US4577931A
Expired / Lapsed
US
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Liquid crystal composition
Assignee: Epson Corp
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Filing: 1983-05-24
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Granted: 1986-03-25
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Expires: 2003-05-24
Abstract
Abstract Liquid crystal display devices including liquid crystal compositions of cyclohexanecarboxylic esters and esters having an acyloxyl group have excellent time-sharing characteristics, low duty ratio and driving voltage.
Inventors
- 👤 Bunzo Kiyonaga
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 13:15
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/42
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
160 words
A liquid crystal composition comprising at least one compound of each of formulas (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR11## where R 1 is a straight-chain alkyl group having 2 to 6 atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 2
Dependent Claim
160 words
A liquid crystal composition comprising at least one compound of each of formulas (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR11## where R 1 is a straight-chain alkyl group having 2 to 6 atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 3
Dependent Claim
34 words
A liquid crystal composition as described in claim 1, wherein said compounds of formula (1) comprise compounds wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 4
Dependent Claim
93 words
A liquid crystal composition as described in claim 1, further comprising at least one of the compounds of formulas (4) and (5): ##STR12## where R 6 is a straight-chain alkyl group having 2 to 4 carbon atoms; R 7 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 8 is a straight chain alkyl group having 2 to 7 carbon atoms, and when present about 3 to 12 weight percent of compounds of formula (4) and when present about 5 to 15 weight percent of compounds of formula (5).
Claim 5
Dependent Claim
34 words
A liquid crystal composition as described in claim 3, wherein said compounds of formula (1) comprise compounds wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 6
Dependent Claim
42 words
A liquid crystal composition as described in claim 2, wherein from about 34 to about 100 weight percent of compounds of formula (1) are those wherein said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 7
Dependent Claim
45 words
A liquid crystal composition as described in claim 2, wherein R 1 of the compound of formula (1) is selected from the group consisting of C 3 H 7 ; C 4 H 9 ; C 5 H 11 and C 6 H 13 .
Claim 8
Dependent Claim
40 words
A liquid crystal composition as described in claim 6, wherein R 2 of the compound of formula (1) is selected from the group consisting of C 5 H 11 ; C 6 H 13 and C 2 H 5 .
Claim 9
Dependent Claim
24 words
A liquid crystal composition as described in claim 2, wherein R 3 of the compound of formula (2) is C 5 H 11 .
Claim 10
Dependent Claim
35 words
A liquid crystal composition as described in claim 2, wherein R 4 of the compound of formula (2) is selected from the group consisting of C 3 H 7 and C 5 H 11 .
Claim 11
Dependent Claim
40 words
A liquid crystal composition as described in claim 6, wherein R 5 of the compound of formula (3) is selected from the group consisting of C 2 H 5 ; C 3 H 7 and C 4 H 9 .
Claim 12
Dependent Claim
35 words
A liquid crystal composition as described in claim 8, wherein R 9 of the compound of formula (6) is selected from the group consisting of C 2 H 5 and C 4 H 9 .
Claim 13
Dependent Claim
47 words
A liquid crystal composition as described in claim 3, comprising about 58 weight percent of compounds of formula (1), about 28 weight percent of compounds of formula (2), about 10.5 weight percent of compounds of formula (3), and about 3.5 weight percent of compounds of formula (4).
Claim 14
Dependent Claim
47 words
A liquid crystal composition as described in claim 3, comprising about 51.0 weight percent of compounds of formula (1), about 22.0 weight percent of compounds of formula (2), about 17.0 weight percent of compounds of formula (3), and about 10.0 weight percent of compounds of formula (4).
Claim 15
Dependent Claim
56 words
A liquid crystal composition as described in claim 3, comprising about 45.0 weight percent of compounds of formula (1), about 22.0 weight percent of compounds of formula (2), about 17.0 weight percent of compounds of formula (3), about 8.0 weight percent of compounds of formula (4), and about 8.0 weight percent of compounds of formula (5).
Claim 16
Dependent Claim
38 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio of about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 1.
Claim 17
Dependent Claim
31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 1.
Claim 18
Dependent Claim
39 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 2.
Claim 19
Dependent Claim
31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 2.
Claim 20
Dependent Claim
39 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature, including a liquid crystal composition as described in claim 3.
Claim 21
Dependent Claim
31 words
A liquid crystal display device adapted for time-sharing operation with a duty ratio in the range of about 1/32 to 1/48, including a liquid crystal composition as described in claim 3.
Claim 22
Dependent Claim
219 words
A liquid crystal display device comprising two opposed substantially parallel substrates with liquid crystal electrodes selectively disposed on the interior surface thereof, a liquid crystal composition in the space between the substrates, time-sharing circuit means for generating time-sharing signals to be selectively applied to the liquid crystal electrodes for operating a liquid crystal display in a time-sharing mode, the liquid crystal composition comprising at least one compound of each of formula (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR13## wherein R 1 is a straight-chain alkyl group having 2 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 23
Dependent Claim
219 words
A liquid crystal display device comprising two opposed substantially parallel substrates with liquid crystal electrodes selectively disposed on the interior surface thereof, a liquid crystal composition in the space between the substrates, time-sharing circuit means for generating time-sharing signals to be selectively applied to the liquid crystal electrodes for operating a liquid crystal display in a time-sharing mode, the liquid crystal composition comprising at least one compound of each of formula (1) and (2), and at least one of the compounds of formulas (3) and (6): ##STR13## wherein R 1 is a straight-chain alkyl group having 2 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 4 is a straight-chain alkyl group having 1 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 2 to 8 carbon atoms, and R 9 is a straight-chain alkyl group having 2 to 8 carbon atoms, and including about 40 to 65 weight percent of compounds of formula (1), about 20 to 30 weight percent of compounds of formula (2), and when present about 7 to 20 weight percent of compounds of formula (3) and when present about 7 to 20 weight percent of compounds of formula (6).
Claim 24
Dependent Claim
36 words
A liquid crystal display device as set forth in claim 21, wherein said formula (1) compounds are those in which said groups R 1 and R 2 have a total of eight to ten carbon atoms.
Claim 25
Dependent Claim
95 words
A liquid crystal display device as set forth in claim 21, further containing at least one of the compounds represented by formulas (4) and (5): ##STR14## wherein R 6 is a straight-chain alkyl group having 2 to 4 carbon atoms; R 7 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 8 is a straight-chain alkyl group having 2 to 7 carbon atoms, and when present about 3 to 12 weight percent of compounds of formula (4) and when present about 5 to 15 weight percent of compounds of formula (5).
Claim 26
Dependent Claim
37 words
A liquid crystal display device as set forth in claim 21, wherein said time-sharing circuit means operates with a duty ratio down to about 1/32 at a voltage of about 10 V or below at room temperature.
Claim 27
Dependent Claim
29 words
A liquid crystal display device as set forth in claim 21, wherein said time-sharing circuit means operates with a duty ratio in the range of about 1/32 to 1/48.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-03-24 | 1989-09-23 | 1990-03-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-03-24 | 1993-09-23 | 1994-03-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-03-24 | 1997-09-23 | 1998-03-25 | $7700.00 | Window Closed / Lapsed |