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Process for the preparation and/or further processing of polymer blends

Assignee: Bayer AG
•
Filing: 1984-11-26
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Granted: 1986-01-14
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Expires: 2004-11-26
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Abstract

Abstract The present invention relates to a process for the preparation and/or further processing of polymer blends of thermoplastic, aromatic tetramethylbisphenol F-containing polycarbonates with styrene/acrylonitrile copolymers and/or with styrene/acrylonitrile graft polymers on special rubbers.

Inventors

  • 👤 Volker Serini
  • 👤 Christian Lindner
  • 👤 Horst Peters
  • 👤 Wolfgang Nising

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:43
CPC Classifications
C; C08; C08L; C08L51/00; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08L55/00; C08L55/02; C08L69/00

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 236 words
A process for the production of a polymer blend consisting essentially of A-1 to 99% by weight of a thermoplastic aromatic tetramethylbisphenol F-containing polycarbonate and a copolymer selected from B-99 to 1% by weight of a styrene/acrylonitrile copolymer or C-99 to 1% by weight of a graft polymer, consisting of 5 to 95% by weight of a styrene/acrylonitrile copolymer and 95 to 5% by weight of a butadiene rubber with 0 to 50% by weight of comonomers in addition to butadiene, of an ethylene/propylene/diene rubber or of a rubber consisting of acrylates with 0 to 30% by weight of other comonomers, prepared by polymerisation of styrene/acrylonitrile blends in the presence of one of the stated rubbers, or combinations thereof, the sum of the components A+B+C being 100% by weight, in which the aromatic polycarbonate (A) contains at least 80% by weight of repeating structural units of the formula (1) ##STR4## and not more than 20% by weight of repeating structural units of the formula (3) ##STR5## wherein --O--R--O-- is a diphenolate radical, and the repeating structural units of the formula (1) must amount to at least 25% by weight of the aromatic polycarbonate; the amount of acrylonitrile in the styrene/acrylonitrile copolymer of components B and C is 1.5 to 15% by weight; and mixing of the components to form the blend is carried out at a temperature of above 270° C., in an extruder or kneader.
Claim 2
Dependent Claim 236 words
A process for the production of a polymer blend consisting essentially of A-1 to 99% by weight of a thermoplastic aromatic tetramethylbisphenol F-containing polycarbonate and a copolymer selected from B-99 to 1% by weight of a styrene/acrylonitrile copolymer or C-99 to 1% by weight of a graft polymer, consisting of 5 to 95% by weight of a styrene/acrylonitrile copolymer and 95 to 5% by weight of a butadiene rubber with 0 to 50% by weight of comonomers in addition to butadiene, of an ethylene/propylene/diene rubber or of a rubber consisting of acrylates with 0 to 30% by weight of other comonomers, prepared by polymerisation of styrene/acrylonitrile blends in the presence of one of the stated rubbers, or combinations thereof, the sum of the components A+B+C being 100% by weight, in which the aromatic polycarbonate (A) contains at least 80% by weight of repeating structural units of the formula (1) ##STR4## and not more than 20% by weight of repeating structural units of the formula (3) ##STR5## wherein --O--R--O-- is a diphenolate radical, and the repeating structural units of the formula (1) must amount to at least 25% by weight of the aromatic polycarbonate; the amount of acrylonitrile in the styrene/acrylonitrile copolymer of components B and C is 1.5 to 15% by weight; and mixing of the components to form the blend is carried out at a temperature of above 270° C., in an extruder or kneader.
Claim 3
Dependent Claim 22 words
A process according to claim 1 in which --O--R--O has 6 to 30 carbon atoms and which is different from formula (1).
Claim 4
Dependent Claim 23 words
A process according to claim 1 or 2 in which amount of acrylonitrile in the styrene/acrylonitrile copolymer is 7 to 10% by weight.
Claim 5
Dependent Claim 62 words
A process according to any of claims 1 or 2 in which a polymer combination of 70 to 90%, by weight, of a polycarbonate of component A and 30 to 10% by weight of a graft polymer of component C, where the graft polymer contains 65 to 90%, by weight, of rubber and 35 to 10% by weight styrene/acrylonitrile copolymer is mixed.
Claim 6
Dependent Claim 90 words
A process according to claims 1 or 2 in which a polymer combination of a polycarbonate of component A, a styrene/acrylonitrile copolymer of component B and a graft copolymer of component C is mixed, in which components A and B each amount to at least 10% by weight, components A and B together amount to 65 to 90% by weight and component C amounts to 10 to 35% by weight, and in which component C contains 65 to 90%, by weight, rubber and 5 to 10%, by weight, styrene/acrylonitrile copolymer.
Claim 7
Dependent Claim 40 words
A process according to claims 1 or 2 in which a polymer combination of 10 to 60%, by weight, of a polycarbonate of component A and 90 to 40%, by weight, of a styrene/acrylonitrile copolymer of component B is mixed.
Claim 8
Dependent Claim 58 words
A process according to claim 1 in which a polymer combination of 20 to 60%, by weight, of a polycarbonate of component A and 80 to 40% by weight of a graft polymer of component C where the graft polymer, which contains 15 to 50%, by weight, rubber and 85 to 50%, by weight, styrene/acrylonitrile copolymer is mixed.
Claim 9
Dependent Claim 26 words
A process according to claims 1 or 2, 7 or 9 in which the mixing is carried out at a temperature of 280° to 330° C.
Claim 10
Dependent Claim 58 words
A process according to claim 2 in which a polymer combination of 20 to 60%, by weight, of a polycarbonate of component A and 80 to 40%, by weight, of a graft polymer of component C where the graft polymer, which contains 15 to 50%, by weight, rubber and 85 to 50%, by weight, styrene/acrylonitrile copolymer is mixed.
Claim 11
Dependent Claim 15 words
A polymer blend produced by the process of claims 1 or 2, 7 or 9.
Claim 12
Dependent Claim 38 words
A process for further processing a polymer blend according to claim 9 to give shaped articles, in which the polymer blend is molded at a temperature above 270° C., in an extruder, injection molding machine or high-temperature press.
Claim 13
Dependent Claim 24 words
A shaped article produced by the process of claim 10 which is a washing machine component, a hot-water boiler, tableware or an automobile component.
Claim 14
Dependent Claim 13 words
A shaped article according to claim 11 which is an automobile headlight reflector.

References Cited (Backward Citations)

US31165A Cited
US4172103A Cited
USRE31165E Cited
EP0012357A1 Cited
US4409363A Cited
GB2118194A Cited
US4463130A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-01-13 1989-07-15 1990-01-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-01-13 1993-07-15 1994-01-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-01-13 1997-07-15 1998-01-14 $7700.00 Window Closed / Lapsed

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