End-capping catalysts for forming alkoxy-functional one component RTV compositions

Claim 2

A one-package substantially anhydrous room temperature vulcanizable organopolysiloxane composition convertible to a tack-free elastomer, comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical; (2) an effective amount of cross-linking agent; and (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof.

Claim 3

The composition of claim 1 wherein the cross-linking agent has the formula ##STR39## where R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylester, alkylketone and alkylcyano radicals of a C.sub.(7-13) arakyl radical, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical and b is a whole number equal to 0 or 1.

Claim 4

The composition of claim 1 wherein ingredient (3)(i) of the end-capping catalyst is an acid anhydride.

Claim 5

The composition of claim 1 wherein ingredient (3)(i) of the end-capping catalyst has the formula ##STR40## where R 30 and R 31 are C.sub.(1-20) monovalent hydrocarbon radicals and j is a whole number that varies from 0 to 3.

Claim 6

The composition of claim 1 wherein ingredient (3) (i) of the end-capping catalyst has the formula ##STR41## where R 32 is a C.sub.(1-20) monovalent hydrocarbon radical.

Claim 7

The composition of claim 1 wherein ingredient (3) (i) of the end-capping catalyst is an inorganic acid.

Claim 8

The composition of claim 6 wherein the inorganic acid is selected from the class consisting of HCl, H 3 PO 4 , H 2 SO 4 , and polyphosphoric acid.

Claim 9

The composition of claim 3 wherein the acid anhydride has the formula ##STR42## where R 33 , R 34 are C.sub.(1-20) monovalent hydrocarbon radicals.

Claim 10

The composition of claim 1 wherein ingredient (3) (i) of the end-capping catalyst is selected from the group consisting of BF.sub.3, (CH.sub.3 CH.sub.2).sub.2 O, and AlCl.sub.3.

Claim 11

The composition of claim 1 wherein the total acid number does not exceed 15.

Claim 12

The composition of claim 1 wherein the acid number is at least 0.1.

Claim 13

The composition of claim 1 wherein ingredient (3) (i) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane and ingredient (3) (ii) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane.

Claim 14

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical: (2) an effective amount of a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (4) a stabilizing amount of silane scavenger for hydroxy functional groups having the formula ##STR43## wherein R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, and alkylcyano radicals, or a C.sub.(7-13) aralkyl radicl, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical, X is a hydrolyzable leaving group selected from the group consisting of amido, amino, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato, and ureido radicals and, c is a whole number equal to 0 to 3 inclusive, f is an integer equal to 1 to 4 inclusive and the sum of c+f is equal to 1 to 4 inclusive; and (5) an effective amount of a condensation catalyst.

Claim 15

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical: (2) an effective amount of a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (4) a stabilizing amount of silane scavenger for hydroxy functional groups having the formula ##STR43## wherein R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, and alkylcyano radicals, or a C.sub.(7-13) aralkyl radicl, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical, X is a hydrolyzable leaving group selected from the group consisting of amido, amino, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato, and ureido radicals and, c is a whole number equal to 0 to 3 inclusive, f is an integer equal to 1 to 4 inclusive and the sum of c+f is equal to 1 to 4 inclusive; and (5) an effective amount of a condensation catalyst.

Claim 16

The composition of claim 13 wherein the cross-linking agent has the formula ##STR44## where R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylester, alkylketone and alkylcyano radicals or a C.sub.(7-13) arakyl radical, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical and b is a whole number equal to 0 or 1.

Claim 17

The composition of claim 13 wherein ingredient (3) (i) of the end-capping catalyst is an acid anhydride.

Claim 18

The composition of claim 13 wherein ingredient (3) (i) of the end-capping catalyst has the formula ##STR45## where R 30 and R 31 are C.sub.(1-20) monovalent hydrocarbon radicals and j is a whole number that varies from 0 to 3.

Claim 19

The composition of claim 13 wherein ingredient (3) (i) of the end-capping catalyst has the formula ##STR46## where R 32 is a C.sub.(1-20) monovalent hydrocarbon radical.

Claim 20

The composition of claim 13 wherein ingredient (3) (i) of the end-capping catalyst is an inorganic acid.

