Blend of fluorochemical guanidines and poly(oxyalkylenes)

Claim 2

A composition comprising a blend of: (a) a normally solid, water-insoluble, fluorochemical guanidine composition which is a fluoroaliphatic radical-containing, substituted guanidine compound, or composition comprising a mixture of such compounds, said compound having one or more monovalent fluoroaliphatic radicals, having at least three fully fluorinated carbon atoms, and one or more substituted guanidino moieties, which moieties can be represented in terms of the formula ##STR23## said radicals and moieties being bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH 3 )--, sulfonamido, carbonamido, sulfonamidoalkylene, carbonamidoalkylene, carbonyloxy, urethane, and urea groups, and combinations thereof, with the proviso that when only one guanidino moiety is present, and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms of the moiety, and when more than one guanidino moiety is present, said moieties are bonded together by divalent linking groups selected from the group consisting of alkylene, aralkylene, arylene, polyoxyalkylene, and combinations thereof and can contain said fluoroaliphatic radical; and (b) a normally liquid or low melting solid, water soluble or dispersible, fluoroaliphatic radical-containing poly(oxyalkylene), or composition comprising a mixture of such poly(oxyalkylenes), said poly(oxyalkylene) having one or more of said fluoroaliphatic radicals and one or more poly(oxyalkylene) moieties, said radicals and poly(oxyalkylene) moieties bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, phosphoxy, and amine groups and combinations thereof.

Claim 3

A composition according to claim 1 wherein said fluorochemical guanidine compounds are represented by the general formula ##STR24## where n is 0 to 20, x is 0 or 1, A is a divalent organic linking group selected from alkylene, aralkylene, arylene, and polyoxyalkylene groups and combinations thereof, which can contain hetero moieties and said fluoroaliphatic group, R f , R 1 and R 2 are hydrogen atoms, said R f , or an organic radical selected from alkyl, cycloalkyl, and aryl groups and combinations thereof which can contain hetero moieties, the two R 2 groups of a guanidino moiety can be bonded together to form a cyclic structure with the adjacent N-atom of said guanidine moiety, Q is a linking group selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH 3 )--, sulfonamido, carbonamido, sulfonamidoalkylene, carbonamidoalkylene, carbonyloxy, urethane, and urea groups, and thereof.

Claim 4

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR25## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 --, ##STR26## or --N(iso--C 3 H 7 ) 2 , and n is 2.

Claim 5

A composition according to claim 2 wherein said fluoroaliphatic radical-containing poly(oxyalkylene) has the general formula (R.sub.f).sub.s Z[(R.sup.3).sub.y Z'B].sub.t or [(R.sub.f).sub.s Z[(R.sup.3).sub.y Z'B'].sub.t ].sub.w where R f is said fluoroaliphatic radical, Z is a linkage selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, phosphoxy, and amine groups and combinations thereof through which R f and (R 3 ) y are covalently bonded together, (R 3 ) y is a poly(oxyalkylene) moiety, R 3 being oxyalkylene with 2 to 4 carbon atoms, and y is an integer or number of at least 5 and can be as high as 100 or higher, B is a hydrogen atom or a monovalent terminal organic radical selected from acyl, alkyl, and aryl radicals, B' is B or a valence bond, with the proviso that at least one B' is a valence bond interconnecting a Z-bonded (R 3 ) y radical to another Z, Z' is a linkage selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, phosphoxy, and amine groups and combinations thereof through which B or B' and (R 3 ) y are covalently bonded together, s is an integer or number of at least 1 and can be as high as 25 or higher, t is an integer or number of at least 1 and can be as high as 60 or higher, and w is an integer or number greater than 1 and can be as high as 30 or higher.

Claim 6

A composition according to claim 2 wherein said fluorochemical poly(oxyalkylene) is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 ) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 7

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR27## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 --, ##STR28## or --N(iso--C 3 H 7 ) 2 , and n is 2, and wherein said fluorochemical poly(oxyalkylene) is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 8

A fiber finish comprising an organic solution or aqueous dispersion comprising the composition of claim 2.

Claim 9

The fiber finish according to claim 7 further comprising a fiber lubricant.

Claim 10

A method for imparting oil and water repellency to a fibrous substrate, which comprises treating the surface thereof with the fiber finish of claim 7.

Claim 11

In the manufacture of spun synthetic organic fibers wherein a fiber finish is applied to said fibers, the improvement comprising employing as said fiber finish the fiber finish of claim 8.

Claim 12

A fibrous substrate coated with the fluorochemical blend composition of claim 2.

Claim 13

A fibrous substrate according to claim 11 wherein said substrate is nylon carpet fiber.

