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US4577931A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal composition

Assignee: Epson Corp
•
Filing: 1983-05-24
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Granted: 1986-03-25
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Expires: 2003-05-24
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Abstract

Abstract Liquid crystal display devices including liquid crystal compositions of cyclohexanecarboxylic esters and esters having an acyloxyl group have excellent time-sharing characteristics, low duty ratio and driving voltage.

Inventors

  • 👤 Bunzo Kiyonaga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:15
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/42

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 160 words
A liquid crystal composition comprising at least one compound of each of formulas (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR11## where R 1 is a straight-chain alkyl group having 2 to 6 atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 2
Dependent Claim 160 words
A liquid crystal composition comprising at least one compound of each of formulas (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR11## where R 1 is a straight-chain alkyl group having 2 to 6 atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 3
Dependent Claim 34 words
A liquid crystal composition as described in claim 1, wherein said compounds of formula (1) comprise compounds wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 4
Dependent Claim 93 words
A liquid crystal composition as described in claim 1, further comprising at least one of the compounds of formulas (4) and (5): ##STR12## where R 6 is a straight-chain alkyl group having 2 to 4 carbon atoms; R 7 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 8 is a straight chain alkyl group having 2 to 7 carbon atoms, and when present about 3 to 12 weight percent of compounds of formula (4) and when present about 5 to 15 weight percent of compounds of formula (5).
Claim 5
Dependent Claim 34 words
A liquid crystal composition as described in claim 3, wherein said compounds of formula (1) comprise compounds wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 6
Dependent Claim 42 words
A liquid crystal composition as described in claim 2, wherein from about 34 to about 100 weight percent of compounds of formula (1) are those wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 7
Dependent Claim 45 words
A liquid crystal composition as described in claim 2, wherein R 1 of the compound of formula (1) is selected from the group consisting of C 3 H 7 ; C 4 H 9 ; C 5 H 11 and C 6 H 13 .
Claim 8
Dependent Claim 40 words
A liquid crystal composition as described in claim 6, wherein R 2 of the compound of formula (1) is selected from the group consisting of C 5 H 11 ; C 6 H 13 and C 2 H 5 .
Claim 9
Dependent Claim 24 words
A liquid crystal composition as described in claim 2, wherein R 3 of the compound of formula (2) is C 5 H 11 .
Claim 10
Dependent Claim 35 words
A liquid crystal composition as described in claim 2, wherein R 4 of the compound of formula (2) is selected from the group consisting of C 3 H 7 and C 5 H 11 .
Claim 11
Dependent Claim 40 words
A liquid crystal composition as described in claim 6, wherein R 5 of the compound of formula (3) is selected from the group consisting of C 2 H 5 ; C 3 H 7 and C 4 H 9 .
Claim 12
Dependent Claim 35 words
A liquid crystal composition as described in claim 8, wherein R 9 of the compound of formula (6) is selected from the group consisting of C 2 H 5 and C 4 H 9 .
Claim 13
Dependent Claim 47 words
A liquid crystal composition as described in claim 3, comprising about 58 weight percent of compounds of formula (1), about 28 weight percent of compounds of formula (2), about 10.5 weight percent of compounds of formula (3), and about 3.5 weight percent of compounds of formula (4).
Claim 14
Dependent Claim 47 words
A liquid crystal composition as described in claim 3, comprising about 51.0 weight percent of compounds of formula (1), about 22.0 weight percent of compounds of formula (2), about 17.0 weight percent of compounds of formula (3), and about 10.0 weight percent of compounds of formula (4).
Claim 15
Dependent Claim 56 words
A liquid crystal composition as described in claim 3, comprising about 45.0 weight percent of compounds of formula (1), about 22.0 weight percent of compounds of formula (2), about 17.0 weight percent of compounds of formula (3), about 8.0 weight percent of compounds of formula (4), and about 8.0 weight percent of compounds of formula (5).
Claim 16
Dependent Claim 38 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio of about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 1.
Claim 17
Dependent Claim 31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 1.
Claim 18
Dependent Claim 39 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 2.
Claim 19
Dependent Claim 31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 2.
Claim 20
Dependent Claim 39 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 3.
Claim 21
Dependent Claim 31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 3.
Claim 22
Dependent Claim 219 words
A liquid crystal display device comprising two opposed substantially parallel substrates with liquid crystal electrodes selectively disposed on the interior surface thereof, a liquid crystal composition in the space between the substrates, time-sharing circuit means for generating time-sharing signals to be selectively applied to the liquid crystal electrodes for operating a liquid crystal display in a time-sharing mode, the liquid crystal composition comprising at least one compound of each of formula (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR13## wherein R 1 is a straight-chain alkyl group having 2 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 23
Dependent Claim 219 words
A liquid crystal display device comprising two opposed substantially parallel substrates with liquid crystal electrodes selectively disposed on the interior surface thereof, a liquid crystal composition in the space between the substrates, time-sharing circuit means for generating time-sharing signals to be selectively applied to the liquid crystal electrodes for operating a liquid crystal display in a time-sharing mode, the liquid crystal composition comprising at least one compound of each of formula (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR13## wherein R 1 is a straight-chain alkyl group having 2 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 24
Dependent Claim 36 words
A liquid crystal display device as set forth in claim 21, wherein said formula (1) compounds are those in which said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 25
Dependent Claim 95 words
A liquid crystal display device as set forth in claim 21, further containing at least one of the compounds represented by formulas (4) and (5): ##STR14## wherein R 6 is a straight-chain alkyl group having 2 to 4 carbon atoms; R 7 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 8 is a straight-chain alkyl group having 2 to 7 carbon atoms, and when present about 3 to 12 weight percent of compounds of formula (4) and when present about 5 to 15 weight percent of compounds of formula (5).
Claim 26
Dependent Claim 37 words
A liquid crystal display device as set forth in claim 21, wherein said time-sharing circuit means operates with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature.
Claim 27
Dependent Claim 29 words
A liquid crystal display device as set forth in claim 21, wherein said time-sharing circuit means operates with a duty ratio in the range of about 1/32 to 1/48.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-24 1989-09-23 1990-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-24 1993-09-23 1994-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-24 1997-09-23 1998-03-25 $7700.00 Window Closed / Lapsed

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