US4522470A
Expired / Lapsed
US
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Liquid crystal composition and display device
Assignee: Epson Corp
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Filing: 1983-07-05
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Granted: 1985-06-11
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Expires: 2003-07-05
Abstract
Abstract Liquid crystal compositions for use in multiplex operations have a positive dielectric anisotropy of about 0.10 to about 0.12. Liquid crystal display devices having cell thicknesses of about 4 to 6 microns incorporate such liquid crystal compositions and operate at a duty ratio of 1/16 and voltages no greater than 5 V.
Inventors
- 👤 Chiyoaki Iijima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 22:25
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/42; C09K19/46
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
165 words
A liquid crystal composition comprising at least one of each of compounds represented by the formulas (1), (2), (3), and (4): ##STR7## wherein, R 1 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 2 to 5 carbon atoms; R 4 is a straight-chain alkyl group having 3 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 1 to 7 carbon atoms; R 6 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 7 is a straight-chain alkyl group having 1 to 5 carbon atoms, and wherein compound (1) is present between about 40 to 70% by weight, compound (2) is present between about 25 to 45% by weight, compound (3) is present between about 3 to 15% by weight, and compound (4) is present between about 3 to 15% by weight of the composition.
Claim 2
Dependent Claim
165 words
A liquid crystal composition comprising at least one of each of compounds represented by the formulas (1), (2), (3), and (4): ##STR7## wherein, R 1 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 2 to 5 carbon atoms; R 4 is a straight-chain alkyl group having 3 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 1 to 7 carbon atoms; R 6 is a straight-chain alkyl group having 3 to 5 carbon atoms; and R 7 is a straight-chain alkyl group having 1 to 5 carbon atoms, and wherein compound (1) is present between about 40 to 70% by weight, compound (2) is present between about 25 to 45% by weight, compound (3) is present between about 3 to 15% by weight, and compound (4) is present between about 3 to 15% by weight of the composition.
Claim 3
Dependent Claim
34 words
A liquid composition according to claim 1, wherein R 5 is straight-chain alkyl group having 2 to 5 carbon atoms and R 7 is a straight-chain alkyl group having 4 or 5 carbon atoms.
Claim 4
Dependent Claim
56 words
A liquid composition according to claim 1, wherein compound (1) is present between about 45 to 65% by weight, compound (2) is present between about 25 to 43% by weight, compound (3) is present between about 4 to 11% by weight, and compound (4) is present between about 4 to 8% by weight of the composition.
Claim 5
Dependent Claim
41 words
A liquid composition according to claim 1, including about 56.5 percent by weight of compound (1); about 27.5 percent by weight of compound (2); about 8 percent by weight of compound (3); and about 8 percent by weight of compound (4).
Claim 6
Dependent Claim
41 words
A liquid composition according to claim 3, including about 45.0 percent by weight of compound (1); about 41.0 percent by weight of compound (2); about 7.0 percent by weight of compound (3); and about 7.0 percent by weight of compound 4.
Claim 7
Dependent Claim
41 words
A liquid composition according to claim 3, including about 50.0 percent by weight of compound (1); about 36.0 percent by weight of compound (2); about 7.0 percent by weight of compound (3); and about 7.0 percent by weight of compound 4.
Claim 8
Dependent Claim
41 words
A liquid composition according to claim 3, including about 64 percent by weight of compound (1); about 28 percent by weight of compound (2); about 4 percent by weight of compound (3); and about 4 percent by weight of compound (4).
Claim 9
Dependent Claim
41 words
A liquid composition according to claim 3, including about 55 percent by weight of compound (1); about 28 percent by weight of compound (2); about 11 percent by weight of compound (3); and about 6 percent by weight of compound (4).
Claim 10
Dependent Claim
22 words
A liquid crystal composition according to claim 1 wherein the optical anisotropy of the liquid crystal composition is about 0.1 to 0.12.
Claim 11
Dependent Claim
214 words
A liquid crystal display device comprising opposed, spaced-apart transparent substrates, electrodes selectively deposited on the interior surfaces of each substrate, a nematic liquid crystal composition having positive dielectric anistropy disposed between said substrates, and a polarizer on the outer surface of each substrate, said liquid crystal composition comprising at least one of each of compounds represented by the formulas (1), (2), (3), and (4): ##STR8## wherein, R 1 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 2 to 5 carbon atoms; R 4 is a straight-chain alkyl group having 3 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 1 to 7 carbon atoms; R 6 is a straight-chain alkyl group having 3 to 5 carbon atoms, and R 7 is a straight-chain alkyl group having 1 to 5 carbon atoms, and wherein said liquid crystal composition comprises from about 40 to 70% by weight of compounds of formula (1), from about 25 to 45% by weight of compounds of formula (2), from about 3 to 15% by weight of compounds of formula (3), and from about 3 to 15% by weight of compounds of formula (4).
