US4532054A
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Polyetherimide bearing compositions
Assignee: General Electric Co
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Filing: 1984-07-02
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Granted: 1985-07-30
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Expires: 2004-07-02
Abstract
Abstract Nonmetallic bearing compositions contain a polyetherimide resin and, as modifiers and reinforcements, a fluoropolymer, such as polytetrafluoroethylene, a lubricating agent selected from the group consisting of molybdenum disulfide, graphite or a silicone fluid, molybdenum disulfide-containing lubricant or any mixture thereof, and a reinforcing agent selected from the group consisting of glass fibers, carbon fibers and glass beads. The present compositions can be fabricated into a variety of shapes by injection molding, and have excellent wear resistance, load-bearing capabilities, and low coefficients of friction without the use of external lubrication.
Inventors
- 👤 Robert O. Johnson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:28
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; F; F16; F16C; F16C33/00; F16C33/02; F16C33/04; F16C33/20; F16C33/201
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
284 words
A bearing composition which comprises a polyetherimide resin of the formula: ##STR13## and the following modifiers and reinforcements: (a) from about 1% to about 25% by wt. of a fluoropolymer; (b) from about 1% to about 25% by wt. of a lubricating agent selected from the group consisting of silicone fluid, a molybdenum disulfide, graphite or a molybdenum disulfide-containing solid lubricant, or any mixture thereof; and (c) from 0% to about 50% of a reinforcing agent selected from the group consisting of glass fibers, carbon fibers, glass beads and mixtures thereof; wherein the above proportions are selected such that said bearing compositions contain from about 35% by wt. to about 60% by wt. polyetherimide resin and from about 40% by wt. to about 65% by wt. modifiers and reinforcements; wherein "a" represents a whole number from about 10 to about 10,000, the group --O--A< is selected from: ##STR14## wherein R' is hydrogen, lower alkyl or lower alkoxy; Z is a member of the class consisting of (1) ##STR15## and (2) divalent organic radicals of the general formula ##STR16## where X is a member selected from the class consisting of divalent radicals of the formula: ##STR17## where q is 0 or 1, y is a whole number from 1 to 5 and R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6 to 20 carbon atoms and halogenated derivatives thereof, (2) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals of the formula ##STR18## where Q is a member selected from the class consisting of ##STR19## where x is a whole number from 1 to 5 inclusive.
Claim 2
Dependent Claim
284 words
A bearing composition which comprises a polyetherimide resin of the formula: ##STR13## and the following modifiers and reinforcements: (a) from about 1% to about 25% by wt. of a fluoropolymer; (b) from about 1% to about 25% by wt. of a lubricating agent selected from the group consisting of silicone fluid, a molybdenum disulfide, graphite or a molybdenum disulfide-containing solid lubricant, or any mixture thereof; and (c) from 0% to about 50% of a reinforcing agent selected from the group consisting of glass fibers, carbon fibers, glass beads and mixtures thereof; wherein the above proportions are selected such that said bearing compositions contain from about 35% by wt. to about 60% by wt. polyetherimide resin and from about 40% by wt. to about 65% by wt. modifiers and reinforcements; wherein "a" represents a whole number from about 10 to about 10,000, the group --O--A< is selected from: ##STR14## wherein R' is hydrogen, lower alkyl or lower alkoxy; Z is a member of the class consisting of (1) ##STR15## and (2) divalent organic radicals of the general formula ##STR16## where X is a member selected from the class consisting of divalent radicals of the formula: ##STR17## where q is 0 or 1, y is a whole number from 1 to 5 and R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6 to 20 carbon atoms and halogenated derivatives thereof, (2) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals of the formula ##STR18## where Q is a member selected from the class consisting of ##STR19## where x is a whole number from 1 to 5 inclusive.
Claim 3
Dependent Claim
12 words
The bearing composition of claim 1, wherein the group --O--A< is ##STR20##
Claim 4
Dependent Claim
14 words
The bearing composition of claim 2, wherein Z is ##STR21## and R is ##STR22##
Claim 5
Dependent Claim
24 words
The bearing composition of claim 1, wherein the polyetherimide resin has the formula ##STR23## wherein n is an integer from 10 to about 100.
Claim 6
Dependent Claim
60 words
The bearing composition of claim 1, 2, 3, or 4 wherein the polyetherimide resin has a glass transition temperature of at least about 200° C., the fluoropolymer is polytetrafluoroethylene, has a particle size from about 1 to about 25 microns, and is present at a concentration of from about 5% by wt. to about 20% by wt. of the composition.
Claim 7
Dependent Claim
38 words
The bearing composition of claim 5, wherein the lubricating agent is molybdenum disulfide or a molybdenum disulfide-containing lubricant and is present at a concentration of from about 1% by wt. to about 15% by wt. of the composition.
Claim 8
Dependent Claim
32 words
The bearing composition of claim 5, wherein the lubricating agent is silicone fluid and is present at a concentration of about 1% by wt. to about 5% by wt. of the composition.
Claim 9
Dependent Claim
32 words
The bearing composition of claim 5, wherein the lubricating agent is graphite and is present at a concentration of from about 5% by wt. to about 20% by wt. of the composition.
Claim 10
Dependent Claim
61 words
The bearing composition of claim 6, wherein the reinforcing agent is glass fiber having chopped strands with average lengths from about 3 mm to about 6 mm and average diameters of from about 5 microns to about 15 microns, wherein said glass fiber is present at a concentration from about 5% by wt. to about 40% by wt. of the composition.
Claim 11
Dependent Claim
60 words
The bearing composition of claim 6, wherein the reinforcing agent is carbon fiber having strands of average lengths from about 0.4 mm to about 6 mm and average diameters of from about 5 microns to about 25 microns, wherein said carbon fiber is present at a concentration from about 5% by wt. to about 30% by wt. of the composition.
Claim 12
Dependent Claim
50 words
The bearing composition of claim 6, wherein the reinforcing agent contains glass beads having an average particle size of from about 1 to about 53 microns, and wherein said glass beads are present at a concentration of from about 5% by wt. to about 40% by wt. of the composition.
Claim 13
Dependent Claim
21 words
The bearing composition of claim 8, wherein the polyetherimide resin has a glass transition temperature of at least about 215° C.
Claim 14
Dependent Claim
128 words
The bearing composition of claim 4, wherein the polytetrafluoroethylene has a particle size of from 5 to about 10 microns and is present at a concentration of about 15% by wt. of the composition; the lubricating agent is a combination of molybdenum disulfide having a particle size from about 200 to about 300 mesh, present at a concentration of about 2.5% by wt. of the composition, and graphite having a particle size from about 200 to about 300 mesh, present at a concentration of about 10% by wt. of the composition; the reinforcing agent is silane-treated glass fiber having chopped strands with average lengths about 3 mm and average diameters of about 10 microns and is present at a concentration of about 25% by wt. of the composition.
Claim 15
Dependent Claim
25 words
A method for forming a nonmetallic bearing which comprises injection molding the composition of claim 1, 2, 3, 4 or 13 to the desired shape.
Claim 16
Dependent Claim
15 words
A nonmetallic bearing formed from the composition of claim 1, 2, 3, 4 or 13.
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