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US4565850A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic composition containing nematic oligomer

Assignee: Honeywell International Inc
•
Filing: 1983-03-03
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Granted: 1986-01-21
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Expires: 2003-03-03
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Abstract

Abstract A thermotropic oligomer such as a polyester is blended with a high molecular weight thermoplastic polymer such as poly(ethylene terephthalate) to raise the modulus value of the composition compared to the polymer alone, especially at the glass transition temperature of the polymer and above.

Inventors

  • 👤 Dusan C. Prevorsek
  • 👤 Murali K. Akkapeddi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 22:16
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/88; C; C08; C08L; C08L101/00; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 204 words
A thermoplastic composition comprising: (a) a thermoplastic polymer of high molecular weight selected from the group consisting of polyesters, polyamides, polycarbonates and polyacetals which has a fusion temperature at a first temperature, has a glass transition temperature and forms an isotropic liquid above the first temperature, and (b) dispersed in said thermoplastic polymer a polyester oligomer having a melting point at a second temperature, said second temperature being not more than 50° C. less than said first temperature nor more than 70° C. more than said first temperature; said oligomer exhibiting nematic behavior between said second temperature and a third temperature, said third temperature being at least 30° C. above said second temperature and at least about 10° C. above said first temperature; said oligomer having a number average length/diameter ratio (L/D) of between 10 and 50, a glass transition temperature at least 10° C. greater than the glass transition temperature of said polymer and a Small's solubility parameter within 2 of the Small's solubility parameter of said polymer; the amount of said oligomer being sufficient to raise the modulus value of the thermoplastic composition to at least 110% of the corresponding value of the polymer at the glass transition temperature of said polymer.
Claim 2
Dependent Claim 204 words
A thermoplastic composition comprising: (a) a thermoplastic polymer of high molecular weight selected from the group consisting of polyesters, polyamides, polycarbonates and polyacetals which has a fusion temperature at a first temperature, has a glass transition temperature and forms an isotropic liquid above the first temperature, and (b) dispersed in said thermoplastic polymer a polyester oligomer having a melting point at a second temperature, said second temperature being not more than 50° C. less than said first temperature nor more than 70° C. more than said first temperature; said oligomer exhibiting nematic behavior between said second temperature and a third temperature, said third temperature being at least 30° C. above said second temperature and at least about 10° C. above said first temperature; said oligomer having a number average length/diameter ratio (L/D) of between 10 and 50, a glass transition temperature at least 10° C. greater than the glass transition temperature of said polymer and a Small's solubility parameter within 2 of the Small's solubility parameter of said polymer; the amount of said oligomer being sufficient to raise the modulus value of the thermoplastic composition to at least 110% of the corresponding value of the polymer at the glass transition temperature of said polymer.
Claim 3
Dependent Claim 14 words
The thermoplastic composition of claim 1 wherein said thermoplastic polymer is a poly(alkylene arylate).
Claim 4
Dependent Claim 19 words
The thermoplastic composition of claim 2 wherein said thermoplastic polymer is a poly(alkylene terephthalate), said alkylene having 2-4 carbons.
Claim 5
Dependent Claim 13 words
The thermoplastic composition of claim 3 wherein said thermoplastic polymer is poly(ethylene terephthalate).
Claim 6
Dependent Claim 13 words
The thermoplastic composition of claim 3 wherein said thermoplastic polymer is poly(butylene terephthalate).
Claim 7
Dependent Claim 49 words
The thermoplastic composition of claim 3 wherein said oligomer is a polyester having residues selected from: ##STR2## with the moles of I+IV=II and wherein R, R' and R" are each 1,4-phenylene, 2,5-naphthalene, 2,6-napththalene 1,4-cyclohexyl, 4,4'-biphenyl, 2,6-anthracene-9,10-dione or any of them substituted by alkyl, aryl, fluoro, chloro, bromo or alkoxy.
Claim 8
Dependent Claim 35 words
The thermoplastic composition of claim 6 wherein said residues are terephthaloyl or substituted terephthaloyl, substituted hydroquinone and an additional biphenol wherein R is 4,4'-biphenyl or hydroquinone, each unsubstituted or substituted by methyl, chloro or t-butyl.
Claim 9
Dependent Claim 15 words
The thermoplastic composition of claim 6 wherein said residues are carbonyl, terephthaloyl and substituted hydroquinone.
Claim 10
Dependent Claim 17 words
The thermoplastic composition of claim 6 wherein said residues are substituted terephthaloyl, substituted 4,4'-dihydroxybiphenyl and substituted hydroquinone.
Claim 11
Dependent Claim 15 words
The thermoplastic composition of claim 6 wherein said residues are terephthaloyl, 2,6-naphthalenedicarboxyl and substituted hydroquinone.
Claim 12
Dependent Claim 12 words
The thermoplastic composition of claim 10 wherein said substituted hydroquinone is methylhydroquinone.
Claim 13
Dependent Claim 25 words
The thermoplastic composition of claim 1 wherein the glass transition temperature of said oligomer is at least 20° C. greater than that of said polymer.
Claim 14
Dependent Claim 18 words
The thermoplastic composition of claim 12 wherein said polymer is poly (alkylene terephthalate), said alkylene having 2-4 carbons.
Claim 15
Dependent Claim 12 words
The thermoplastic composition of claim 1 wherein said polymer is a polyamide.
Claim 16
Dependent Claim 39 words
The thermoplastic composition of claim 14 wherein said polymer has residues of the formula: ##STR3## wherein w, x and y are each independently integers from 4 to 16 and wherein the moles of V equal the moles of VII.
Claim 17
Dependent Claim 18 words
The thermoplastic composition of claim 14 wherein said oligomer is a polyamide which is at least partially N-substituted.
Claim 18
Dependent Claim 13 words
The thermoplastic composition of claim 14 wherein said oligomer is a thermotropic polyester.
Claim 19
Dependent Claim 14 words
The thermoplastic compositions of claim 14 wherein said oligomer is a thermotropic poly(ester amide).
Claim 20
Dependent Claim 14 words
The thermoplastic composition of claim 14 wherein said oligomer is a thermotropic poly(ether amide).
Claim 21
Dependent Claim 21 words
The thermoplastic composition of claim 1 wherein said second temperature is not more than 20° C. more than said first temperature.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-01-20 1989-07-22 1990-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-01-20 1993-07-22 1994-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-01-20 1997-07-22 1998-01-21 $7700.00 Window Closed / Lapsed

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