Claim 12
Dependent Claim
214 words
A liquid crystal display device comprising opposed, spaced-apart transparent substrates, electrodes selectively deposited on the interior surfaces of each substrate, a nematic liquid crystal composition having positive dielectric anistropy disposed between said substrates, and a polarizer on the outer surface of each substrate, said liquid crystal composition comprising at least one of each of compounds represented by the formulas (1), (2), (3), and (4): ##STR8## wherein, R 1 is a straight-chain alkyl group having 3 to 6 carbon atoms; R 2 is a straight-chain alkyl group having 1 to 6 carbon atoms; R 3 is a straight-chain alkyl group having 2 to 5 carbon atoms; R 4 is a straight-chain alkyl group having 3 to 5 carbon atoms; R 5 is a straight-chain alkyl group having 1 to 7 carbon atoms; R 6 is a straight-chain alkyl group having 3 to 5 carbon atoms, and R 7 is a straight-chain alkyl group having 1 to 5 carbon atoms, and wherein said liquid crystal composition comprises from about 40 to 70% by weight of compounds of formula (1), from about 25 to 45% by weight of compounds of formula (2), from about 3 to 15% by weight of compounds of formula (3), and from about 3 to 15% by weight of compounds of formula (4).
Claim 13
Dependent Claim
23 words
A liquid crystal display device according to claim 10 wherein the optical anistropy of the liquid crystal composition is about 0.1 to 0.12.
Claim 14
Dependent Claim
18 words
A liquid crystal display device according to claim 10, wherein the cell thickness is about 4 to 6μ.
Claim 15
Dependent Claim
18 words
A liquid crystal display device according to claim 11, wherein the cell thickness is about 4 to 6μ.
Claim 16
Dependent Claim
26 words
A liquid crystal display device according to claim 10 further including time-sharing circuit means for generating time-sharing signals and selectively applying said signals to the electrodes.
Claim 17
Dependent Claim
18 words
A liquid crystal display device according to claim 14 having a duty ratio of up to about 1/16.
Claim 18
Dependent Claim
23 words
A liquid crystal display device according to claim 15 which operates at a voltage of no more than 5 V at room temperature.
Claim 19
Dependent Claim
83 words
A liquid crystal composition according to claim 1, further including at least one compound represented by the formulas (5) and (6): ##STR9## wherein, R 8 is a straight-chain alkyl group having 2 to 8 carbon atoms; R 9 and R 10 each is a straight-chain alkyl group having 2 to 5 carbon atoms, and wherein said at least one compound represented by formulas (5) and (6) is present in an amount between about 1 to 10% by weight of the liquid crystal composition.
Claim 20
Dependent Claim
25 words
A liquid crystal composition according to claim 1, further including at least at least one compound represented by the formulas (7), (8), and (9): ##STR10##
Claim 21
Dependent Claim
32 words
A liquid crystal composition according to claim 18, wherein each of the compounds represented by formulas (7), (8) and (9) is included in an amount between about 0.01 to 3% by weight.
Claim 22
Dependent Claim
89 words
A liquid crystal display device according to claim 10, wherein said nematic crystal composition further includes at least one compound represented by the formulas (5) and (6): ##STR11## wherein, R 8 is a straight-chain alkyl group having 2 to 8 carbon atoms; R 9 and R 10 each is a straight-chain alkyl group having 2 to 5 carbon atoms, and wherein said at least one compound represented by formulas (5) and (6) is included in an amount between about 1 to 10% by weight of said liquid crystal composition.
Claim 23
Dependent Claim
29 words
A liquid crystal display device according to claim 10, wherein said liquid crystal composition further includes at least one compound represented by the formulas (7), (8), and (9): ##STR12##
Claim 24
Dependent Claim
40 words
A liquid crystal display device according to claim 21, wherein said at least one compound represented by the formulas (7), (8) and (9) is included in an amount between about 0.01 to 3% by weight in said liquid crystal composition.
Claim 25
Dependent Claim
18 words
A liquid crystal composition according to claim 1, further including compounds represented by formulas (7) and (8): ##STR13##
Claim 26
Dependent Claim
30 words
A liquid crystal composition according to claim 23, wherein said compounds represented by formulas (7) and (8) are included in a total amount between about 0.01 to 3% by weight.
Claim 27
Dependent Claim
25 words
A liquid crystal display device according to claim 10, wherein said nematic liquid crystal composition further includes compounds represented by formulas (7) and (8): ##STR14##
Claim 28
Dependent Claim
31 words
A liquid crystal display device according to claim 25, wherein said compounds represented by formulas (7) and (8) are included in a total amount between about 0.01 to 3% by weight.
References Cited (Backward Citations)
US4372871A
Cited
US4229315A
Cited
GB2028363A
Cited
DE2934918A1
Cited
GB2017742A
Cited
US4322354A
Cited
JPS562371A
Cited
US4309304A
Cited
US4328116A
Cited
US4364838A
Cited
GB2067586A
Cited
JPS56149487A
Cited
JPS56149488A
Cited
US4410445A
Cited
JPS5785881A
Cited
US4313878A
Cited
US4323472A
Cited
US4323471A
Cited
EP0074608A2
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-10 | 1988-12-10 | 1989-06-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-10 | 1992-12-10 | 1993-06-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-10 | 1996-12-10 | 1997-06-11 | $7700.00 | Window Closed / Lapsed |