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US4552908A
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US
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Water-dilutable aqueous coating compositions
Assignee: Imperial Chemical Industries Ltd
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Filing: 1984-08-17
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Granted: 1985-11-12
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Expires: 2004-08-17
Abstract
Abstract Aqueous coating compositions comprise a polymer of defined molecular weight which contains either anionizable or cationizable groups and also certain defined non-ionizable water-soluble moieties (derived for example from polyethylene glycol), water, optionally an organic coupling solvent and optionally either base or acid. The presence of regularly distributed non-ionizable water-soluble moieties enables the selection of aqueous polymer solutions which, on dilution, show a regular relationship between viscosity and solids content. The polymer solutions are useful in the formulation of coating compositions, particularly paints.
Inventors
- 👤 Peter F. Nicks
- 👤 Gillian A. Young
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 23:05
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/08; C09D157/00; C09D5/00; C09D5/02
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
232 words
A water-dilutable aqueous coating composition which comprises: (A) X parts of a water-dispersible film-forming polymer of molecular weight in the range 2,000-30,000, the polymer comprising (a) anionisable groups, at least partially neutralised with a base when required, selected from --COOH, --SO 3 H and --PO 4 H 2 , or cationisable groups, at least partially neutralised with an acid when required, of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups, the same or different, or R 1 and R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline and its hydrolysates, all being of molecular weight not greater than 2,000; (B) Y parts of an organic coupling solvent for the film-forming polymer which has a boiling point greater than that of water, where Y=X(Z/100), Z being in the range 0-150, and (C) water, which is characterised in that when a solution of X parts of the water-dispersible polymer in Y parts of the organic coupling solvent or, when Y=O, in water is progressively diluted with water, there is no increase in viscosity of the diluted aqueous solution as measured at 25° C. by a low shear viscometer.
Claim 2
Dependent Claim
232 words
A water-dilutable aqueous coating composition which comprises: (A) X parts of a water-dispersible film-forming polymer of molecular weight in the range 2,000-30,000, the polymer comprising (a) anionisable groups, at least partially neutralised with a base when required, selected from --COOH, --SO 3 H and --PO 4 H 2 , or cationisable groups, at least partially neutralised with an acid when required, of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups, the same or different, or R 1 and R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline and its hydrolysates, all being of molecular weight not greater than 2,000; (B) Y parts of an organic coupling solvent for the film-forming polymer which has a boiling point greater than that of water, where Y=X(Z/100), Z being in the range 0-150, and (C) water, which is characterised in that when a solution of X parts of the water-dispersible polymer in Y parts of the organic coupling solvent or, when Y=O, in water is progressively diluted with water, there is no increase in viscosity of the diluted aqueous solution as measured at 25° C. by a low shear viscometer.
Claim 3
Dependent Claim
20 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer has a molecular weight in the range 2,000-15,000.
Claim 4
Dependent Claim
20 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer is selected from addition polymers, polyesters and polyurethanes.
Claim 5
Dependent Claim
24 words
An aqueous coating composition according to claim 1 wherein ionisable groups and non-ionisable water-soluble moieties are regularly distributed along the length of the polymer.
Claim 6
Dependent Claim
36 words
An aqueous coating composition according to claim 1 comprising a film-forming polymer having ionisable groups in the range 0.3-3.6 moles/Kg of polymer and 0.5-40% by weight of non-ionisable water-soluble moieties based on the weight of polymer.
Claim 7
Dependent Claim
27 words
An aqueous coating composition according to claim 1 wherein there is present from 5 to 150 parts of organic coupling solvent per 100 parts of film-forming polymer.
Claim 8
Dependent Claim
27 words
An aqueous coating composition according to claim 1 wherein the organic coupling solvent is selected from alcohols, glycols, ester alcohols, ether alcohols and esters of ether alcohols.
Claim 9
Dependent Claim
23 words
An aqueous coating composition according to claim 6 wherein the organic coupling solvent is a propylene glycol ether or an ester derivative thereof.
Claim 10
Dependent Claim
127 words
A water-dispersible film-forming polymer suitable for use in an aqueous coating composition according to claim 1 which has a molecular weight in the range 2,000-30,000 and comprises: (a) anionisable groups selected from --COOH, --SO 3 H, --PO 4 H 2 , or cationisable groups of structure --N R 1 R 2 , where R 1 and R 2 are H or C 1-18 alkyl or substituted alkyl groups the same or different, or R 1 R 2 represent part of a cyclic structure, and (b) non-ionisable water-soluble moieties selected from moieties of polyethylene glycol or its monoethers of molecular weight not greater than 1,000; and moieties of poly(meth)acrylamide, of polyvinylpyrrolidone or of poly 2-ethyl oxazoline or its hydrolysates, all being of molecular weight not greater than 2,000.
Claim 11
Dependent Claim
13 words
A water-dilutable paint which comprises a water-dilutable coating composition according to claim 1.
References Cited (Backward Citations)
US28576A
Cited
US28474A
Cited
US3284393A
Cited
US3251816A
Cited
US3450655A
Cited
US3714100A
Cited
USRE28576F1
Cited
USRE28474E
Cited
USRE28474F1
Cited
USRE28576E
Cited
US3891527A
Cited
US3862894A
Cited
US4077930A
Cited
US3997492A
Cited
US4138376A
Cited
US4363886A
Cited
US4373054A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-11 | 1989-05-13 | 1989-11-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-11 | 1993-05-13 | 1993-11-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-11 | 1997-05-13 | 1997-11-12 | $7700.00 | Window Closed / Lapsed |