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US4540728A
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Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl) amines as monomers and polymers and stabilized synthetic resin compositions
Assignee: Adeka Corp
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Filing: 1983-09-09
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Granted: 1985-09-10
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Expires: 2003-09-09
Abstract
Abstract Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl) amines are provided, having a molecular weight within the range from about 800 to about 20,000, and derived from the monomer: <IMAGE> I wherein: R1 is selected from the group consisting of hydrogen; oxyl; alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms; and acyl having from two to about eighteen carbon atoms; Y is selected from the group consisting of <IMAGE> where R2 and R3 are hydrogen or alkyl having from one to about eight carbon atoms and n is 0 or 1; Z is selected from the group consisting of <IMAGE> in which R4, R5 and R6 are selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aryl having from six to about thirty carbon atoms; as well as stabilized synthetic resin compositions having an improved resistance to deterioration by light and containing such a polymer.
Inventors
- 👤 Yutaka Nakahara
- 👤 Ryoji Kimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 12:48
CPC Classifications
C; C07; C07D; C07D405/00; C07D405/02; C07D405/06; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/56; C07D211/58; C07D211/92; C07D211/94; C08; C08F; C08F26/00; C08F26/02; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C08L; C08L23/00; C08L23/02; C08L57/00; C08L75/00; C08L75/04
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
139 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines having the formula: ##STR89## wherein: R is selected from the group consisting of hydrogen; oxyl; alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms; and acyl having from two to about eighteen carbon atoms; Y is ##STR90## where R 2 and R 3 are hydrogen or alkyl having from one to about eight carbon atoms and n is 0 or 1; Z is selected from the group consisting of ##STR91## in which R 4 , R 5 and R 6 are selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aryl having from six to about thirty carbon atoms.
Claim 2
Dependent Claim
139 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines having the formula: ##STR89## wherein: R is selected from the group consisting of hydrogen; oxyl; alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms; and acyl having from two to about eighteen carbon atoms; Y is ##STR90## where R 2 and R 3 are hydrogen or alkyl having from one to about eight carbon atoms and n is 0 or 1; Z is selected from the group consisting of ##STR91## in which R 4 , R 5 and R 6 are selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aryl having from six to about thirty carbon atoms.
Claim 3
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which R is hydrogen.
Claim 4
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which R is alkyl.
Claim 5
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which R is acyl.
Claim 6
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which R is epoxyalkyl.
Claim 7
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which R is alkylaryl.
Claim 8
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Y is OCH<.
Claim 9
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Y is ##STR92##
Claim 10
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Y is ##STR93##
Claim 11
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Z is ##STR94##
Claim 12
Dependent Claim
13 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Z is --OR 4 .
Claim 13
Dependent Claim
11 words
Diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1 in which Z is ##STR95##
Claim 14
Dependent Claim
21 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 1, having a molecular weight within the range from about 800 to about 20,000.
Claim 15
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which R is hydrogen.
Claim 16
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which R is alkyl.
Claim 17
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which R is acyl.
Claim 18
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which R is epoxyalkyl.
Claim 19
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperadyl)amines according to claim 13 in which R is alkylaryl.
Claim 20
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Y is --OCH<.
Claim 21
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Y is ##STR96##
Claim 22
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Y is ##STR97##
Claim 23
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Z is ##STR98##
Claim 24
Dependent Claim
15 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Z is OR 4 .
Claim 25
Dependent Claim
13 words
Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl)amines according to claim 13 in which Z is ##STR99##
Claim 26
Dependent Claim
65 words
A polyvinyl chloride resin composition having improved resistance to deterioration when exposed to light, comprising a polyvinyl chloride resin formed at least in part of the recurring group: ##STR100## and having a chlorine content in excess of 49%, where X is either hydrogen or chlorine, and an amount sufficient to improve resistance to deterioration of the resin of a compound in accordance with claim 13.
Claim 27
Dependent Claim
20 words
A polyvinyl chloride resin composition in accordance with claim 25 in which the polyvinyl chloride resin is polyvinyl chloride homopolymer.
Claim 28
Dependent Claim
25 words
A polyvinyl chloride resin composition in accordance with claim 25 in which the polyvinyl chloride resin is a copolymer of vinyl chloride and vinyl acetate.
Claim 29
Dependent Claim
51 words
An olefin polymer composition having improved resistance to deterioration comprising an olefin polymer selected from the group consisting of polymers of alphaolefins having from two to six carbon atoms and polystyrene, and an amount sufficient to improve resistance to deterioration of the resin of a compound in accordance with claim 13.
Claim 30
Dependent Claim
14 words
An olefin polymer composition in accordance with claim 28 wherein the polyolefin is polypropylene.
Claim 31
Dependent Claim
14 words
An olefin polymer composition in accordance with claim 28 wherein the polyolefin is polyethylene.
Claim 32
Dependent Claim
15 words
An olefin polymer composition in accordance with claim 28 wherein the polyolefin is ethylene-propylene copolymer.
Claim 33
Dependent Claim
36 words
An acrylonitrile-butadiene-styrene polymer having improved resistance to deterioration when exposed to light comprising an acrylonitrile-butadiene-styrene polymer and an amount sufficient to improve resistance to deterioration of the resin of a compound in accordance with claim 13.
Claim 34
Dependent Claim
33 words
A polyurethane resin composition having improved resistance to deterioration comprising a polyurethane resin and an amount sufficient to improve resistance to deterioration of the resin of a compound in accordance with claim 13.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-09 | 1989-03-11 | 1989-09-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-09 | 1993-03-11 | 1993-09-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-09 | 1997-03-11 | 1997-09-10 | $7700.00 | Window Closed / Lapsed |