Negative photoresist compositions with polyglutarimide polymer

Claim 2

A negative photoresist composition comprising a polyglutarimide polymer and a negative-acting photosensitizer dissolved in a solvent, said polyglutarimide polymer comprising at least about 5 weight percent glutarimide units of the formula: ##STR2## where R 1 , R 2 , and R 3 independently are hydrogen, unsubstituted and substituted alkyl, aryl, aralkyl or alkaryl hydrocarbons having from one to twenty carbon atoms or mixtures thereof, where at least about 20 mole percent of the R 3 substituents of said glutarimide units are hydrogen, said negative acting photosensitizer being selected from the group consisting of photosensitive azides and bisazides and being present in said composition at a sufficient quantity to enable the composition to become insoluble in an aqueous base developer upon the exposure of said composition to actinic radiation, such that negative photoresist films formed from said composition are thermally stable and aqueous base developable after exposure to actinic radiation.

Claim 3

The negative photoresist of claim 1 wherein said solvent is an aqueous base and said negative-acting photosensitizer is a water soluble bisazide.

Claim 4

The negative photoresist composition of claim 2 wherein said hydrogen R 3 substituents of the glutarimide units are partially functionalized by reacting said polyglutarimide with an unsaturated compound selected from the group consisting of alkenyl halides and alkenyl aromatic halides such that after said partial functionalization at least about 20 mole percent of said R 3 substituents are hydrogen.

Claim 5

The negative photoresist composition of claim 3 wherein said alkenyl halide is selected from the group consisting of allyl bromide, crotyl bromide and butenyl bromide.

Claim 6

The negative photoresist composition of claim 3 wherein said alkenyl aromatic halide is cinnamyl bromide.

Claim 7

The negative photoresist composition of claim 1 wherein said solvent is an organic solvent selected from the group consisting of N-methyl pyrrolidinone, N,N-dimethyl acetamide, dimethylformamide, cyclopentanone, cyclohexanone, methyl carbitol, 2-methoxyethanol, tetrahydrofuran, tetrahydrofurfuryl alcohol, chlorobenzene, cellosolve, acetate, xylene, butylacetate, and mixtures thereof.

Claim 8

A surface comprising a film of the negative photoresist composition of claim 1 having a thickness ranging from about 0.5 micrometer to about 3.0 micrometers.

Claim 9

A negative photoresist composition comprising a fully functionalized polyglutarimide polymer and an organic solvent-soluble, negative acting photosensitizer dissolved in a solvent, said polyglutarimide polymer comprising at least 5 weight percent glutarimide units of the formula: ##STR3## where R 1 , R 2 and R 3 prior to functionalization are hydrogen, unsubstituted and substituted alkyl, aryl, aralkyl or alkaryl hydrocarbons having from one to twenty carbon atoms or mixtures thereof and where after functionalization less than about 20 mole percent of the R 3 substituents of said glutarimide units are hydrogen, said functionalization resulting from reacting said polyglutarimide with an unsaturated compound selected from the group consisting of alkenyl halides and alkenyl aromatic halides, and where said fully functionalized polyglutarimide is dissolved in an organic solvent at a concentration of from about 5 to about 30 weight percent, said negative acting photosensitizer being present in said composition at a sufficient quantity to enable the composition to become insoluble in organic solvent developer upon the exposure of said composition to actinic radiation, such that negative photoresist films formed from said composition are thermally stable, and organic solvent developable after exposure to actinic radiation.

Claim 10

A negative photoresist composition comprising a fully functionalized polyglutarimide polymer and an organic solvent-soluble, negative acting photosensitizer dissolved in a solvent, said polyglutarimide polymer comprising at least 5 weight percent glutarimide units of the formula: ##STR3## where R 1 , R 2 and R 3 prior to functionalization are hydrogen, unsubstituted and substituted alkyl, aryl, aralkyl or alkaryl hydrocarbons having from one to twenty carbon atoms or mixtures thereof and where after functionalization less than about 20 mole percent of the R 3 substituents of said glutarimide units are hydrogen, said functionalization resulting from reacting said polyglutarimide with an unsaturated compound selected from the group consisting of alkenyl halides and alkenyl aromatic halides, and where said fully functionalized polyglutarimide is dissolved in an organic solvent at a concentration of from about 5 to about 30 weight percent, said negative acting photosensitizer being present in said composition at a sufficient quantity to enable the composition to become insoluble in organic solvent developer upon the exposure of said composition to actinic radiation, such that negative photoresist films formed from said composition are thermally stable, and organic solvent developable after exposure to actinic radiation.