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US4165338A Expired / Lapsed US ⏱️ 0.0 years remaining

2-Hydroxy-1,1,2,3,3-pentahydro-perfluoroalkyl derivatives, their production and use

Assignee: Daikin Industries Ltd
•
Filing: 1977-06-16
•
Granted: 1979-08-21
•
Expires: 1997-06-16
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Abstract

Abstract A compound of the formula: <IMAGE> WHEREIN Q is a hydrogen atom, -CH2CH(OH)CH2Rf or a hydrocarbon residue having a valence corresponding to m which may contain one or more of -O-, -COO-, -NH-, -N= and <IMAGE> IN THE CHAIN, R is a hydrogen atom, a hydrocarbon residue or -CH2CH(OH)CH2Rf and m is an integer of not less than 1, Rf being a perfluoroalkyl group, an omega -hydro-perfluoroalkyl group o an DIFFERENTIAL -chloro-erfluoroalkylgroup having 4 to 20 carbon atoms, which is useful as an agent for rendering fibrous materials oleophobic and anti-soiling and may be prepared by reacting a perfluoroalkylpropylene oxide of the formula: <IMAGE> wherein Rf is the same as defined above, with a reagent of the formula:

Inventors

  • 👤 Atsuo Katsushima
  • 👤 Iwao Hisamoto
  • 👤 Shoshin Fukui
  • 👤 Chiaki Maeda
  • 👤 Akitoshi Iwatani
  • 👤 Takahisa Kato
  • 👤 Masayuki Nagai
  • 👤 Hiroyuki Shinkai
  • 👤 Masayuki Asaoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 05:49
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/277; C; C08; C08F; C08F8/00; C08F8/18; D06M13/00; D06M13/10; D06M13/224; D06M13/236; D06M13/322; D06M13/368

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 86 words
A compound of the formula: ##STR27## wherein Q is a hydrogen atom, --CH 2 CH(OH)CH 2 Rf or a hydrocarbon residue having a valence corresponding to m which may contain one or more of --O--, --COO--, --NH--, --N═ and ##STR28## in the chain, R is a hydrogen atom, a hydrocarbon residue or --CH 2 CH(OH)CH 2 Rf and m is an integer of not less than 1, Rf being a perfluoroalkyl group, an ω- hydro-perfluoroalkyl group or an ω-chloro-perfluoroalkyl group having 4 to 20 carbon atoms.
Claim 2
Dependent Claim 86 words
A compound of the formula: ##STR27## wherein Q is a hydrogen atom, --CH 2 CH(OH)CH 2 Rf or a hydrocarbon residue having a valence corresponding to m which may contain one or more of --O--, --COO--, --NH--, --N═ and ##STR28## in the chain, R is a hydrogen atom, a hydrocarbon residue or --CH 2 CH(OH)CH 2 Rf and m is an integer of not less than 1, Rf being a perfluoroalkyl group, an ω- hydro-perfluoroalkyl group or an ω-chloro-perfluoroalkyl group having 4 to 20 carbon atoms.
Claim 3
Dependent Claim 16 words
A quaternary ammonium salt of a compound of claim 1 with an organic or inorganic acid.
Claim 4
Dependent Claim 48 words
The compound according to claim 1 having the formula: ##STR29## wherein R 1 and R 2 are each a hydrogen atom, --CH 2 CH(OH)CH 2 Rf or a hydrocarbon residue, Rf being a perfluoroalkyl group, an ω-hydro-perfluoroalkyl group or an ω-chloro-perfluoroalkyl group having 4 to 20 carbon atoms.
Claim 5
Dependent Claim 21 words
The compound according to claim 3, wherein R 1 and R 2 are each a hydrogen atom or a hydrocarbon residue.
Claim 6
Dependent Claim 28 words
The compound according to claim 3, wherein R 1 is a hydrogen atom or a hydrocarbon residue and R 2 is --CH 2 CH(OH) - CH 2 Rf.
Claim 7
Dependent Claim 19 words
The compound according to claim 3, wherein R 1 and R 2 are each --CH 2 CH(OH)CH 2 Rf.
Claim 8
Dependent Claim 17 words
The compound according to claim 3, wherein R 1 and R 2 are each a hydrogen atom.
Claim 9
Dependent Claim 22 words
The compound according to claim 3, wherein R 1 is a hydrogen atom and R 2 is --CH 2 CH(OH)CH 2 Rf.
Claim 10
Dependent Claim 23 words
The compound of claim 3, wherein said hydrocarbon residue is selected from the group consisting of alkyl, aralkyl, cycloalkyl, aryl, alkylaryl, and alkenyl.

References Cited (Backward Citations)

US2700686A Cited
US3873619A Cited
DE1966959A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-08-20 1983-02-19 1983-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-08-20 1987-02-19 1987-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-08-20 1991-02-19 1991-08-21 $7700.00 Window Closed / Lapsed

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