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US4504576A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic support paper having a surface size

Assignee: FELIX SCHOELLER JR & Co KG A CORP OF BR DEUTSCHLAND GmbH
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Filing: 1983-02-15
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Granted: 1985-03-12
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Expires: 2003-02-15
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Abstract

Abstract Photographic support paper for photographic coatings containing silver salt, which possesses a neutral internal size and contains a cationic setting agent, the paper support being treated with at least one organic acid which either is a multivalent acid, the acid groups of which are separated from one another by at most three carbon atoms, and/or is a hydroxy acid capable of internal complex formation.

Inventors

  • 👤 Gregor Kemme

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:41
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/03; D21H17/05; D21H17/14; D21H17/15; G; G03; G03C; G03C1/00; G03C1/76; G03C1/775

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 170 words
In a photographic support paper for a photographic coating containing silver salt, the support paper containing a neutral internal size and a cationic setting agent which result in the presence of photochemically disturbing compounds which cause haze in the photographic coating when deposited on the internally sized paper, the improvement wherein said internally sized paper with setting agent includes a surface size on said internally sized paper of a dried aqueous solution of at least one organic acid, organic salt or organic acid amide which is present in an amount sufficient to substantially reduce the haze which said photochemically disturbing compounds would otherwise produce in the photographic coating, said organic acid, salt or acid amide being selected from the group consisting of (A) polybasic acids, polybasic acid salts or polybasic acid amides, the acid, salt or acid amide groups of which are separated from one another by not more than 3 carbon atoms, and (B) hydroxy acids, hydroxy acid salts or hydroxy acid amides which are capable of forming chelates.
Claim 2
Dependent Claim 170 words
In a photographic support paper for a photographic coating containing silver salt, the support paper containing a neutral internal size and a cationic setting agent which result in the presence of photochemically disturbing compounds which cause haze in the photographic coating when deposited on the internally sized paper, the improvement wherein said internally sized paper with setting agent includes a surface size on said internally sized paper of a dried aqueous solution of at least one organic acid, organic salt or organic acid amide which is present in an amount sufficient to substantially reduce the haze which said photochemically disturbing compounds would otherwise produce in the photographic coating, said organic acid, salt or acid amide being selected from the group consisting of (A) polybasic acids, polybasic acid salts or polybasic acid amides, the acid, salt or acid amide groups of which are separated from one another by not more than 3 carbon atoms, and (B) hydroxy acids, hydroxy acid salts or hydroxy acid amides which are capable of forming chelates.
Claim 3
Dependent Claim 39 words
Photographic support paper according to claim 1, wherein the organic acid, salt or acid amide has been applied to the support paper in the form of at least one of the free acid, an ammonium salt or amide thereof.
Claim 4
Dependent Claim 39 words
Photographic support paper according to claim 1, in which the aqueous solution of the organic acid, salt or acid amide additionally contains at least one further additive selected from the group consisting of pigments, optical brighteners and wetting agents.
Claim 5
Dependent Claim 31 words
Photographic support paper according to claim 1, wherein the aqueous solution of the organic acid has been applied by coating or impregnation thereon on one or both sides of the paper.
Claim 6
Dependent Claim 22 words
Photographic support paper according to claim 1, wherein the paper contains barytes and the aqueous solution comprises an aqueous solution of gelatin.
Claim 7
Dependent Claim 56 words
Photographic support paper according to claim 1 wherein the support is coated with a polyolefin coating and the solution is an aqueous solution containing a starch ether, sodium chloride, a dispersed ionomeric resin and the organic acid, salt or acid amide in the form of the ammonium salt or the acid amide of an organic acid.
Claim 8
Dependent Claim 100 words
Photographic support paper according to claim 1, wherein the organic acid, salt or acid amide is selected from the group consisting of an acid, salt or acid amide of oxalic acid, lactic acid, citric acid, aconitic acid, tartaric acid, pyrotartaric acid, malic acid, gluconic acid, succinic acid, alkyl succinic acids, glutaric acid, oxymalonic acid, sulphoacetic acid, glutamic acid, aspartic acid, maleic acid, copolymers of maleic acid with other monomers which may be styrene, itaconic acid and copolymers, citraconic acid and copolymers thereof, polyacrylic acid, polymethacrylic acid, polyvinylsulphonic acid, polyvinylphosphoric acid, benzenedisulphonic acid, sulphuric acid esters of carbohydrates, or mixtures thereof.
Claim 9
Dependent Claim 43 words
Photographic support paper according to claim 1, wherein the aqueous solution includes: 6% by wt. oxidized starch, 2% by wt. sodium chloride, 0.2% by wt. optical brightener, 5% by wt. organic acid or ammonium salt of the acid, and 86.8% by wt. water.
Claim 10
Dependent Claim 111 words
Photographic support paper according to claim 1, wherein the aqueous solution for treating the photographic support has at least one of the following compositions: (a) 2% by wt. gelatine 3% by wt. ammonium polyacrylate 0.1% by wt. optical brightener, or (b) 2% by wt. gelatine 2% by wt. ammonium cellulose sulphate 0.1% by wt. optical brightener, or (c) 2% by wt. gelatine 2% by wt. ammonium polyvinyl sulphonate 0.1% by wt. optical brightener, or (d) 3% by wt. gelatine 3% by wt. ammonium glutaconate 0.1% by wt. optical brightener with the remainder of said compositions being water, the pH of the solution being adjusted by means of ammonia to approximately 7.
Claim 11
Dependent Claim 32 words
Photographic paper support according to claim 1, wherein the organic acid, salt or acid amide has been applied to the support paper in the form of a lactone of an organic acid.
Claim 12
Dependent Claim 22 words
Photographic support paper according to claim 5, wherein said aqueous solution also includes at least one of glycerine and an optical brightener.
Claim 13
Dependent Claim 22 words
Photographic support paper according to claim 6, wherein said organic acid, salt or acid amide comprises ammonium citrate or polyacrylic acid amide.

References Cited (Backward Citations)

US3139373A Cited
US3326744A Cited
US3296065A Cited
US3332834A Cited
US3821069A Cited
US4317756A Cited
US4302283A Cited
US4288287A Cited
US4331508A Cited
US4353981A Cited
US4410619A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-03-11 1988-09-10 1989-03-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-03-11 1992-09-10 1993-03-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-03-11 1996-09-10 1997-03-12 $7700.00 Window Closed / Lapsed

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