Dye-bleach materials and process

Claim 2

A composition capable of bleaching upon exposure to radiation of selected wavelength within the range 200 to 1100 nm and/or upon heating to at least 70° C., said composition comprising a bleachable dye in reactive association with a mesoionic bleaching compound wherein said mesoionic compound contains a five- or six-membered heterocycle which cannot be represented satisfactorily by any one covalent or polar structure and possesses a sextet of electrons in association with all the atoms comprising the ring.

Claim 3

A composition as claimed in claim 1, in which the weight ratio of mesoionic compound:bleachable dye is at least 4:1.

Claim 4

A composition as claimed in claim 1, in which the bleachable dye has the general formula: ##STR17## in which: n is an integer of 1 to 5, R 1 to R 4 are selected to provide an electron donor moiety at one end of the conjugated chain and an electron acceptor moiety at the other, and represent alkyl, aryl groups or heterocyclic rings any of which may be substituted, said group generally containing up to 14 atoms selected from C, N, O and S; or R 1 and r 2 and/or R 3 and R 4 may represent the necessary atoms to complete optionally substituted aryl groups or heterocyclic rings, generally containing up to 14 atoms selected from C, N, O and S.

Claim 5

A composition as claimed in claim 2, in which the bleachable dye has the general formula: ##STR18## in which: n is an integer of 1 to 5, R 1 to R 4 are selected to provide an electron donor moiety at one end of the conjugated chain and an electron acceptor moiety at the other, and represent alkyl, aryl groups or heterocyclic rings any of which may be substituted, said group generally containing up to 14 atoms selected from C, N, O and S; or R 1 and R 2 and/or R 3 and R 4 may represent the necessary atoms to complete optionally substituted aryl groups or heterocyclic rings, generally containing up to 14 atoms selected from C, N, O and S.

Claim 6

A composition as claimed in claim 3, in which the bleachable dye is a cyanine, merocyanine or oxonol dye.

Claim 7

A composition as claimed in claim 4, in which the bleachable dye is a cyanine, merocyanine or oxonol dye.

Claim 8

A composition as claimed in claim 1 in which the mesoionic compound has the general formula: ##STR19## in which: R 12 represents an alkyl or aryl group or a heterocyclic ring, any of which groups may be substituted, and R 13 represents an alkyl or aryl group either of which may be substituted, a hydrogen atom, an amino or an alkoxy group.

Claim 9

A composition as claimed in claim 4, in which the mesoionic compound has the general formula: ##STR20## in which: R 12 represents an alkyl or aryl group or a heterocyclic ring, any of which groups may be substituted, and R 13 represents an alkyl or aryl group either of which may be substituted, a hydrogen atom, an amino or an alkoxy group.

Claim 10

A composition as claimed in claim 6, in which the mesoionic compound has the general formula: ##STR21## in which: R 12 represents an alkyl or aryl group or a heterocyclic ring, any of which groups may be substituted, and R 13 represents an alkyl or aryl group either of which may be substituted, a hydrogen atom, an amino or an alkoxy group.

Claim 11

A composition as claimed in claim 1, in which the mesoionic compound is a sydnone of the general formula: ##STR22## in which: R 15 and R 16 independently represent a hydrogen or halogen atom, an alkyl or alkoxy group, CN or OH.

Claim 12

A composition as claimed in claim 2, in which the mesoionic compound is a sydnone of the general formula: ##STR23## in which: r 15 and R 16 independently represent a hydrogen or halogen atom, an alkyl or alkoxy group, CN or OH.

Claim 13

A composition as claimed in claim 4, in which the mesoionic compound is a sydnone of the general formula: ##STR24## in which: R 15 and R 16 independently represent a hydrogen or halogen atom, an alkyl or alkoxy group, CN or OH.

Claim 14

A composition as claimed in claim 5, in which the mesoionic compound is a sydnone of the general formula: ##STR25## in which: R 15 and R 16 independently represent a hydrogen or halogen atom, an alkyl or alkoxy group, CN or OH.

Claim 15

A composition as claimed in claim 6, in which the mesoionic compound is a sydnone of the general formula: ##STR26## in which: R 15 and R 16 independently represent a hydrogen or halogen atom, an alkyl or alkoxy group, CN or OH.

Claim 16

A composition as claimed in claim 1, in which the dye and mesoionic compound are dissolved in a solvent.

Claim 17

A composition as claimed in claim 2, which additionally comprises a binder and optionally a solvent.

