US4263190A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Adhesion of textile cords to rubber using a butadiene-styrene vinylpyridine rubber latex and an aldehyde condensate-glyoxal reaction products mixture
Assignee: Wyeth Holdings LLC
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Filing: 1979-12-26
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Granted: 1981-04-21
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Expires: 1999-12-26
Abstract
Abstract A cord dip composition comprising a styrene-butadiene-vinyl pyridine terpolymer latex and a mixture of an aldehyde condensate and a glyoxal reaction product, are disclosed.
Inventors
- 👤 Daniel M. Zavisza
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 16:57
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C09; C09J; C09J125/00; C09J125/02; C09J125/04; C09J125/08; C09J125/10; D; D06; D06M; D06M15/00; D06M15/693; C08J2321/00; C08L; C08L2666/00; C08L2666/02; C08L2666/14; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2964; Y10T428/2967; Y10T428/2969
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
174 words
A composition which consists essentially of (I) a styrene-butadiene-vinylpyridine terpolymer latex and (II) a mixture of from about 10 to 90 percent, by weight, based on the total weight of said mixture, of (A) an aldehyde condensate comprising (1) those represented by formula: ##STR5## wherein each X represents hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), or (2) those represented by formula: ##STR6## wherein each Y is selected from hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), and from about 90 to 10 percent, by weight of (B) a glyoxal reaction product comprising: (a) those which are the products of reaction of from about 0.1 to 10 molar proportions of urea with one molar proportion of glyoxal or (b) those which are the products of reaction of 0.1 to 10 molar proportions of urea and from 0.01 to 2 molar proportions of formaldehyde with one molar proportion of glyoxal; provided that each of said (A) and (B) in said mixture contains at least two reaction hydroxyl, hydroxymethyl, or alkoxymethyl groups per molecule.
Claim 2
Dependent Claim
174 words
A composition which consists essentially of (I) a styrene-butadiene-vinylpyridine terpolymer latex and (II) a mixture of from about 10 to 90 percent, by weight, based on the total weight of said mixture, of (A) an aldehyde condensate comprising (1) those represented by formula: ##STR5## wherein each X represents hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), or (2) those represented by formula: ##STR6## wherein each Y is selected from hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), and from about 90 to 10 percent, by weight of (B) a glyoxal reaction product comprising: (a) those which are the products of reaction of from about 0.1 to 10 molar proportions of urea with one molar proportion of glyoxal or (b) those which are the products of reaction of 0.1 to 10 molar proportions of urea and from 0.01 to 2 molar proportions of formaldehyde with one molar proportion of glyoxal; provided that each of said (A) and (B) in said mixture contains at least two reaction hydroxyl, hydroxymethyl, or alkoxymethyl groups per molecule.
Claim 3
Dependent Claim
12 words
A composition according to claim 1 wherein said (A) is hexakismethoxymethyl melamine.
Claim 4
Dependent Claim
12 words
A composition according to claim 1 wherein said (A) is tris(methoxymethyl) melamine.
Claim 5
Dependent Claim
11 words
A composition according to claim 1 wherein said (B) is 4,5-dihydroxy-2-imidazolidinone.
Claim 6
Dependent Claim
11 words
A composition according to claim 1 wherein said (B) is 1,3-dimethylol-4,5-dihydroxy-2-imidazolidinone.
Claim 7
Dependent Claim
48 words
A method for forming a strong adhesive bond between a vulcanized natural or synthetic rubber composition and a textile fiber embedded therein which comprises dipping the textile fiber in the composition of claim 1, imbedding the so-dipped fiber in a vulcanizable rubber composition and vulcanizing said rubber composition.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-20 | 1984-10-20 | 1985-04-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-20 | 1988-10-20 | 1989-04-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-20 | 1992-10-20 | 1993-04-21 | $7700.00 | Window Closed / Lapsed |