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US4524093A Expired / Lapsed US ⏱️ 0.0 years remaining

Fabric coating composition with low formaldehyde evolution

Assignee: Goodrich Corp
•
Filing: 1984-04-30
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Granted: 1985-06-18
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Expires: 2004-04-30
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Abstract

Abstract An improved polymeric latex coating composition, which substantially comprises an aqueous emulsion of alkyl acrylate monomers; copolymerized with acrylonitrile, itaconic acid, and N-methylol acrylamide; and containing a glyoxal curing resin and an acid catalyst, substantially reduces the evolution of formaldehyde and exhibits good durability.

Inventors

  • 👤 William E. deVry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:26
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/39; C; C08; C08L; C08L61/00; C08L61/20; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/08

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 74 words
In an aqueous acrylic latex coating composition, the improvement which essentially comprises incorporating into the latex from about 1% to about 15% by dry weight of an imidazolidone curing resin of the formula ##STR2## where X=--H, or --OH; and R=--CH 2 O--R' where R' is alkyl having 1-10 carbons, and from about 0.5% to about 10% by dry weight of a metal chloride-type acid catalyst wherein said improvement substantially reduces formaldehyde evolution during curing.
Claim 2
Dependent Claim 74 words
In an aqueous acrylic latex coating composition, the improvement which essentially comprises incorporating into the latex from about 1% to about 15% by dry weight of an imidazolidone curing resin of the formula ##STR2## where X=--H, or --OH; and R=--CH 2 O--R' where R' is alkyl having 1-10 carbons, and from about 0.5% to about 10% by dry weight of a metal chloride-type acid catalyst wherein said improvement substantially reduces formaldehyde evolution during curing.
Claim 3
Dependent Claim 60 words
A composition of claim 1 wherein the acrylic latex contains from about 45% to about 95% by dry weight of one or more alkyl acrylates or methacryates, from about 1% to about 15% by dry weight acrylonitrile, from about 1% to about 4% by dry weight itaconic acid, and from about 0.5% to about 4% by dry weight N-methylol acrylamide.
Claim 4
Dependent Claim 14 words
A composition of claim 1 wherein the catalyst comprises magnesium chloride and citric acid.
Claim 5
Dependent Claim 81 words
A process for substantially reducing the formaldehyde evolution from a fabric coating during curing which comprises the steps of applying to a fabric and curing an aqueous acrylic latex coating composition containing from about 1% to about 10% by dry weight of an imidazolidone curing resin having the formula ##STR3## where X=--H, or --OH; and R=--CH 2 O--R', where R' is alkyl having 1-10 carbons, and from about 0.5% to about 10% by dry weight of a metal chloride-type acid catalyst.
Claim 6
Dependent Claim 81 words
A process for substantially reducing the formaldehyde evolution from a fabric coating during curing which comprises the steps of applying to a fabric and curing an aqueous acrylic latex coating composition containing from about 1% to about 10% by dry weight of an imidazolidone curing resin having the formula ##STR3## where X=--H, or --OH; and R=--CH 2 O--R', where R' is alkyl having 1-10 carbons, and from about 0.5% to about 10% by dry weight of a metal chloride-type acid catalyst.
Claim 7
Dependent Claim 14 words
A process of claim 4 wherein the catalyst comprises magnesium chloride and citric acid.
Claim 8
Dependent Claim 62 words
A process of claim 4 wherein the acrylic latex coating composition contains from about 45% to about 95% by dry weight of one or more alkyl acrylates or methacrylates, from about 1% to about 15% by dry weight acrylonitrile, from about 1% to about 4% by dry weight itaconic acid, and from about 0.5% to about 4% by dry weight N-methylol acrylamide.
Claim 9
Dependent Claim 20 words
A composition of claim 1 wherein the imidazolidone is selected from the group consisting of di-methoxy-methyl-dihydroxy-ethylene urea and di-ethoxy-methyl-dihydroxy-ethylene urea.
Claim 10
Dependent Claim 20 words
A process of claim 4 wherein the imidazolidone is selected from the group consisting of di-methoxy-methyl-dihydroxy-ethylene urea and di-ethoxy-methyl-dihydroxy-ethylene urea.
Claim 11
Dependent Claim 19 words
A process of claim 4 wherein said acrylic latex coating composition is used as a backcoating for textile fabrics.

References Cited (Backward Citations)

US3157562A Cited
US4076870A Cited
US4198462A Cited
US4263190A Cited
US4306872A Cited
US4295846A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-17 1988-12-17 1989-06-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-17 1992-12-17 1993-06-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-17 1996-12-17 1997-06-18 $7700.00 Window Closed / Lapsed

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