US4254242A
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Fire-retardant resin composition
Assignee: Unitika Ltd
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Filing: 1978-05-26
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Granted: 1981-03-03
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Expires: 1998-05-26
Abstract
Abstract A fire-retardant resin composition comprising (A) an aromatic copolyester derived from (1) a mixture of terephthalic acid and isophthalic acid and/or the functional derivatives thereof and (2) a bisphenol and/or the functional derivatives thereof; (B) a polyamide; and (C) an aromatic halogen compound; with component (C) being present in a higher concentration in component (A) than in component (B). Molded articles prepared from the resin composition have superior mechanical properties, thermal stability, chemical properties and fire retardancy.
Inventors
- 👤 Kayomon Kyo
- 👤 Yasuhiko Asai
- 👤 Haruo Kohyama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:43
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/03; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/19; C08G63/193; C08G63/195; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/0008; C08K5/0066; C08K5/02; C08K5/03; C08K5/04; C08K5/36; C08K5/41; C08L77/00
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
296 words
A fire-retarding resin composition comprising (A) an aromatic copolyester comprising the reaction product in about equimolar amounts of (1) a mixture of terephthalic acid and isophthalic acid and/or the functional derivatives thereof with the terephthalic acid unit to the isophthalic acid unit molar ratio being about 9:1 to about 1:9 and (2) a bisphenol of the general formula [I] ##STR12## wherein --X-- represents a member selected from the group consisting of --O--, --S--, --SO 2 , --CO--, an alkylene group containing 1 to 5 carbon atoms and an alkylidene group containing 1 to 5 carbon atoms, and R 1 , R 2 , R 3 , R 4 , R 1 ', R 2 ', R 3 ' and R 4 ', which may be the same of different, each is selected from the group consisting of a hydrogen atom, a chlorine atom, a bromine atom and an alkyl group containing 1 to 5 carbon atoms, and/or a derivative thereof; (B) a polyamide containing therein a repeating unit of the general formula [II]: ##STR13## wherein R 5 , R 6 and R 7 , which may be the same or different, each represents an alkylene group containing 4 to 11 carbon atoms and n is an integer of from 30 to 500, and (C) an aromatic halogen compound, with the amount of component (C) being 0.5 to B 40% by weight based on the total amount of components (A), (B) and (C), and with component (C) being present in a higher concentration in component (A) than in component (B), wherein component (C) is present in component (A) in an amount of at least 1.2 times by weight larger than the average concentration of component (C) when component (C) is dispersed uniformly in components (A) and (B).
Claim 2
Dependent Claim
296 words
A fire-retarding resin composition comprising (A) an aromatic copolyester comprising the reaction product in about equimolar amounts of (1) a mixture of terephthalic acid and isophthalic acid and/or the functional derivatives thereof with the terephthalic acid unit to the isophthalic acid unit molar ratio being about 9:1 to about 1:9 and (2) a bisphenol of the general formula [I] ##STR12## wherein --X-- represents a member selected from the group consisting of --O--, --S--, --SO 2 , --CO--, an alkylene group containing 1 to 5 carbon atoms and an alkylidene group containing 1 to 5 carbon atoms, and R 1 , R 2 , R 3 , R 4 , R 1 ', R 2 ', R 3 ' and R 4 ', which may be the same of different, each is selected from the group consisting of a hydrogen atom, a chlorine atom, a bromine atom and an alkyl group containing 1 to 5 carbon atoms, and/or a derivative thereof; (B) a polyamide containing therein a repeating unit of the general formula [II]: ##STR13## wherein R 5 , R 6 and R 7 , which may be the same or different, each represents an alkylene group containing 4 to 11 carbon atoms and n is an integer of from 30 to 500, and (C) an aromatic halogen compound, with the amount of component (C) being 0.5 to B 40% by weight based on the total amount of components (A), (B) and (C), and with component (C) being present in a higher concentration in component (A) than in component (B), wherein component (C) is present in component (A) in an amount of at least 1.2 times by weight larger than the average concentration of component (C) when component (C) is dispersed uniformly in components (A) and (B).
Claim 3
Dependent Claim
15 words
The composition of claim 1, wherein the bisphenol of the general formula [I] is 2,2-bis(4-hydroxyphenyl)propane.
Claim 4
Dependent Claim
11 words
The composition of claim 1, wherein the polyamide (B) is polycaprolactam.
Claim 5
Dependent Claim
12 words
The composition of claim 1, wherein the polyamide (B) is polyhexamethylene adipamide.
Claim 6
Dependent Claim
110 words
The composition of claim 1, wherein the aromatic halogen compound (C) is a compound of the general formula [IV]: ##STR14## wherein A and B, which may be the same or different, each represents a hydrogen atom, a bromine atom or a chlorine atom, and at least one of each of A and B is a bromine atom or a chlorine atom, R 8 is --O--, --S--, --SO 2 --, an alkylene group containing 1 to 5 carbon atoms or an alkylidene group containing 1 to 5 carbon atoms, each of which may be partially halogenated, and each of which may contain at least one ether linkage in the chain thereof.
