US4564654A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the preparation and/or further processing of polymer blends
Assignee: Bayer AG
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Filing: 1984-11-26
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Granted: 1986-01-14
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Expires: 2004-11-26
Abstract
Abstract The present invention relates to a process for the preparation and/or further processing of polymer blends of thermoplastic, aromatic tetramethylbisphenol F-containing polycarbonates with styrene/acrylonitrile copolymers and/or with styrene/acrylonitrile graft polymers on special rubbers.
Inventors
- 👤 Volker Serini
- 👤 Christian Lindner
- 👤 Horst Peters
- 👤 Wolfgang Nising
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 07:38
CPC Classifications
C; C08; C08L; C08L51/00; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08L55/00; C08L55/02; C08L69/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
236 words
A process for the production of a polymer blend consisting essentially of A-1 to 99% by weight of a thermoplastic aromatic tetramethylbisphenol F-containing polycarbonate and a copolymer selected from B-99 to 1% by weight of a styrene/acrylonitrile copolymer or C-99 to 1% by weight of a graft polymer, consisting of 5 to 95% by weight of a styrene/acrylonitrile copolymer and 95 to 5% by weight of a butadiene rubber with 0 to 50% by weight of comonomers in addition to butadiene, of an ethylene/propylene/diene rubber or of a rubber consisting of acrylates with 0 to 30% by weight of other comonomers, prepared by polymerisation of styrene/acrylonitrile blends in the presence of one of the stated rubbers, or combinations thereof, the sum of the components A+B+C being 100% by weight, in which the aromatic polycarbonate (A) contains at least 80% by weight of repeating structural units of the formula (1) ##STR4## and not more than 20% by weight of repeating structural units of the formula (3) ##STR5## wherein --O--R--O-- is a diphenolate radical, and the repeating structural units of the formula (1) must amount to at least 25% by weight of the aromatic polycarbonate; the amount of acrylonitrile in the styrene/acrylonitrile copolymer of components B and C is 1.5 to 15% by weight; and mixing of the components to form the blend is carried out at a temperature of above 270° C., in an extruder or kneader.
Claim 2
Dependent Claim
236 words
A process for the production of a polymer blend consisting essentially of A-1 to 99% by weight of a thermoplastic aromatic tetramethylbisphenol F-containing polycarbonate and a copolymer selected from B-99 to 1% by weight of a styrene/acrylonitrile copolymer or C-99 to 1% by weight of a graft polymer, consisting of 5 to 95% by weight of a styrene/acrylonitrile copolymer and 95 to 5% by weight of a butadiene rubber with 0 to 50% by weight of comonomers in addition to butadiene, of an ethylene/propylene/diene rubber or of a rubber consisting of acrylates with 0 to 30% by weight of other comonomers, prepared by polymerisation of styrene/acrylonitrile blends in the presence of one of the stated rubbers, or combinations thereof, the sum of the components A+B+C being 100% by weight, in which the aromatic polycarbonate (A) contains at least 80% by weight of repeating structural units of the formula (1) ##STR4## and not more than 20% by weight of repeating structural units of the formula (3) ##STR5## wherein --O--R--O-- is a diphenolate radical, and the repeating structural units of the formula (1) must amount to at least 25% by weight of the aromatic polycarbonate; the amount of acrylonitrile in the styrene/acrylonitrile copolymer of components B and C is 1.5 to 15% by weight; and mixing of the components to form the blend is carried out at a temperature of above 270° C., in an extruder or kneader.
Claim 3
Dependent Claim
22 words
A process according to claim 1 in which --O--R--O has 6 to 30 carbon atoms and which is different from formula (1).
Claim 4
Dependent Claim
23 words
A process according to claim 1 or 2 in which amount of acrylonitrile in the styrene/acrylonitrile copolymer is 7 to 10% by weight.
Claim 5
Dependent Claim
62 words
A process according to any of claims 1 or 2 in which a polymer combination of 70 to 90%, by weight, of a polycarbonate of component A and 30 to 10% by weight of a graft polymer of component C, where the graft polymer contains 65 to 90%, by weight, of rubber and 35 to 10% by weight styrene/acrylonitrile copolymer is mixed.
Claim 6
Dependent Claim
90 words
A process according to claims 1 or 2 in which a polymer combination of a polycarbonate of component A, a styrene/acrylonitrile copolymer of component B and a graft copolymer of component C is mixed, in which components A and B each amount to at least 10% by weight, components A and B together amount to 65 to 90% by weight and component C amounts to 10 to 35% by weight, and in which component C contains 65 to 90%, by weight, rubber and 5 to 10%, by weight, styrene/acrylonitrile copolymer.
Claim 7
Dependent Claim
40 words
A process according to claims 1 or 2 in which a polymer combination of 10 to 60%, by weight, of a polycarbonate of component A and 90 to 40%, by weight, of a styrene/acrylonitrile copolymer of component B is mixed.
Claim 8
Dependent Claim
58 words
A process according to claim 1 in which a polymer combination of 20 to 60%, by weight, of a polycarbonate of component A and 80 to 40% by weight of a graft polymer of component C where the graft polymer, which contains 15 to 50%, by weight, rubber and 85 to 50%, by weight, styrene/acrylonitrile copolymer is mixed.
Claim 9
Dependent Claim
26 words
A process according to claims 1 or 2, 7 or 9 in which the mixing is carried out at a temperature of 280° to 330° C.
Claim 10
Dependent Claim
58 words
A process according to claim 2 in which a polymer combination of 20 to 60%, by weight, of a polycarbonate of component A and 80 to 40%, by weight, of a graft polymer of component C where the graft polymer, which contains 15 to 50%, by weight, rubber and 85 to 50%, by weight, styrene/acrylonitrile copolymer is mixed.
Claim 11
Dependent Claim
15 words
A polymer blend produced by the process of claims 1 or 2, 7 or 9.
Claim 12
Dependent Claim
38 words
A process for further processing a polymer blend according to claim 9 to give shaped articles, in which the polymer blend is molded at a temperature above 270° C., in an extruder, injection molding machine or high-temperature press.
Claim 13
Dependent Claim
24 words
A shaped article produced by the process of claim 10 which is a washing machine component, a hot-water boiler, tableware or an automobile component.
Claim 14
Dependent Claim
13 words
A shaped article according to claim 11 which is an automobile headlight reflector.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-01-13 | 1989-07-15 | 1990-01-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-13 | 1993-07-15 | 1994-01-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-13 | 1997-07-15 | 1998-01-14 | $7700.00 | Window Closed / Lapsed |