Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith

Claim 2

Normally solid, water-insoluble, fluorochemical guanidine compositions which are fluoroaliphatic radical-containing, substituted guanidine compounds, or compositions comprising mixtures thereof, said compounds having one or more monovalent fluoroaliphatic radicals having at least three fully fluorinated carbon atoms and one or more substituted guanidino moieties of the formula ##STR18## said radicals and moieties being bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH 3 )--, sulfonamido, carbonamido, sulonamidoalkylene, carbonamidolkylene, carbonyloxy, urethane, urea, and combinations thereof, with the proviso that when only one guanidino moiety is present, and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms of the moiety, and when more than one guanidine moiety is present, said moieties are bonded together by divalent linking groups selected from the group consisting of alkylene, aralkylene, arylene, polyoxyalkylene, and combinations thereof and can contain said fluoroaliphatic radical.

Claim 3

A fluorochemical guanidine represented by the formula ##STR19## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4-- , ##STR20## is --N(C 4 H 9 ) 2 , and n is 2.

Claim 4

A fluorochemical guanidine represented by the formula ##STR19## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4-- , ##STR20## is --N(C 4 H 9 ) 2 , and n is 2.

Claim 5

A fluorochemical guanidine represented by the formula ##STR21## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 --, R 2 --N--R 2 is ##STR22## and n is 1 to 6.

Claim 6

A fluorochemical guanidine represented by the formula ##STR21## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 --, R 2 --N--R 2 is ##STR22## and n is 1 to 6.

Claim 7

A fluorochemical guanidine represented by the formula ##STR23## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 , R 2 --N--R 2 is --N(iso--C 3 H 7 ) 2 , and n is 1 to 6.

Claim 8

A fluorochemical guanidine represented by the formula ##STR23## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --C 6 H 4 CH 2 C 6 H 4 , R 2 --N--R 2 is --N(iso--C 3 H 7 ) 2 , and n is 1 to 6.

Claim 9

A fiber comprising an organic solution or aqueous dispersion comprising the fluorochemical guanidine composition of claim 1.

Claim 10

The fiber finish according to claim 5 further comprising a fiber lubricant.

Claim 11

A method for imparting oil and water repellency to a fibrous substrate, which comprises treating the surface thereof with the fiber finish of claim 5.

Claim 12

In the manufacture of spun synthetic organic fibers wherein a fiber finish is applied to said fibers, the improvement comprising employing as said fiber finish the fiber finish of claim 6.

Claim 13

A fibrous substrate coated with the fluorochemical guanidine composition of claim 1.

Claim 14

A fibrous substrate according to claim 9 wherein said substrate is nylon carpet fiber.

Claim 15

A fluorochemical guanidine represented by the formula ##STR24## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is --N(C 4 H 9 ) 2 , and n is 1 to 6.

Claim 16

A fluorochemical guanidine represented by the formula ##STR24## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is --N(C 4 H 9 ) 2 , and n is 1 to 6.

Claim 17

A fluorochemical guanidine represented by the formula ##STR25## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is ##STR26## and n is 1 to 6.

Claim 18

A fluorochemical guanidine represented by the formula ##STR25## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is ##STR26## and n is 1 to 6.

Claim 19

A fluorochemical guanidine represented by the formula ##STR27## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is --N(iso--C 3 H 7 ) 2 , and n is 1 to 6.

Claim 20

A fluorochemical guanidine represented by the formula ##STR27## where R--Q is C 8 F 17 SO 2 N(C 2 H 5 )C 2 H 4 OCONH--, A is --CH 2 C 6 H 4 CH 2 --, R 2 --N--R 2 is --N(iso--C 3 H 7 ) 2 , and n is 1 to 6.

Claim 21

Normally solid, water-insoluble, fluorochemical guanidine compositions which are fluoroaliphatic radical-containing substituted guanidine compounds or compositions comprising a mixture of such compounds, said compounds being represented by the general formula ##STR28## where n is 0 to 20, x is 0 to 1, R 1 and R 2 are hydrogen atoms, a monovalent fluoroaliphatic radical, R f , having at least three fully fluorinated carbon atoms, or an organic radical selected from the group consisting of alkyl, cycloalkyl, aryl, and combinations thereof, A is a divalent linking group selected from the group consisting of alkylene, aralkylene, arylene polyoxyalkylene, and combinations thereof, which can contain said R f , and Q is a divalent hetero atom-containing or organic linking group selected from the group consisting of aliphatic aromatic aralkyl, fluoroaliphatic, and combinations thereof, with the proviso that at least one fluoroaliphatic radical, R f , is present in one or more of the R 1 , R 2 , and A groups, that where R 1 or R 2 is R f , x is 1, and that when only one guanidino moiety is present and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms.

Claim 22

Normally solid, water-insoluble, fluorochemical guanidine compositions which are fluoroaliphatic radical-containing substituted guanidine compounds or compositions comprising a mixture of such compounds, said compounds being represented by the general formula ##STR28## where n is 0 to 20, x is 0 to 1, R 1 and R 2 are hydrogen atoms, a monovalent fluoroaliphatic radical, R f , having at least three fully fluorinated carbon atoms, or an organic radical selected from the group consisting of alkyl, cycloalkyl, aryl, and combinations thereof, A is a divalent linking group selected from the group consisting of alkylene, aralkylene, arylene polyoxyalkylene, and combinations thereof, which can contain said R f , and Q is a divalent hetero atom-containing or organic linking group selected from the group consisting of aliphatic aromatic aralkyl, fluoroaliphatic, and combinations thereof, with the proviso that at least one fluoroaliphatic radical, R f , is present in one or more of the R 1 , R 2 , and A groups, that where R 1 or R 2 is R f , x is 1, and that when only one guanidino moiety is present and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms.

Claim 23

Fluorochemical guanidine compositions according to claim 14 wherein said R 1 and R 2 have no more than about 18 carbon atoms.

Claim 24

Fluorochemical guanidine compositions according to claim 14 wherein two R 2 groups of a guanidino are bonded together to form a cyclic structure with the adjacent nitrogen atom of that guanidino group.

Claim 25

Fluorochemical guanidine compositions according to claim 14 wherein said R 1 , R 2 , A, and Q are free of active hydrogen atoms that can react readily with isocyanate under urethane bond forming conditions.