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US4161571A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for production of the maleic anhydride adduct of a liquid polymer

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1977-11-18
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Granted: 1979-07-17
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Expires: 1997-11-18
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Abstract

Abstract A process for production of the maleic anhydride adduct of a liquid polymer having a maleic anhydride addition amount of 2 to 70% by weight, which comprises reacting a liquid polymer having a molecular weight of 150 to 5,000 and a viscosity of 2 to 50,000 cp at 30 DEG C. in the presence of at least one compound, as a gelation inhibitor, selected from the group consisting of imidazoles, thiazoles, metallic salts of mercaptothiazoles, urea derivatives, naphthylamines, nitrosamines, iron, iron compounds and specific halogen compounds, said liquid polymer being selected from the group consisting of liquid polybutadienes, liquid polyisoprenes and liquid copolymers comprising units of butadiene or isoprene and units of at least one compound selected from the group consisting of other diolefins, olefins and aromatic vinyl compounds.

Inventors

  • 👤 Seimei Yasui
  • 👤 Takao Oshima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 17:53
CPC Classifications
C; C08; C08C; C08C19/00; C08C19/28; C08F; C08F279/00; C08F279/02

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 220 words
A process for the production of the maleic anhydride adducts of a liquid polymer having a maleic anhydride addition amount of 2 to 70% by weight, which comprises reacting a liquid polymer having a molecular weight of 150 to 5,000 and a viscosity of 2 to 50,000 centipoise at 30° C., said liquid polymer being selected from the group consisting of liquid polybutadienes, liquid polyisoprenes and liquid copolymers comprising units of butadiene or isoprene and units of at least one compound selected from the group consisting of other diolefins, olefins and aromatic vinyl compounds, with maleic anhydride in the presence of at least one compound, as a gelatin inhibitor, selected from the group consisting of: (a) organic salts of iron, organic complexes of iron, chelate compounds of iron and inorganic compounds of iron; (b) chlorides, bromides and iodides of the elements belonging to Groups (III), (IV), (V) or (VI) of the Periodic Table, and ether complexes, ester complexes and aldehyde complexes thereof; and (c) alkyl metal halides of the formula: R.sub.n M'Y.sub.m-n wherein M' is a metal belonging to Group (III) or (IV) of the Periodic Table, R is alkyl having 1 to 8 carbon atoms, Y is chlorine, bromine or iodine, m is an atomic valence of the metal M', and n is a positive integer smaller than m.
Claim 2
Dependent Claim 220 words
A process for the production of the maleic anhydride adducts of a liquid polymer having a maleic anhydride addition amount of 2 to 70% by weight, which comprises reacting a liquid polymer having a molecular weight of 150 to 5,000 and a viscosity of 2 to 50,000 centipoise at 30° C., said liquid polymer being selected from the group consisting of liquid polybutadienes, liquid polyisoprenes and liquid copolymers comprising units of butadiene or isoprene and units of at least one compound selected from the group consisting of other diolefins, olefins and aromatic vinyl compounds, with maleic anhydride in the presence of at least one compound, as a gelatin inhibitor, selected from the group consisting of: (a) organic salts of iron, organic complexes of iron, chelate compounds of iron and inorganic compounds of iron; (b) chlorides, bromides and iodides of the elements belonging to Groups (III), (IV), (V) or (VI) of the Periodic Table, and ether complexes, ester complexes and aldehyde complexes thereof; and (c) alkyl metal halides of the formula: R.sub.n M'Y.sub.m-n wherein M' is a metal belonging to Group (III) or (IV) of the Periodic Table, R is alkyl having 1 to 8 carbon atoms, Y is chlorine, bromine or iodine, m is an atomic valence of the metal M', and n is a positive integer smaller than m.
Claim 3
Dependent Claim 16 words
A method according to claim 1, wherein the gelation inhibitor is an organic salt of iron.
Claim 4
Dependent Claim 20 words
A method according to claim 2, wherein the organic acid salt of iron is a carboxylic acid salt of iron.
Claim 5
Dependent Claim 18 words
A method according to claim 1, wherein the gelation inhibitor is an organic complex or chelate of iron.
Claim 6
Dependent Claim 30 words
A method according to claim 4, wherein the organic complex or chelate of iron is tris-(dipyridyl)iron chloride, bis-(ethylenediamine)iron sulfate, bis-(acetylacetonate)iron, bis-(ethylacetoacetate)iron, bis-(dimethylglyoximate)iron or the complex between iron chloride and pyridine.
Claim 7
Dependent Claim 22 words
A method according to claim 2, wherein the organic salt of iron is iron acetate, iron naphthenate, iron octylate or iron benzoate.
Claim 8
Dependent Claim 17 words
A method according to claim 1, wherein the gelation inhibitor is an inorganic acid salt of iron.
Claim 9
Dependent Claim 29 words
A method according to claim 7, wherein the inorganic acid salt of iron is iron sulfate, iron nitrate, ferrous chloride, ferric chloride, ferrous bromide, ferric bromide or iron iodide.
Claim 10
Dependent Claim 41 words
A method according to claim 1, wherein the gelation inhibitor is the chloride, bromide or iodide of an element belonging to Group (III), (IV), (V) or (VI) of the Periodic Table, or an ether complex, ester complex or aldehyde complex thereof.
Claim 11
Dependent Claim 15 words
A method according to claim 9, wherein the element is phosphorus, boron, aluminum or titanium.
Claim 12
Dependent Claim 44 words
A method according to claim 9, wherein the complex is the ether complex, ester complex or aldehyde complex of boron trichloride, aluminum trichloride, titanium tetrachloride, phosphorus trichloride, phosphorus pentachloride, phosphorus tribromide, phosphorus pentabromide, boron tribromide, boron triiodide, aluminum tribromide, titanium tetrabromide or titanium tetraiodide.
Claim 13
Dependent Claim 28 words
A method according to claim 1, wherein the gelation inhibitor is said alkyl metal halide of the formula: R.sub.n M'Y.sub.m-n in which M' is aluminum, boron or tin.
Claim 14
Dependent Claim 23 words
A method according to claim 1, wherein the amount of gelation inhibitor is 0.001 to 5% by weight based on the liquid polymer.
Claim 15
Dependent Claim 23 words
A method according to claim 13, wherein the amount of gelation inhibitor is 0.005 to 0.5% by weight based on the liquid polymer.
Claim 16
Dependent Claim 23 words
A method according to claim 1, wherein the addition reaction is carried out at 120° to 230° C. for 1 to 10 hours.
Claim 17
Dependent Claim 15 words
A method according to claim 15, wherein the reaction temperature is 160° to 190° C.

References Cited (Backward Citations)

US2388477A Cited
US2388514A Cited
US3546184A Cited
US3778418A Cited
US3937677A Cited
FR2262677A1 Cited
US4082817A Cited
US4080493A Cited
US4091198A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-07-16 1983-01-15 1983-07-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-07-16 1987-01-15 1987-07-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-07-16 1991-01-15 1991-07-17 $7700.00 Window Closed / Lapsed

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