Claim 14

A composition comprising a blend of: (a) a normally solid, water-insoluble, fluorochemical guanidine composition which is a fluoroaliphatic radical-containing, substituted guanidine compound or composition comprising a mixture of said compounds, said compounds being represented by the general formula ##STR29## where n is 0 to 20, x is 0 to 1, R 1 and R 2 are hydrogen atoms, a monovalent fluoroaliphatic radical, R f , having at least three fully fluorinated carbon atoms, or an organic radical selected from alkyl, cycloalkyl, and aryl groups and combinations thereof which can contain hetero moieties, the two R 2 groups of a guanidino moiety can be bonded together to form a cyclic structure with the adjacent N-atom of said guanidino moiety, A is a divalent organic linking group selected from alkylene, aralkylene, arylene, and polyoxyalkylene groups and combinations thereof, which can contain hetero moieties and said fluoroaliphatic radical, R f , and Q is a divalent linking group selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH 3 )--, sulfonamido, carbonamido, sulfonamidoalkylene, carbonamidoalkylene, carbonyloxy, urethane, and urea groups, and combinations thereof, with the proviso that at least one fluoroaliphatic radical, R f , is present in one or more of the R 1 , R 2 , and A groups, that where R 1 or R 2 is R f , x is 1, and that when only one guanidino moiety is present and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms of the moiety, and when more than one guanidino moiety is present, said moieties are bonded together by divalent linking groups selected from the group consisting of alkylene, aralkylene, arylene, polyoxyalkylene, and combinations thereof and can contain said fluoroaliphatic radical; and (b) a normally liquid or low melting solid, water soluble or dispersible, fluoroaliphatic radical-containing poly(oxyalkylene), or composition comprising a mixture of such poly(oxyalkylenes), said poly(oxyalkylene) having one or more of said fluoroaliphatic radicals and one or more poly(oxyalkylene) moieties, said radicals and poly(oxyalkylene) moieties bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, crbonyl, sulfone, sulfoxy, phosphoxy, and amine groups and combinations thereof.

Claim 15

A composition comprising a blend of: (a) a normally solid, water-insoluble, fluorochemical guanidine composition which is a fluoroaliphatic radical-containing, substituted guanidine compound or composition comprising a mixture of said compounds, said compounds being represented by the general formula ##STR29## where n is 0 to 20, x is 0 to 1, R 1 and R 2 are hydrogen atoms, a monovalent fluoroaliphatic radical, R f , having at least three fully fluorinated carbon atoms, or an organic radical selected from alkyl, cycloalkyl, and aryl groups and combinations thereof which can contain hetero moieties, the two R 2 groups of a guanidino moiety can be bonded together to form a cyclic structure with the adjacent N-atom of said guanidino moiety, A is a divalent organic linking group selected from alkylene, aralkylene, arylene, and polyoxyalkylene groups and combinations thereof, which can contain hetero moieties and said fluoroaliphatic radical, R f , and Q is a divalent linking group selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH 3 )--, sulfonamido, carbonamido, sulfonamidoalkylene, carbonamidoalkylene, carbonyloxy, urethane, and urea groups, and combinations thereof, with the proviso that at least one fluoroaliphatic radical, R f , is present in one or more of the R 1 , R 2 , and A groups, that where R 1 or R 2 is R f , x is 1, and that when only one guanidino moiety is present and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms of the moiety, and when more than one guanidino moiety is present, said moieties are bonded together by divalent linking groups selected from the group consisting of alkylene, aralkylene, arylene, polyoxyalkylene, and combinations thereof and can contain said fluoroaliphatic radical; and (b) a normally liquid or low melting solid, water soluble or dispersible, fluoroaliphatic radical-containing poly(oxyalkylene), or composition comprising a mixture of such poly(oxyalkylenes), said poly(oxyalkylene) having one or more of said fluoroaliphatic radicals and one or more poly(oxyalkylene) moieties, said radicals and poly(oxyalkylene) moieties bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, crbonyl, sulfone, sulfoxy, phosphoxy, and amine groups and combinations thereof.

Claim 16

A composition according to claim 2 wherein said fluorochemical guanidine is presented by the formula ##STR30## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR31## or --N(iso--C 3 H 7 ) 2 , and n is 1-6.

Claim 17

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR32## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR33## or --N(iso--C 3 H 7 ) 2 , and n is 1-6, and wherein said fluorochemical poly(oxyalkylene) is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 18

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR34## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR35## is --N(C 4 H 9 ) 2 , and n is 1 to 6, and wherein said fluorochemical poly(oxyalkylene) is a copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 19

A composition according to claim 2 wherein said fluorochemical poly(oxyalkylene) is a copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 , CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 3 (C 2 H 4 O) 9 C 2 H 4 OH, and CH 2 CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 20

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR36## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 --, ##STR37## or --N(iso--C 3 H 7 ) 2 , and n is 2, and wherein said fluorochemical poly(oxyalkylene) is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 , CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 OH, and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 21

A composition according to claim 2 wherein said fluorochemical guanidine is represented by the formula ##STR38## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR39## or --N(iso--C 3 H 7 ) 2 , and n is 1-6, and wherein said fluorochemical poly(oxyalkylene) is a copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 , CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 OH, and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 22

A composition comprising a blend of a fluorochemical guanidine represented by the formula ##STR40## wherein R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR41## is --N(C 4 H 9 ) 2 , and n is 1 to 6, and a fluorochemical poly(oxyalkylene) which is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 , CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 OH, and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .

Claim 23

A composition comprising a blend of a fluorochemical guanidine represented by the formula ##STR40## wherein R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, ##STR41## is --N(C 4 H 9 ) 2 , and n is 1 to 6, and a fluorochemical poly(oxyalkylene) which is the copolymer of C 8 F 17 SO 2 N(C 4 H 9 )C 2 H 4 O 2 CCH═CH 2 , CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 OH, and CH 2 ═CHCO 2 (C 2 H 4 O) 10 (C 3 H 6 O) 22 (C 2 H 4 O) 9 C 2 H 4 O 2 CCH═CH 2 .