Claim 21

The composition of claim 18 wherein the inorganic acid is selected from the class consisting of HCl, H 3 PO 4 , H 2 SO 4 , and polyphosphoric acid.

Claim 22

The composition of claim 15 wherein the acid anhydride has the formula ##STR47## where R 33 , R 34 are C.sub.(1-20) monovalent hydrocarbon radicals.

Claim 23

The composition of claim 13 wherein ingredient (3) (i) of the end-capping catalyst is selected from the group consisting of BF 3 , (CH 3 CH 2 ) 2 O, and AlCl 3 .

Claim 24

The composition of claim 13 wherein the total acid number does not exceed 15.

Claim 25

The composition of claim 13 wherein the total acid number is at least 0.1.

Claim 26

The composition of claim 13 wherein ingredient (3) (i) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane and ingredient (3) (ii) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane.

Claim 27

The composition of claim 13 wherein the scavenging silane has the formula ##STR48## where R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals, or a C.sub.(7-13) aralkyl radical, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical, X is a hydrolyzable leaving group selected from the group consisting of amido, amino, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato and ureido radicals; and, a is an integer equal to 1 or 2 inclusive, b is a whole number equal to 0 to 1 inclusive and silane is both the silane scavenger for hydroxy functional groups and a polyalkoxysilane cross-linking agent for terminating the silicon atom at each organopolysiloxane chain end with at least two alkoxy radicals.

Claim 28

A room temperature vulcanizable composition in accordance with claim 13 where the silane scavenger is methyldimethoxy-N-methylacetamidosilane.

Claim 29

A room temperature vulcanizable composition in accordance with claim 13, which contains a tin compound as the condensation catalyst.

Claim 30

A room temperature vulcanizable composition in accordance with claim 13, where R, R 1 and R 2 are methyl and which has a tin compound as a condensation catalyst.

Claim 31

An RTV composition in accordance with claim 13 wherein the condensation catalyst is dibutyltindiacetate.

Claim 32

An RTV composition in accordance with claim 13 containing a polymethoxysilane cross-linking agent.

Claim 33

A one-package room temperature vulcanizable composition in accordance with claim 30, where the polymethoxysilane is methyltrimethoxysilane.

Claim 34

A one-package RTV in accordance with claim 13, where the substituted guanidine is butyltetramethylguanidine.

Claim 35

A one-package RTV in accordance with claim 13 wherein ingredient (3) (ii) is a dialkylamine.

Claim 36

A one-package, stable, room temperature vulcanizable composition in accordance with claim 13 having an excess of up to 3% by weight of silane scavenger based on the weight of the organopolysiloxane.

Claim 37

A room temperature vulcanizable composition in accordance with claim 13 wherein ingredient (3) (ii) is di-n-hexylamine.

Claim 40

A mixture comprising (a) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR50## (b) a stabilizing amount of a silane scavenger for hydroxy functional groups of the formula ##STR51## (c) 0 to 10 parts of cross-linking silane of the formula ##STR52## (d) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof, and (e) an effective amount of condensation catalyst, where R is selected from C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals or a C.sub.(7-13) aralkyl radical, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical, X is a hydrolyzable leaving group selected from the group consisting of amido, amino, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato and ureido radicals, and a is an integer equal to 1 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2.

Claim 41

A mixture comprising (a) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR50## (b) a stabilizing amount of a silane scavenger for hydroxy functional groups of the formula ##STR51## (c) 0 to 10 parts of cross-linking silane of the formula ##STR52## (d) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof, and (e) an effective amount of condensation catalyst, where R is selected from C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R 1 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals or a C.sub.(7-13) aralkyl radical, R 2 is a C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radical, X is a hydrolyzable leaving group selected from the group consisting of amido, amino, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato and ureido radicals, and a is an integer equal to 1 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2.

Claim 42

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising: (a) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical; (b) optionally, a polyalkoxysilane cross-linking agent; (c) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (d) an effective amount of a condensation catalyst; and (e) a stabilizing amount of a scavenger for hydroxy functional groups selected from the group consisting of non-cyclic silyl nitrogen compounds of the formula ##STR53## and cyclic silyl nitrogen compounds having at least one unit of the formula ##STR54## and the rest of the units, if any, having the formula ##STR55## where R 10 and R 12 are C 1-8 aliphatic organic radicals selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 , R 13 and R 14 are C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals, a varies from 0 to 2, h is 0 or 1, s varies from 1 to 25, Q is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR56## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, f varies from 0 to 3, d is a whole number that varies from 1 to 25, R 22 is selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 23 is selected from the group consisting of monovalent hydrocarbon radicals and hydrocarbonoxy radicals, A is selected from the group consisting of hydrogen, C 1-8 monovalent substituted and unsubstituted hydrocarbon radicals and radicals of the formula ##STR57## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, g varies from 0 to 3, and in the above scavenger there is at least one hydrocarbonoxy group in the molecule.

Claim 43

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising: (a) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical; (b) optionally, a polyalkoxysilane cross-linking agent; (c) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (d) an effective amount of a condensation catalyst; and (e) a stabilizing amount of a scavenger for hydroxy functional groups selected from the group consisting of non-cyclic silyl nitrogen compounds of the formula ##STR53## and cyclic silyl nitrogen compounds having at least one unit of the formula ##STR54## and the rest of the units, if any, having the formula ##STR55## where R 10 and R 12 are C 1-8 aliphatic organic radicals selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 , R 13 and R 14 are C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals, a varies from 0 to 2, h is 0 or 1, s varies from 1 to 25, Q is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR56## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, f varies from 0 to 3, d is a whole number that varies from 1 to 25, R 22 is selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 23 is selected from the group consisting of monovalent hydrocarbon radicals and hydrocarbonoxy radicals, A is selected from the group consisting of hydrogen, C 1-8 monovalent substituted and unsubstituted hydrocarbon radicals and radicals of the formula ##STR57## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, g varies from 0 to 3, and in the above scavenger there is at least one hydrocarbonoxy group in the molecule.

Claim 44

A room temperature vulcanizable composition in accordance with claim 38, having an effective amount of a cross-linking silane of the formula ##STR58## where R 1 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals, or a C 7-13 aralkyl radical, R 2 is a C 1-13 monovalent substituted or unsubstituted hydrocarbon radical, and b is a whole number equal to 0 or 1.

Claim 47

A mixture comprising: (a) 100 parts of a silanol terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR65## (b) a stabilizing amount of scavenger for hydroxy functional groups selected from the group consisting of non-cyclic silyl nitrogen compounds of the formula ##STR66## and cyclic silyl nitrogen compounds having at least one unit of the formula ##STR67## and the rest of the units, if any, having the formula ##STR68## where R is a C 1-13 monovalent substituted or unsubstituted hydrocarbon radical, R 10 and R 12 are C 1-8 aliphatic organic radicals selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 , R 13 and R 14 are C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals, a varies from 0 to 2, h is 0 or 1, s varies from 1 to 25, Q is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR69## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, f varies from 0 to 3, d is a whole number that varies from 1 to 25, R 22 is selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 23 is independently selected from C 1-8 monovalent hydrocarbon radicals and hydrocarbonoxy radicals, A is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR70## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, and g varies from 0 to 3, wherein in the above scavenger there is at least one hydrocarbonoxy group in the molecule, (c) 0 to 10 parts of polyalkoxy cross-linking silane; (d) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (e) an effective amount of condensation catalyst.

Claim 48

A mixture comprising: (a) 100 parts of a silanol terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR65## (b) a stabilizing amount of scavenger for hydroxy functional groups selected from the group consisting of non-cyclic silyl nitrogen compounds of the formula ##STR66## and cyclic silyl nitrogen compounds having at least one unit of the formula ##STR67## and the rest of the units, if any, having the formula ##STR68## where R is a C 1-13 monovalent substituted or unsubstituted hydrocarbon radical, R 10 and R 12 are C 1-8 aliphatic organic radicals selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 , R 13 and R 14 are C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals, a varies from 0 to 2, h is 0 or 1, s varies from 1 to 25, Q is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR69## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, f varies from 0 to 3, d is a whole number that varies from 1 to 25, R 22 is selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 23 is independently selected from C 1-8 monovalent hydrocarbon radicals and hydrocarbonoxy radicals, A is selected from the group consisting of hydrogen, C 1-8 monovalent substituted or unsubstituted hydrocarbon radicals and radicals of the formula ##STR70## where R 10 is a C 1-8 aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, alkylcyano and aryl, R 11 is a C 1-8 monovalent substituted or unsubstituted hydrocarbon radical, and g varies from 0 to 3, wherein in the above scavenger there is at least one hydrocarbonoxy group in the molecule, (c) 0 to 10 parts of polyalkoxy cross-linking silane; (d) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (e) an effective amount of condensation catalyst.

Claim 49

The mixture of claim 41, wherein the scavenger and cross-linking agent has the formula ##STR71##

Claim 50

The composition of claim 41 wherein ingredient (d) (i) of the end-capping catalyst is an acid anhydride.

Claim 51

The composition of claim 41 wherein ingredient (d) (i) of the end-capping catalyst has the formula ##STR72## where R 30 and R 31 are C.sub.(1-20) monovalent hydrocarbon radicals and j is a whole number that varies from 0 to 3.

Claim 52

The composition of claim 41 wherein ingredient (d) (i) of the end-capping catalyst has the formula ##STR73## where R 32 is a C.sub.(1-20) monovalent hydrocarbon radical.

Claim 53

The composition of claim 41 wherein ingredient (d) (i) of the end-capping catalyst is an inorganic acid.

Claim 54

The composition of claim 46, wherein the inorganic acid is selected from the group consisting of HCl, H 3 PO 4 , H 2 SO 4 , and polyphosphoric acid.

Claim 55

The composition of claim 43 wherein the acid anhydride has the formula ##STR74## where R 33 , R 34 are C.sub.(1-20) monovalent hydrocarbon radicals.

Claim 56

The composition of claim 41 wherein ingredient (d) (i) of the end-capping catalyst is selected from the group consisting of BF 3 , (CH 3 CH 2 ) 2 O, and AlCl 3 .

Claim 57

The composition of claim 41 wherein the total acid number does not exceed 15.

Claim 58

The composition of claim 41 wherein the total acid number is at least 0.1.

Claim 59

The composition of claim 41 wherein ingredient (d) (i) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane and ingredient (d) (ii) is present at a concentration of 0.1 to 0.5 parts by weight per 100 parts by weight of the organopolysiloxane.

Claim 60

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical; (2) a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (4) an effective amount of condensation catalyst; and (5) a stabilizing amount of a scavenger for hydroxy functional groups which is a silicon-nitrogen compound selected from the group consisting of: (A) silicon-nitrogen compounds having the formula ##STR75## where Y is selected from R"' and R" 2 N-- and (B) silicon-nitrogen polymers comprising (1) from 3 to 100 mole percent chemically combined structural units having the formula ##STR76## and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula ##STR77## where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR"Si linkage, the free valences of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silazy unit are joined to a member selected from an R"' radical and an (R") 2 N radical and where the ratio of the sum of said R"' radicals and said (R") 2 N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, and R" is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals, and fluoroalkyl radicals, R"' is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive.

Claim 61

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising: (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least 1 hydroxy radical; (2) a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (4) an effective amount of condensation catalyst; and (5) a stabilizing amount of a scavenger for hydroxy functional groups which is a silicon-nitrogen compound selected from the group consisting of: (A) silicon-nitrogen compounds having the formula ##STR75## where Y is selected from R"' and R" 2 N-- and (B) silicon-nitrogen polymers comprising (1) from 3 to 100 mole percent chemically combined structural units having the formula ##STR76## and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula ##STR77## where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR"Si linkage, the free valences of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silazy unit are joined to a member selected from an R"' radical and an (R") 2 N radical and where the ratio of the sum of said R"' radicals and said (R") 2 N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, and R" is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals, and fluoroalkyl radicals, R"' is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive.

Claim 64

A mixture comprising (A) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR82## (B) 1 to 10 parts of a polyalkoxy cross-linking silane; (C) an effective amount of end-capping catalyst, comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (D) a stabilizing amount of scavenger for hydroxy functional groups selected from the group consisting of silicon-nitrogen compounds having the formula ##STR83## where Y is selected from R"' and R" 2 N and silicon-nitrogen polymers comprising (1) from 3 to 100 mole percent chemically combined structural units having the formula ##STR84## and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula ##STR85## where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR"Si linkage, the free valences of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silajy unit are joined to a member selected from an R"' radical and an (R") 2 N radical, and where the ratio of the sum of said R"' radicals and said (R") 2 N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, and R" is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals, anf fluoroalkyl radicals, R"' is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive, and (E) an effective amount of condensation catalyst, where R is selected from C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radicals.