Claim 18

A composition as claimed in claim 16, suitable for forming a radiation sensitive coating on a support comprising: 0.01 to 1.0% by weight of dye, 0.04 to 10% by weight of mesoionic compound, 0.5 to 25% by weight of binder, to 100% solvent (w/v).

Claim 19

A composition as claimed in claim 17, suitable for forming a radiation sensitive coating on a support comprising: 0.8 to 0.4% by weight of dye, 3 to 4.5% by weight of mesoionic compound, 1 to 20% by weight of binder, to 100% solvent (w/v).

Claim 20

A composition as claimed in claim 16, which additionally comprises a plasticizer in an amount of 10% by weight.

Claim 21

A composition as claimed in claim 19, in which the plasticizer is selected from glycerol, sorbitol, polyglycols, polyethylene glycols and esters thereof, and any mixtures thereof.

Claim 22

An element capable of recording a positive image upon imagewise exposure to radiation within the wavelength range of 200 to 1100 nm or upon heating to a temperature of at least 70° C., comprising a support having on at least one surface thereof a bleachable dye in reactive association with a mesoionic bleaching compound wherein said mesoionic compound contains a five- or six-membered heterocycle which cannot be represented satisfactorily by any one covalent or polar structure and possesses a sextet of electrons in association with all the atoms comprising the ring.

Claim 23

An element capable of recording a positive image upon imagewise exposure to radiation within the wavelength range of 200 to 1100 nm or upon heating to a temperature of at least 70° C., comprising a support having on at least one surface thereof a bleachable dye in reactive association with a mesoionic bleaching compound wherein said mesoionic compound contains a five- or six-membered heterocycle which cannot be represented satisfactorily by any one covalent or polar structure and possesses a sextet of electrons in association with all the atoms comprising the ring.

Claim 24

An element capable of recording a positive image upon imagewise exposure to radiation within the wavelength range of 200 to 1100 nm or upon heating to a temperature of at least 70° C., comprising a support having on at least one surface thereof a bleachable dye in reactive association with a mesoionic bleaching compound in which the bleachable dye has the general formula: ##STR27## in which: n is an integer of 1 to 5, R 1 to R 4 are selected to provide an electron donor moiety at one end of the conjugated chain and an electron acceptor moiety at the other, and represent alkyl, aryl groups or heterocyclic rings any of which may be substituted, said group generally containing up to 14 atoms selected from C, N, O and S; or R 1 and R 2 and/or R 3 and R 4 may represent the necessary atoms to complete optionally substituted aryl groups or heterocyclic rings, generally containing up to 14 atoms selected from C, N, O and S.

Claim 25

An element capable of recording a positive image upon imagewise exposure to radiation within the wavelength range of 200 to 1100 nm or upon heating to a temperature of at least 70° C., comprising a support having on at least one surface thereof a bleachable dye in reactive association with a mesoionic bleaching compound in which the bleachable dye has the general formula: ##STR27## in which: n is an integer of 1 to 5, R 1 to R 4 are selected to provide an electron donor moiety at one end of the conjugated chain and an electron acceptor moiety at the other, and represent alkyl, aryl groups or heterocyclic rings any of which may be substituted, said group generally containing up to 14 atoms selected from C, N, O and S; or R 1 and R 2 and/or R 3 and R 4 may represent the necessary atoms to complete optionally substituted aryl groups or heterocyclic rings, generally containing up to 14 atoms selected from C, N, O and S.

Claim 26

A recording element comprising a support, one or more radiation sensitive layers and as an antihalation layer, a layer containing a bleachable dye in reactive association with a mesoionic bleaching compound wherein said mesoionic compound contains a five: or six-membered heterocycle which cannot be represented satisfactorily by any one covalent or polar structure and possesses a sextet of electrons in association with all the atoms comprising the ring.

Claim 27

A recording element comprising a support, one or more radiation sensitive layers and as an antihalation layer, a layer containing a bleachable dye in reactive association with a mesoionic bleaching compound wherein said mesoionic compound contains a five: or six-membered heterocycle which cannot be represented satisfactorily by any one covalent or polar structure and possesses a sextet of electrons in association with all the atoms comprising the ring.

Claim 28

A method of recording a positive image comprising imagewise exposing the element of claim 21 to a heat source of at least 70° C. or radiation having a wavelength at the maximum absorbance of the mesoionic compound.

Claim 29

A method of bleaching an antihalation layer of the element of claim 23 which comprises irradiating said antihalation layer with radiation having a wavelength of the maximum absorbance of the mesoionic compound or heating said layer to a temperature of at least 70° C.