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US4574055A Expired / Lapsed US ⏱️ 0.0 years remaining

Resistor compositions

Assignee: Shoei Chemical Inc
•
Filing: 1984-12-12
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Granted: 1986-03-04
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Expires: 2004-12-12
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Abstract

Abstract A resistor composition comprising conductive particles, a glass frit and a vehicle in which RuO2 particles coated with a polynary oxide of Bi and/or Pb and Ru are employed and, by using the surface-coated RuO2, the composition can provide readily a improved resistor having a advantageous combination of properties, particularly a very small absolute TCR and high voltage stability throughout a wide resistance range. The produced resistor can be successfully laser-trimmed without adversely affecting the properties thereof.

Inventors

  • 👤 Eiichi Asada
  • 👤 Toshio Inokuma
  • 👤 Mikio Yamazoe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 06:27
CPC Classifications
H; H01; H01C; H01C17/00; H01C17/06; H01C17/065; H01C17/06506; H01C17/06513; H01C17/06533; H01C17/0654; C; C03; C03C; C03C3/00; C03C3/04; C03C3/062; C03C3/07; C03C3/072; C03C8/00; C03C8/02; C03C8/10; C03C8/14

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 111 words
A resistor composition comprising conductive particles, a glass frit and a vehicle, said conductive particles comprising particles selected from the group consisting of coated RuO 2 particles and a mixture of said coated RuO 2 particles and uncoated RuO 2 particles wherein the weight ratio of coated RuO 2 particles/uncoated RuO 2 particles is from 5/95 to 100/0, said coated RuO 2 particles having a polynary oxide coating of a metal component selected from the group consisting of (1) Bi and Ru; (2) Pb and Ru; and (3) Bi, Pb and Ru; the weight ratio of said conductive particles to said glass frit being in the range of 60:40 to 5:95.
Claim 2
Dependent Claim 111 words
A resistor composition comprising conductive particles, a glass frit and a vehicle, said conductive particles comprising particles selected from the group consisting of coated RuO 2 particles and a mixture of said coated RuO 2 particles and uncoated RuO 2 particles wherein the weight ratio of coated RuO 2 particles/uncoated RuO 2 particles is from 5/95 to 100/0, said coated RuO 2 particles having a polynary oxide coating of a metal component selected from the group consisting of (1) Bi and Ru; (2) Pb and Ru; and (3) Bi, Pb and Ru; the weight ratio of said conductive particles to said glass frit being in the range of 60:40 to 5:95.
Claim 3
Dependent Claim 20 words
A resistor composition as claimed in claim 1 in which said conductive particles consist of said coated RuO 2 particles.
Claim 4
Dependent Claim 28 words
A resistor composition as claimed in claim 1 in which said conductive particles consist of a mixture of uncoated RuO 2 particles and said coated RuO 2 particles.
Claim 5
Dependent Claim 34 words
A resistor composition as claimed in claim 1 containing up to 20 wt. % based on the combined weight of said conductive particles and said glass frit, of one or more metal oxide additives.
Claim 6
Dependent Claim 38 words
A resistor composition as claimed in claim 4 in which said metal oxide additives are selected from the group consisting of copper oxide, manganese oxide, lanthanum oxide, neodymium oxide, samarium oxide, praseodymium oxide, alumina, silica, and niobium oxide.
Claim 7
Dependent Claim 28 words
A resistor composition as claimed in claim 1, which also contains conductive particles of at least one metal selected from the group consisting of Ag, Au and Pd.
Claim 8
Dependent Claim 68 words
A resistor composition as claimed in claim 1, in which said glass frit has a particle size of not larger than 10 micrometers, said coated RuO 2 particles have a specific surface area of from about 5 to about 60 m 2 /g, and the amount of the polynary oxide coating is from 1-25 mol %, with respect to the total amount of said coated RuO 2 particles.
Claim 9
Dependent Claim 64 words
A resistor composition as claimed in claim 1, in which said coated RuO 2 particles have been prepared by coating the surfaces of RuO 2 particles with compounds of said metal component and then calcining said coated RuO 2 particles at 700° to 900° C., for from 1 to 10 hours, in an oxidizing atmosphere to convert the coating to said polynary oxide coating.

References Cited (Backward Citations)

US3583931A Cited
US3560410A Cited
US3681262A Cited
US4175061A Cited
US4124539A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-03 1989-09-02 1990-03-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-03 1993-09-02 1994-03-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-03 1997-09-02 1998-03-04 $7700.00 Window Closed / Lapsed

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