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US4508874A Expired / Lapsed US ⏱️ 0.0 years remaining

Impact resistant polymeric compositions containing polyamides, maleic anhydride adducts of hydrogenated polymers and graft copolymers thereof

Assignee: Bridgestone Firestone Inc
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Filing: 1983-11-04
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Granted: 1985-04-02
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Expires: 2003-11-04
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Abstract

Abstract Polymeric compositions having resistance to impact comprising (a) from about 50 to about 90 percent by weight of a polyamide having a number average molecular weight of at least 10,000 and (b) from about 10 to about 50 percent by weight of a maleic anhydride adduct of a hydrogenated polymer of one or more conjugated dienes or a hydrogenated copolymer of a conjugated diene and a vinyl aromatic hydrocarbon, said hydrogenated polymer or copolymer having a residual unsaturation content of from about 0.5 to about 20% of its original unsaturation content prior to hydrogenation; wherein at least 5 percent by weight of components (a) and (b) are present in the form of a graft copolymer containing at least 20 percent of polyamide. The compositions exhibit especially advantageous properties, particularly high impact strength and are useful in a variety of molding applications such as molded bushings, gears, cams, valves and a variety of other products.

Inventors

  • 👤 William L. Hergenrother
  • 👤 Mark G. Matlock
  • 👤 Richard J. Ambrose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 09:43
CPC Classifications
C; C08; C08L; C08L77/00; Y; Y10; Y10S; Y10S525/00; Y10S525/94

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 51 words
A maleic anhydride adduct of a hydrogenated polymer of one or more conjugated dienes or hydrogenated copolymer of a conjugated diene and a vinyl aromatic hydrocarbon, said hydrogenated polymer or copolymer having a residual unsaturation content of from about 0.5 to about 20% of its original unsaturation content prior to hydrogenation.
Claim 2
Dependent Claim 51 words
A maleic anhydride adduct of a hydrogenated polymer of one or more conjugated dienes or hydrogenated copolymer of a conjugated diene and a vinyl aromatic hydrocarbon, said hydrogenated polymer or copolymer having a residual unsaturation content of from about 0.5 to about 20% of its original unsaturation content prior to hydrogenation.
Claim 3
Dependent Claim 16 words
The adduct of claim 1 containing from 0.1 to 25 percent by weight of maleic anhydride.
Claim 4
Dependent Claim 16 words
The adduct of claim 1 containing from 0.2 to 5 percent by weight of maleic anhydride.
Claim 5
Dependent Claim 13 words
The adduct of claim 1 wherein said hydrogenated polymer is a hydrogenated polybutadiene.
Claim 6
Dependent Claim 18 words
The adduct of claim 1 wherein said hydrogenated copolymer is a hydrogenated random copolymer of butadiene and styrene.
Claim 7
Dependent Claim 18 words
The adduct of claim 5 wherein said random copolymer contains up to 60 percent by weight of styrene.
Claim 8
Dependent Claim 36 words
The adduct of claim 1 wherein said hydrogenated copolymer is a hydrogenated block copolymer of butadiene and styrene, said hydrogenated block copolymer having a 1,2-microstructure content prior to hydrogenation of from about 7% to about 100%.
Claim 9
Dependent Claim 18 words
The adduct of claim 1 wherein said hydrogenated copolymer is a hydrogenated multiblock copolymer of butadiene and styrene.
Claim 10
Dependent Claim 14 words
The adduct of claim 8 wherein said multiblock copolymer is a styrene/butadiene/styrene block copolymer.

References Cited (Backward Citations)

US4080493A Cited
US4161571A Cited
US4161452A Cited
US4292414A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-04-01 1988-10-01 1989-04-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-04-01 1992-10-01 1993-04-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-04-01 1996-10-01 1997-04-02 $7700.00 Window Closed / Lapsed

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