Patent US4552908A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4552908A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-dilutable aqueous coating compositions

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1984-08-17
•
Granted: 1985-11-12
•
Expires: 2004-08-17
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Aqueous coating compositions comprise a polymer of defined molecular weight which contains either anionizable or cationizable groups and also certain defined non-ionizable water-soluble moieties (derived for example from polyethylene glycol), water, optionally an organic coupling solvent and optionally either base or acid. The presence of regularly distributed non-ionizable water-soluble moieties enables the selection of aqueous polymer solutions which, on dilution, show a regular relationship between viscosity and solids content. The polymer solutions are useful in the formulation of coating compositions, particularly paints.

Inventors

  • 👤 Peter F. Nicks
  • 👤 Gillian A. Young

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:05
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/08; C09D157/00; C09D5/00; C09D5/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 232 words
A water-dilutable aqueous coating composition which comprises: (A) X parts of a water-dispersible film-forming polymer of molecular weight in the range 2,000-30,000, the polymer comprising (a) anionisable groups, at least partially neutralised with a base when required, selected from --COOH, --SO 3 H and --PO 4 H 2 , or cationisable groups, at least partially neutralised with an acid when required, of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups, the same or different, or R 1 and R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline and its hydrolysates, all being of molecular weight not greater than 2,000; (B) Y parts of an organic coupling solvent for the film-forming polymer which has a boiling point greater than that of water, where Y=X(Z/100), Z being in the range 0-150, and (C) water, which is characterised in that when a solution of X parts of the water-dispersible polymer in Y parts of the organic coupling solvent or, when Y=O, in water is progressively diluted with water, there is no increase in viscosity of the diluted aqueous solution as measured at 25° C. by a low shear viscometer.
Claim 2
Dependent Claim 232 words
A water-dilutable aqueous coating composition which comprises: (A) X parts of a water-dispersible film-forming polymer of molecular weight in the range 2,000-30,000, the polymer comprising (a) anionisable groups, at least partially neutralised with a base when required, selected from --COOH, --SO 3 H and --PO 4 H 2 , or cationisable groups, at least partially neutralised with an acid when required, of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups, the same or different, or R 1 and R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline and its hydrolysates, all being of molecular weight not greater than 2,000; (B) Y parts of an organic coupling solvent for the film-forming polymer which has a boiling point greater than that of water, where Y=X(Z/100), Z being in the range 0-150, and (C) water, which is characterised in that when a solution of X parts of the water-dispersible polymer in Y parts of the organic coupling solvent or, when Y=O, in water is progressively diluted with water, there is no increase in viscosity of the diluted aqueous solution as measured at 25° C. by a low shear viscometer.
Claim 3
Dependent Claim 20 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer has a molecular weight in the range 2,000-15,000.
Claim 4
Dependent Claim 20 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer is selected from addition polymers, polyesters and polyurethanes.
Claim 5
Dependent Claim 24 words
An aqueous coating composition according to claim 1 wherein ionisable groups and non-ionisable water-soluble moieties are regularly distributed along the length of the polymer.
Claim 6
Dependent Claim 36 words
An aqueous coating composition according to claim 1 comprising a film-forming polymer having ionisable groups in the range 0.3-3.6 moles/Kg of polymer and 0.5-40% by weight of non-ionisable water-soluble moieties based on the weight of polymer.
Claim 7
Dependent Claim 27 words
An aqueous coating composition according to claim 1 wherein there is present from 5 to 150 parts of organic coupling solvent per 100 parts of film-forming polymer.
Claim 8
Dependent Claim 27 words
An aqueous coating composition according to claim 1 wherein the organic coupling solvent is selected from alcohols, glycols, ester alcohols, ether alcohols and esters of ether alcohols.
Claim 9
Dependent Claim 23 words
An aqueous coating composition according to claim 6 wherein the organic coupling solvent is a propylene glycol ether or an ester derivative thereof.
Claim 10
Dependent Claim 127 words
A water-dispersible film-forming polymer suitable for use in an aqueous coating composition according to claim 1 which has a molecular weight in the range 2,000-30,000 and comprises: (a) anionisable groups selected from --COOH, --SO 3 H, --PO 4 H 2 , or cationisable groups of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups the same or different, or R 1 R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline or its hydrolysates, all being of molecular weight not greater than 2,000.
Claim 11
Dependent Claim 13 words
A water-dilutable paint which comprises a water-dilutable coating composition according to claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-11 1989-05-13 1989-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-11 1993-05-13 1993-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-11 1997-05-13 1997-11-12 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag