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US4263190A Expired / Lapsed US ⏱️ 0.0 years remaining

Adhesion of textile cords to rubber using a butadiene-styrene vinylpyridine rubber latex and an aldehyde condensate-glyoxal reaction products mixture

Assignee: Wyeth Holdings LLC
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Filing: 1979-12-26
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Granted: 1981-04-21
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Expires: 1999-12-26
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Abstract

Abstract A cord dip composition comprising a styrene-butadiene-vinyl pyridine terpolymer latex and a mixture of an aldehyde condensate and a glyoxal reaction product, are disclosed.

Inventors

  • 👤 Daniel M. Zavisza

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:57
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C09; C09J; C09J125/00; C09J125/02; C09J125/04; C09J125/08; C09J125/10; D; D06; D06M; D06M15/00; D06M15/693; C08J2321/00; C08L; C08L2666/00; C08L2666/02; C08L2666/14; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2964; Y10T428/2967; Y10T428/2969

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 174 words
A composition which consists essentially of (I) a styrene-butadiene-vinylpyridine terpolymer latex and (II) a mixture of from about 10 to 90 percent, by weight, based on the total weight of said mixture, of (A) an aldehyde condensate comprising (1) those represented by formula: ##STR5## wherein each X represents hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), or (2) those represented by formula: ##STR6## wherein each Y is selected from hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), and from about 90 to 10 percent, by weight of (B) a glyoxal reaction product comprising: (a) those which are the products of reaction of from about 0.1 to 10 molar proportions of urea with one molar proportion of glyoxal or (b) those which are the products of reaction of 0.1 to 10 molar proportions of urea and from 0.01 to 2 molar proportions of formaldehyde with one molar proportion of glyoxal; provided that each of said (A) and (B) in said mixture contains at least two reaction hydroxyl, hydroxymethyl, or alkoxymethyl groups per molecule.
Claim 2
Dependent Claim 174 words
A composition which consists essentially of (I) a styrene-butadiene-vinylpyridine terpolymer latex and (II) a mixture of from about 10 to 90 percent, by weight, based on the total weight of said mixture, of (A) an aldehyde condensate comprising (1) those represented by formula: ##STR5## wherein each X represents hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), or (2) those represented by formula: ##STR6## wherein each Y is selected from hydrogen, hydroxymethyl, or alkoxymethyl (C 1 -C 4 alkoxy), and from about 90 to 10 percent, by weight of (B) a glyoxal reaction product comprising: (a) those which are the products of reaction of from about 0.1 to 10 molar proportions of urea with one molar proportion of glyoxal or (b) those which are the products of reaction of 0.1 to 10 molar proportions of urea and from 0.01 to 2 molar proportions of formaldehyde with one molar proportion of glyoxal; provided that each of said (A) and (B) in said mixture contains at least two reaction hydroxyl, hydroxymethyl, or alkoxymethyl groups per molecule.
Claim 3
Dependent Claim 12 words
A composition according to claim 1 wherein said (A) is hexakismethoxymethyl melamine.
Claim 4
Dependent Claim 12 words
A composition according to claim 1 wherein said (A) is tris(methoxymethyl) melamine.
Claim 5
Dependent Claim 11 words
A composition according to claim 1 wherein said (B) is 4,5-dihydroxy-2-imidazolidinone.
Claim 6
Dependent Claim 11 words
A composition according to claim 1 wherein said (B) is 1,3-dimethylol-4,5-dihydroxy-2-imidazolidinone.
Claim 7
Dependent Claim 48 words
A method for forming a strong adhesive bond between a vulcanized natural or synthetic rubber composition and a textile fiber embedded therein which comprises dipping the textile fiber in the composition of claim 1, imbedding the so-dipped fiber in a vulcanizable rubber composition and vulcanizing said rubber composition.

References Cited (Backward Citations)

US3194294A Cited
US3260565A Cited
US3361617A Cited
US3773612A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-20 1984-10-20 1985-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-20 1988-10-20 1989-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-20 1992-10-20 1993-04-21 $7700.00 Window Closed / Lapsed

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