Claim 65

A mixture comprising (A) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula ##STR82## (B) 1 to 10 parts of a polyalkoxy cross-linking silane; (C) an effective amount of end-capping catalyst, comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; (D) a stabilizing amount of scavenger for hydroxy functional groups selected from the group consisting of silicon-nitrogen compounds having the formula ##STR83## where Y is selected from R"' and R" 2 N and silicon-nitrogen polymers comprising (1) from 3 to 100 mole percent chemically combined structural units having the formula ##STR84## and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula ##STR85## where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR"Si linkage, the free valences of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silajy unit are joined to a member selected from an R"' radical and an (R") 2 N radical, and where the ratio of the sum of said R"' radicals and said (R") 2 N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, and R" is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals, anf fluoroalkyl radicals, R"' is a member selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive, and (E) an effective amount of condensation catalyst, where R is selected from C.sub.(1-13) monovalent substituted or unsubstituted hydrocarbon radicals.

Claim 66

The composition of claim 55 wherein ingredient (C) (i) of the end-capping catalyst is an acid anhydride.

Claim 67

The composition of claim 55 wherein ingredient (C) (i) of the end-capping catalyst has the formula ##STR86## where R 30 and R 31 are C.sub.(1-20) monovalent hydrocarbon radicals and j is a whole number that varies from 0 to 3.

Claim 68

The composition of claim 55 wherein ingredient (C) (i) of the end-capping catalyst has the formula ##STR87## where R 32 is a C.sub.(1-20) monovalent hydrocarbon radical.

Claim 69

The composition of claim 55 wherein ingredient (C) (i) of the end-capping catalyst is an inorganic acid.

Claim 70

The composition of claim 59 wherein the inorganic acid is selected from the group consisting of HCl, H 3 PO 4 , H 2 SO 4 , and polyphosphoric acid.

Claim 71

The composition of claim 56 wherein the acid anhydride has the formula ##STR88## where R 33 , R 34 are C.sub.(1-20) monovalent hydrocarbon radicals.

Claim 72

The composition of claim 55 wherein ingredient (C) (i) of the end-capping catalyst is selected from the group consisting of BF 3 , (CH 3 CH 2 ) 2 O, and AlCl 3 .

Claim 73

The composition of claim 55 wherein the total acid number does not exceed 15.

Claim 74

The composition of claim 55 wherein the total acid number is at least 0.1.

Claim 75

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least one hydroxy radical; (2) a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (4) a stabilizing amount of silane scavenger for hydroxy functional groups which is a silyl amine of the formula ##STR89## where R" is a radical selected from the group consisting of hydrogen and C.sub.(1-8) monovalent hydrocarbon radicals, R 20 is a radical selected from the group consisting of C.sub.(1-8) monovalent hydrocarbon radicals and C.sub.(1-8) alkoxy radicals and fluoroalkyl radicals, and g is a whole number that varies from 1 to 3, h is a whole number that varies from 0 to 2 and the sum of h+g does not exceed 3.

Claim 76

A stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer, comprising (1) an organopolysiloxane wherein the silicon atom at each polymer chain end is terminated with at least one hydroxy radical; (2) a polyalkoxy cross-linking agent; (3) an effective amount of end-capping catalyst comprising a combination of (i) a Lewis acid and (ii) a compound selected from the group consisting of substituted guanidines, amines and mixtures thereof; and (4) a stabilizing amount of silane scavenger for hydroxy functional groups which is a silyl amine of the formula ##STR89## where R" is a radical selected from the group consisting of hydrogen and C.sub.(1-8) monovalent hydrocarbon radicals, R 20 is a radical selected from the group consisting of C.sub.(1-8) monovalent hydrocarbon radicals and C.sub.(1-8) alkoxy radicals and fluoroalkyl radicals, and g is a whole number that varies from 1 to 3, h is a whole number that varies from 0 to 2 and the sum of h+g does not exceed 3.