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US4532264A Expired / Lapsed US ⏱️ 0.0 years remaining

Better foamable styrene and other olefin polymer compositions

Assignee: Dow Chemical Co
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Filing: 1984-04-27
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Granted: 1985-07-30
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Expires: 2004-04-27
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Abstract

Abstract Excellently properties, thermoplastic compositions well adapted for conversion by conventional melt-processing extrusion and other ordinary fabrication techniques into very good quality, lightly cross-linked, thermocollapse-resistant, closed-cell plastic foam(s) and the like expanded cellular product(s) are comprised of an intimate mixture of: (A) a sparsely hydroxylated, normally-solid olefin polymer, particularly a linear alkenyl aromatic or polyolefin polymer which is frequently at least substantially a styrene polymer which is generally in copolymeric form with appropriate moieties of comonomers adapted to provide the requisite attached hydroxyl units therein and thereon; and (B) a minor proportion of an inter-reactive, cross-linking polyisocyanate constituent.

Inventors

  • 👤 Louis C. Rubens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:47
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/6204; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08G2101/00

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 205 words
A lightly cross-linked expanded foam product of the composition comprising, in intimate admixture: (a) as a fundamental constituent, a hydroxylated, normally solid, linear polymer selected from the group consisting of linear olefin polymers, linear alkenyl aromatic copolymers, which is a polymerizate containing at least about 60 percent by weight, based on total polymer weight (i.e., "weight percent") of at least one polymerizable monomer of the general Formula: ##STR5## wherein: G is selected from the group consisting of hydrogen and methyl; and Ar is an aromatic radical, including alkyl and halo-ring-substituted aromatic units, that contains from 6 to about 10 carbon atoms; with the balance being copolymerized units of another addition polymerizable monomer or monomer mixture that is copolymerizable with styrene, the copolymer having a hydroxyl functionality of from 2 to 6average hydroxyl groups per unit weight average molecule; and (b) a substantially minor proportion of an inter-reactive crosslinking polyisocyanate constituent, with the further limitation that the copolymer have a crosslinking coefficient of from about 0.8 to about 3 which results in a visually detectable gel in a solvent which dissolves the corresponding noncrosslinked hydroxylated polymers, and that such composition on incorporation of a blowing agent therein is foamable to a thermal collapse resistant thermoplastic foam.
Claim 2
Dependent Claim 205 words
A lightly cross-linked expanded foam product of the composition comprising, in intimate admixture: (a) as a fundamental constituent, a hydroxylated, normally solid, linear polymer selected from the group consisting of linear olefin polymers, linear alkenyl aromatic copolymers, which is a polymerizate containing at least about 60 percent by weight, based on total polymer weight (i.e., "weight percent") of at least one polymerizable monomer of the general Formula: ##STR5## wherein: G is selected from the group consisting of hydrogen and methyl; and Ar is an aromatic radical, including alkyl and halo-ring-substituted aromatic units, that contains from 6 to about 10 carbon atoms; with the balance being copolymerized units of another addition polymerizable monomer or monomer mixture that is copolymerizable with styrene, the copolymer having a hydroxyl functionality of from 2 to 6average hydroxyl groups per unit weight average molecule; and (b) a substantially minor proportion of an inter-reactive crosslinking polyisocyanate constituent, with the further limitation that the copolymer have a crosslinking coefficient of from about 0.8 to about 3 which results in a visually detectable gel in a solvent which dissolves the corresponding noncrosslinked hydroxylated polymers, and that such composition on incorporation of a blowing agent therein is foamable to a thermal collapse resistant thermoplastic foam.
Claim 3
Dependent Claim 57 words
The foamed product of claim 1 wherein the composition is a lightly cross-linked polymeric network product of reaction in the melt from a molten composition in accordance with that of claim 1 wherein the cross-linking coefficient ("δ") value representing the number of cross-links per weight average molecule in the composition is between about 0.8 and about 3.

References Cited (Backward Citations)

US3313789A Cited
US3284415A Cited
US4234468A Cited
US4215023A Cited
US4262099A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-29 1989-01-28 1989-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-29 1993-01-28 1993-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-29 1997-01-28 1997-07-30 $7700.00 Window Closed / Lapsed

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