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US4554098A Expired / Lapsed US ⏱️ 0.0 years remaining

Mild liquid detergent compositions

Assignee: Colgate Palmolive Co
•
Filing: 1982-02-19
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Granted: 1985-11-19
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Expires: 2002-02-19
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Abstract

Abstract Liquid detergent compositions having good foaming and grease emulsification properties as well as reduced skin irritation effects which consist essentially of, by weight, 8% to 30% of a water-soluble C10-C16 alkyl ether ethylenoxy sulfate salt containing an average of 5 to 12 moles of ethylene oxide in the molecule, a supplementary, water-soluble, non-soap, anionic detergent having in its molecular structure a C8-C22 alkyl alkenyl or acyl group, and a sulfonate, sulfate or carboxylate group, the weight ratio of said alkyl ether sulfate to said supplementary detergent being in the range of 1:1 to 20:1; 1% to 8% of a zwitterionic detergent having the structural formula <IMAGE> wherein R is a C8-C18 alkyl or C8-C18 alkanamido C2-C3 alkyl group, R1 is a C1-C3 alkyl, R2 is a C1-C4 alkylene or hydroxyalkylene and X is S:O or C; 1% to 8% of an N-C8-C18 alkonoic acid C2-C3 alkanolamide, the weight ratio of said alkanolamide to said zwitterionic detergent being in the range of 1:4 to 4:1; and the balance being an aqueous medium comprising water and from 2% to 20% of a solubilizer selected from the group consisting of C2-C3 alcohols, hydrotropes and mixtures thereof. Preferred compositions include, in addition, 2% to 10% by weight of an anti-gelling agent, such as a water-soluble formate. These compositions are characterized by good foaming, cleaning and skin mildness characteristics and are suitable for use as shampoos, dishwashing liquids, liquid soaps and foam baths.

Inventors

  • 👤 Stephen C. Klisch
  • 👤 Kuo-Yann Lai
  • 👤 Clarence R. Robbins

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:11
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0094; C11D1/00; C11D1/88; C11D1/94; C11D1/02; C11D1/04; C11D1/10; C11D1/12; C11D1/123; C11D1/126; C11D1/28; C11D1/29; C11D1/38; C11D1/52; C11D1/523

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 171 words
A high foaming, liquid detergent composition having reduced skin-irritation properties which consists essentially of, by weight, 12% to 24% of alkyl ether sulfate having the structural formula R(OC(2)H(4))nOSO(3)M wherein R is an alkyl of 10 to 16 carbon atoms, n has an average value of 5 to 12 and M is a cation; a supplementary, water-soluble, non-soap, anionic detergent having in its molecular structure a C(7)--C(22) alkyl, alkenyl or acyl group and a sulfonate, sulfate or carboxylate group, the weight ratio of said alkyl ether sulfate to said supplementary detergent being in the range of 1.5:1 to 6:1; 2% to 6% of a zwitterionic detergent having the structural formula ##STR5## wherein R is C(8)--C(18) alkyl or C(8)--C(18) alkanamido C(2)--C(3) alkyl group, R1 is a C(1)--C(4) alkylene or hydroxylene group; 2% to 6% of an N-C(12)--C(14) alkanoic acid C(2)--C(3) alkanolamide, the weight ratio of said alkanolamide to said zwitterionic detergent being in the range of 1:2 to 2:1; and the balance being an aqueous medium containing 2% to 20% of a solubilizer.
Claim 2
Dependent Claim 171 words
A high foaming, liquid detergent composition having reduced skin-irritation properties which consists essentially of, by weight, 12% to 24% of alkyl ether sulfate having the structural formula R(OC(2)H(4))nOSO(3)M wherein R is an alkyl of 10 to 16 carbon atoms, n has an average value of 5 to 12 and M is a cation; a supplementary, water-soluble, non-soap, anionic detergent having in its molecular structure a C(7)--C(22) alkyl, alkenyl or acyl group and a sulfonate, sulfate or carboxylate group, the weight ratio of said alkyl ether sulfate to said supplementary detergent being in the range of 1.5:1 to 6:1; 2% to 6% of a zwitterionic detergent having the structural formula ##STR5## wherein R is C(8)--C(18) alkyl or C(8)--C(18) alkanamido C(2)--C(3) alkyl group, R1 is a C(1)--C(4) alkylene or hydroxylene group; 2% to 6% of an N-C(12)--C(14) alkanoic acid C(2)--C(3) alkanolamide, the weight ratio of said alkanolamide to said zwitterionic detergent being in the range of 1:2 to 2:1; and the balance being an aqueous medium containing 2% to 20% of a solubilizer.
Claim 3
Dependent Claim 39 words
A detergent composition according to claim 1 wherein said solubilizer is selected from the group consisting of C 2 --C 3 monohydric and polyhydric alcohols, water-soluble C 1 --C 3 alkyl substituted benzene sulfonate salts, urea and mixtures thereof.
Claim 4
Dependent Claim 112 words
A detergent according to claim 1 wherein said supplementary anionic detergent is selected from the group consisting of water-soluble salts of C 8 --C 18 alkyl sulfates, C 9 --C 15 alkylbenzene sulfonates, C 8 --C 22 olefin sulfonates, C 8 --C 18 alkyl ether ethylenoxy sulfates containing an average of 1 to 4 ethylene oxide groups, C 10 --C 20 alkane sulfonates, C 6 --C 12 alkylphenyl ether ethylenoxy sulfates containing an average of 2 to 6 ethylene oxide groups, C 8 --C 18 alkyl sulfoacetates, N-mono-C 8 --C 22 alkyl sulfosuccinates, N-C 8 --C 18 acyl sarcosinates, N-C 8 --C 18 acyl taurates and O-C 8 --C 18 alkyl isethionates.
Claim 5
Dependent Claim 36 words
A detergent composition according to claim 3 which contains in addition from 2% to 10% by weight of an antigelling agent selected from the group consisting of sodium, ammonium or potassium formate, isethionate and mixtures thereof.
Claim 6
Dependent Claim 13 words
A detergent according to claim 4 wherein said antigelling agent is sodium formate.
Claim 7
Dependent Claim 36 words
A detergent composition according to claim 3 wherein the salt-forming cation of said alkyl ether sulfate and said supplementary anionic detergent is selected from the group consisting of sodium, potassium, ammonium and mono-, di-, or triethanolammonium.
Claim 8
Dependent Claim 28 words
A detergent composition according to claim 3 wherein said supplementary anionic detergent is a C 8 --C 18 alkyl sulfate or a mono-C 8 --C 22 alkyl sulfosuccinate.
Claim 9
Dependent Claim 32 words
A detergent composition according to claim 7 which contains in addition 2% to 10% of an antigelling agent selected from the group consisting of sodium or potassium formate, isethionate and mixtures thereof.
Claim 10
Dependent Claim 14 words
A detergent composition according to claim 8 wherein said antigelling agent is sodium formate.
Claim 11
Dependent Claim 61 words
A detergent composition according to claim 7 wherein said supplementary anionic detergent is sodium or ammonium C 10 --C 16 alkyl sulfate which is present in an amount of 2% to 10% by weight, said zwitterionic detergent is C 8 --C 18 alkanamidopropyldimethyl betaine and said alkanoic acid C 2 --C 3 alkanolamide is C 12 --C 14 alkanoic acid monoethanolamide.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-18 1989-05-20 1989-11-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-18 1993-05-20 1993-11-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-18 1997-05-20 1997-11-19 $7700.00 Window Closed / Lapsed

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