Claim 7
Dependent Claim
18 words
The composition of claim 5, wherein the compound of the general formula [IV] is a halogenated diphenyl ether.
Claim 8
Dependent Claim
13 words
The composition of claim 6, wherein the halogenated diphenyl ether is decabromodiphenyl ether.
Claim 9
Dependent Claim
13 words
The composition of claim 6, wherein the halogenated diphenyl ether is octabromodiphenyl ether.
Claim 10
Dependent Claim
13 words
The composition of claim 6, wherein the halogenated diphenyl ether is hexabromodiphenyl ether.
Claim 11
Dependent Claim
18 words
The composition of claim 5, wherein the compound of the general formula [IV] is a halogenated diphenyl sulfone.
Claim 12
Dependent Claim
13 words
The composition of claim 10, wherein the halogenated diphenyl sulfone is decabromodiphenyl sulfone.
Claim 13
Dependent Claim
15 words
The composition of claim 5, wherein the compound of the general formula [IV] is bis(tribromophenoxy)ethylene.
Claim 14
Dependent Claim
55 words
The composition of claim 1, wherein the aromatic halogen compound (C) is a compound of the general formula [V]: ##STR15## wherein A represents a hydrogen atom, a bromine atom or a chlorine atom, at least one A is a bromine atom or a chlorine atom and wherein the A's may be the same or different.
Claim 15
Dependent Claim
15 words
The composition of claim 13, wherein the compound of the general formula [V] is hexabromobenzene.
Claim 16
Dependent Claim
99 words
The composition of claim 1, wherein the aromatic halogen compound (C) is a compound of the general formula [VI]: ##STR16## wherein A represents a hydrogen atom, a bromine atom or a chlorine atom, at least one A is a bromine atom or a chlorine atom and the A's may be the same or different, and R 9 is an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 1 to 5 carbon atoms, each of which may be partially halogenated, and each of which may contain at least one ether linkage in the chain thereof.
Claim 17
Dependent Claim
15 words
The composition of claim 15, wherein the compound of the general formula [VI] is pentabromotoluene.
Claim 18
Dependent Claim
15 words
The composition of claim 15, wherein the compound of the general formula [VI] is pentabromoethylbenzene.
Claim 19
Dependent Claim
61 words
The composition of claim 1, wherein the aromatic halogen compound (C) is a compound of the general formula [VII]: ##STR17## wherein A and B, which may be the same or different, each represents a hydrogen atom, a bromine atom or a chlorine atom and at least one of each of A and B is a bromine atom or a chlorine atom.
Claim 20
Dependent Claim
15 words
The composition of claim 18, wherein the compound of the general formula [VII] is decabromodiphenyl.
Claim 21
Dependent Claim
137 words
The composition of claim 1, wherein the aromatic halogen compound (C) is a compound of the general formula [VIII]: ##STR18## wherein A and B, which may be the same or different, each represents a hydrogen atom, a bromine atom or a chlorine atom and at least one of each of A and B is a bromine atom or a chlorine atom, R 10 represents --O--, --S--, --SO 2 --, --CO--, an alkylene group containing 1 to 5 carbon atoms or an alkylidene group containing 1 to 5 carbon atoms, and R 11 represents a hydrogen atom, an alkyl group containing 1 to 5 carbon atoms or a hydroxyalkyl group containing 1 to 5 carbon atoms, each of which may be partially halogenated, and each of which may contain at least one ether linkage in the chain thereof.
Claim 22
Dependent Claim
15 words
The composition of claim 20, wherein the compound of the general formula [VIII] is bis(4-hydroxy-3,5-dibromophenyl)sulfone.
Claim 23
Dependent Claim
20 words
The composition of claim 1, wherein the proportion of the aromatic halogen compound (C) is 2 to 30% by weight.
Claim 24
Dependent Claim
45 words
The composition of claim 1, wherein components (A), (B) and (C) are present in an amount of 20 to 78% by weight, 20 to 78% by weight, and 2 to 30% by weight, respectively, based on the total amount of components (A), (B) and (C).
Claim 25
Dependent Claim
42 words
The composition of claim 1, wherein component (C) is present in component (A) in an amount of at least 1.3 times by weight larger than the average concentration of component (C) when component (C) is dispersed uniformly in components (A) and (B).
Claim 26
Dependent Claim
25 words
The composition of claim 1, wherein said resin composition consists essentially of said aromatic copolyester (A), said polyamide (B) and said aromatic halogen compound (C).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-02 | 1984-09-01 | 1985-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-02 | 1988-09-01 | 1989-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-02 | 1992-09-01 | 1993-03-03 | $7700.00 | Window Closed / Lapsed |