dependent Claim 14 words
The composition of claim 1 in which (a) is 0.5-0.55 and (b) is 0.5-0.45.
Claim 6
Dependent Claim 17 words
The composition of claim 1 in which the titanate (2) of component (b) is ZnTiO 3 .
Claim 7
Dependent Claim 18 words
The composition of claim 1 in which the polynary oxide (3) of component (b) is CdSnO 3 .
Claim 8
Dependent Claim 23 words
The composition of claim 1 in which the binary metal oxides of (b) are 0.05-0.5% by weight each of MnO 2 and CoO.
Claim 9
Dependent Claim 52 words
The composition of claim 1 formed from the following metal oxides in the indicated weight proportions: PbO: 60.6 MgCO 3 : 6.5 TiO 2 : 11.0 WO 3 : 15.7 SrTiO 3 : 3.25 MnO 2 : 0.07 CoO: 0.22 PbTiO 3 : 1.2 ZnTiO 3 : 0.5 CdSnO 3 : 1.0.
Claim 10
Dependent Claim 27 words
The composition of claim 1 in which the mixture of finely divided solids is dispersed in an organic medium comprising a polymeric binder dissolved in organic solvent.
Claim 11
Dependent Claim 22 words
The composition of claim 9 in which the organic solvent is a volatile nonaqueous solvent and the dispersion is of castable consistency.
Claim 12
Dependent Claim 21 words
A dielectric green tape comprising a layer of the composition of claim 10 from which the volatile solvent has been removed.
Claim 13
Dependent Claim 41 words
The composition of claim 9 in which the organic solvent is a solution comprising a resin and thixotropic agent dissolved in a solvent having a boiling point of 130°-350° C. and the dispersion is of paste consistency suitable for screen printing.

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