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Process for activating substrates for electroless metallization

Assignee: Bayer AG
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Filing: 1984-06-27
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Granted: 1986-03-11
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Expires: 2004-06-27
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Abstract

Abstract Complex compounds of elements of sub-groups 1 and 8 of the periodic table in oxidation stages 1-4 with unsaturated ketones of the formula ##STR1## wherein R 1 and R 4 denote alkyl, cycloalkyl or aryl and R 2 and R 3 denote hydrogen or alkyl, are outstandingly suitable for activating substrate surfaces for electroless metallization since these complexes are distinguished by a high storage stability. The palladium complexes of but-3-en-2-one and hept-3-en-2-one are preferred.

Inventors

  • 👤 Kirkor Sirinyan
  • 👤 Rudolf Merten
  • 👤 Henning Giesecke
  • 👤 Gerhard D. Wolf

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 18:50
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 91 words
Process for the activation of substrate surfaces for electroless metallisation by means of solutions or dispersions of complex compounds of Pd, Pt, Ag or Au, said solutions or dispersions having high stability on storage, characterized in that complex compounds of these elements in oxidation stages 1-4 with unsaturated ketones of the formula ##STR3## wherein, independently of one another, R 1 denotes a C 1 -C 6 -alkyl R 2 and R 3 denote hydrogen or C 1 -C 4 -alkyl, and R 4 denotes H or C 1 -C 6 -alkyl.
Claim 2
Dependent Claim 91 words
Process for the activation of substrate surfaces for electroless metallisation by means of solutions or dispersions of complex compounds of Pd, Pt, Ag or Au, said solutions or dispersions having high stability on storage, characterized in that complex compounds of these elements in oxidation stages 1-4 with unsaturated ketones of the formula ##STR3## wherein, independently of one another, R 1 denotes a C 1 -C 6 -alkyl R 2 and R 3 denote hydrogen or C 1 -C 4 -alkyl, and R 4 denotes H or C 1 -C 6 -alkyl.
Claim 3
Dependent Claim 25 words
Process according to claim 1, characterised in that the solutions or dispersions are used without additional complexing agents of the series of donors and acceptors.
Claim 4
Dependent Claim 20 words
Process according to claim 1, characterised in that the complex compounds are used in concentrations of 0.1-3.0 g/liter of solvent.
Claim 5
Dependent Claim 26 words
Process according to claim 1, characterised in that in activated substrates are introduced into wet chemical metallising baths, especially Cu, Ni, Co, Ag and Au baths.
Claim 6
Dependent Claim 24 words
Process according to claim 1, characterised in that the concentration of the complex solutions in the activation baths is monitored continuously with a photometer.
Claim 7
Dependent Claim 15 words
Process according to claim 1, characterised in that the palladium complex of n-but-3-en-2-one is used.

References Cited (Backward Citations)

US3398168A Cited
US3993807A Cited
EP0043485A1 Cited
US4472458A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-10 1989-09-09 1990-03-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-10 1993-09-09 1994-03-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-10 1997-09-09 1998-03-11 $7700.00 Window Closed / Lapsed

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