US4262099A
Expired / Lapsed
US
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Urethane compositions prepared from allyl alcohol polymers
Assignee: Solutia Inc
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Filing: 1979-11-01
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Granted: 1981-04-14
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Expires: 1999-11-01
Abstract
Abstract Urethane compositions prepared from terpolymers of a monovinyl aromatic monomer such as styrene, a C3-C7 allylic alcohol and an ester of a C3-C7 allylic alcohol and a C7-C12 monovalent aromatic acid, wherein the terpolymer preferably contains an average of from about 2 to 4 allylic alcohol units and at least one allylic ester unit per molecule. The compositions are useful as surface coatings, foundry resin binders, molding and encapsulating compounds and in the preparation of rigid and semi-rigid urethane foams.
Inventors
- 👤 John F. Heaps
- 👤 Donald M. Gardner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 05:42
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/62; C08G18/6212; C08G2110/00; C08G2110/0016; C08G2110/0025
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
141 words
A urethane composition comprising a polyisocyanate or polyisocyanate generating compound and a terpolymer of a C 8 -C 12 monovinyl aromatic monomer, a C 3 -C 7 allylic alcohol and an ester of a C 3 -C 7 allylic alcohol and a C 7 -C 12 monovalent aromatic acid, wherein the terpolymer has a number average molecular weight in the range of about 700 to about 3000 and contains at least about 40 weight percent of the monovinyl aromatic monomer, at least one allylic ester unit and on average from about 2 to about 2+x allylic alcohol units per terpolymer molecule, wherein x is a whole or fractional number in the range of 0 to about 2 and wherein the number of isocyanate groups or isocyanate generating groups is in the range of about 2 to about 2+x per terpolymer molecule.
Claim 2
Dependent Claim
141 words
A urethane composition comprising a polyisocyanate or polyisocyanate generating compound and a terpolymer of a C 8 -C 12 monovinyl aromatic monomer, a C 3 -C 7 allylic alcohol and an ester of a C 3 -C 7 allylic alcohol and a C 7 -C 12 monovalent aromatic acid, wherein the terpolymer has a number average molecular weight in the range of about 700 to about 3000 and contains at least about 40 weight percent of the monovinyl aromatic monomer, at least one allylic ester unit and on average from about 2 to about 2+x allylic alcohol units per terpolymer molecule, wherein x is a whole or fractional number in the range of 0 to about 2 and wherein the number of isocyanate groups or isocyanate generating groups is in the range of about 2 to about 2+x per terpolymer molecule.
Claim 3
Dependent Claim
58 words
The composition of claim 1 wherein the terpolymer has a number average molecular weight in the range of about 900 to about 1800 and wherein the weight percentage range of monovinyl aromatic monomer is about 40 to about 85, of allylic alcohol is about 6 to about 17, and of allylic ester is about 9 to about 54.
Claim 4
Dependent Claim
58 words
The composition of claim 1 or 2 wherein the monovinyl aromatic monomer is selected from the group consisting of styrene and vinyl toluene, the allylic alcohol is selected from the group consisting of allyl alcohol and methallyl alcohol and the allylic ester is selected from the group consisting of allyl benzoate, allyl toluate, methallyl benzoate and methallyl toluate.
Claim 5
Dependent Claim
27 words
The composition of claim 1 or 2 wherein the monovinyl aromatic monomer is styrene, the allylic alcohol is allyl alcohol and the allylic ester is allyl benzoate.
Claim 6
Dependent Claim
11 words
A substrate coated with the composition of claims 1 or 2.
Claim 7
Dependent Claim
9 words
A substrate coated with the composition of claim 3.
Claim 8
Dependent Claim
9 words
A substrate coated with the composition of claim 4.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-13 | 1984-10-13 | 1985-04-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-13 | 1988-10-13 | 1989-04-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-13 | 1992-10-13 | 1993-04-14 | $7700.00 | Window Closed / Lapsed |