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US4353981A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic material

Assignee: Mitsubishi Paper Mills Ltd
•
Filing: 1980-09-05
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Granted: 1982-10-12
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Expires: 2000-09-05
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Abstract

Abstract A silver halides photographic material with improved keeping quality, said material having a substrate formed by coating a base web with a film-forming resin, preferably a polyolefin resin, said base web being composed principally of natural pulp or a mixture of two or more different types of natural pulp having a post color number of 2 or below, said post color number being defined by the following formula: <IMAGE> [wherein Ro is brightness (%)x(1)/(100) before fading treatment, R is brightness (%)x(1)/(100) after 18-hour fading treatment at 85 DEG C. and 95% RH, and P is post color (PC) number which indicates the degree (nondimensional number) of fading].

Inventors

  • 👤 Toru Noda
  • 👤 Yoshinobu Ichihashi
  • 👤 Massashi Kubbota

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 19:05
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/775; G03C1/79

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 206 words
A silver halide photographic material in which a photographic layer composed of at least one silver halide emulsion layer is provided on a substrate prepared by coating a base web principally composed of natural pulp with a film-forming resin, wherein the silver halide photographic emulsion layer is one which has been produced by incorporating at least one of the water soluble rhodium compounds or water soluble iridium compounds at the time of formation and dispersion or at the time of physical aging of the silver halide or the silver halide photographic emulsion layer contains a water soluble gold compound; the natural pulp or a mixture of two or more different types of natural pulp used for the base web of said substrate is one which has been produced by performing an additional bleaching treatment with a peroxide or a boron hydride compound in an alkaline state after the conventional pump bleaching treatment and has a PC number of 2.0 or less, said PC number being defined by the following formula: ##EQU3## wherein Ro=brightness (%)×(1)/(100) before the fading treatment, R=brightness (%)×1/100 after 18-hour fading treatment at 85° C. and 95% RH, and P is the post color (PC) number which indicates the degree (nondimensional number) of fading.
Claim 2
Dependent Claim 206 words
A silver halide photographic material in which a photographic layer composed of at least one silver halide emulsion layer is provided on a substrate prepared by coating a base web principally composed of natural pulp with a film-forming resin, wherein the silver halide photographic emulsion layer is one which has been produced by incorporating at least one of the water soluble rhodium compounds or water soluble iridium compounds at the time of formation and dispersion or at the time of physical aging of the silver halide or the silver halide photographic emulsion layer contains a water soluble gold compound; the natural pulp or a mixture of two or more different types of natural pulp used for the base web of said substrate is one which has been produced by performing an additional bleaching treatment with a peroxide or a boron hydride compound in an alkaline state after the conventional pump bleaching treatment and has a PC number of 2.0 or less, said PC number being defined by the following formula: ##EQU3## wherein Ro=brightness (%)×(1)/(100) before the fading treatment, R=brightness (%)×1/100 after 18-hour fading treatment at 85° C. and 95% RH, and P is the post color (PC) number which indicates the degree (nondimensional number) of fading.
Claim 3
Dependent Claim 41 words
A silver halide photographic material according to claim 1, wherein the natural pulp or a mixture of two or more different types of natural pulp used for the base web of said substrate has a PC number of 1.5 or less.
Claim 4
Dependent Claim 26 words
A silver halide photographic material according to claim 1, wherein the additional bleaching treatment is carried out by using a peroxide in an alkaline aqueous medium.
Claim 5
Dependent Claim 15 words
A silver halide photographic material according to claim 3, wherein the peroxide is hydrogen peroxide.
Claim 6
Dependent Claim 37 words
A silver halide photographic material according to claim 1, wherein the natural pulp used for the base web of said substrate is one which has been bleached by using a boron hydride compound in an alkaline state.
Claim 7
Dependent Claim 24 words
A silver halide photographic material according to claim 1, wherein the additional bleaching treatment is carried out at a pH of 8 to 11.
Claim 8
Dependent Claim 35 words
A silver halide photographic material according to claim 1, wherein the conventional bleaching treatment is one selected from chlorine or alkali treatment, extraction or refining treatment, hypochlorite bleaching, chlorine dioxide bleaching and a combination thereof.
Claim 9
Dependent Claim 38 words
A silver halide photographic material according to claim 7, wherein an alkali treatment, alkali extraction or alkali refining is carried out after the additional bleaching treatment using a peroxide or a boron hydride compound in an alkaline state.
Claim 10
Dependent Claim 17 words
A silver halide photographic material according to claim 1, wherein the film-forming resin is a polyethylene resin.
Claim 11
Dependent Claim 54 words
A silver halide photographic material according to claim 1, wherein the silver halide photographic emulsion layer is one which has been produced by incorporating at least one of the water-soluble rhodium compounds or water-soluble iridium compounds at the time of formation and dispersion or at the time of the physical aging of silver halide.
Claim 12
Dependent Claim 20 words
A silver halide photographic material according to claim 1, wherein the silver halide emulsion layer contains a water-soluble gold compound.

References Cited (Backward Citations)

US3100732A Cited
US3284283A Cited
US3582337A Cited
US3885962A Cited
US3865685A Cited
US3901711A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-10-11 1986-04-12 1986-10-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-10-11 1990-04-12 1990-10-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-10-11 1994-04-12 1994-10-12 $7700.00 Window Closed / Lapsed

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