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US4497741A
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Water-soluble zinc and aluminium phthalocyanines
Assignee: BASF Corp
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Filing: 1982-12-01
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Granted: 1985-02-05
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Expires: 2002-12-01
Abstract
Abstract The invention relates to novel zinc and aluminium phthalocyanine compounds of the formula <IMAGE> wherein MePc is the zinc or aluminium phthalocyanine ring system, M is hydrogen or a salt-forming cation, P1 is hydrogen or a group of the formula -NH-CN or NH-SO2R3 or the salts thereof, wherein R3 is alkyl, aryl or a heterocyclic ring system, R2 is a neutral, non-solubilizing substituent, n is 1 to 4 and each of m and q is 0 to 3 and p is 0 to 4. These compounds are prepared by starting from the corresponding sulfohalides. The novel compounds are used as photoactivators, especially for bleaching and removing stains from textiles and for combating microorganisms in or on organic or inorganic substrates. The invention also relates to bleaching, detergent and soaking and microbicidal compositions which contain the novel phthalocyanine compounds.
Inventors
- 👤 Gerd Holzle
- 👤 Mirella Miotto
- 👤 Gerhard Reinert
- 👤 Rudolf Polony
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 12:58
CPC Classifications
C; C07; C07F; C07F5/00; C07F5/06; C07D; C07D487/00; C07D487/22; A; A01; A01N; A01N43/00; A01N43/90; A01N47/00; A01N47/40; C11; C11D; C11D3/00; C11D3/0005; C11D3/0063; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3932; D; D06; D06M; D06M16/00; Y; Y02; Y02W; Y02W10/00; Y02W10/30; Y02W10/37
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
216 words
A phthalocyanine compound of the formula ##STR46## wherein MePc is the zinc or aluminum phthalocyanine ring system, M is hydrogen or the equivalent of a salt-forming cation, R 1 is M or a group of the formula ##STR47## wherein X is hydrogen or ammonium or the equivalent of a monovalent, divalent or trivalent metal ion, and R 3 is C 1 -C 8 -alkyl, unsubstituted or substituted by hydroxy, alkoxy, halogen, cyano, or carbalkoxy, aminocarbonyl or dialkylamino; aryl, unsubstituted or substituted by alkyl or alkoxy, nitro, haloalkyl, halogen, alkoxycarbonyl, cyano, alkylsulfonyl, acylamino, carboxy and derivatives thereof, sulfo and derivatives thereof, acyloxy, trifluoromethyl or dialkylamino, or an unsubstituted or substituted or fused 5- or 6-membered aromatic heterocyclic ring containing one or two nitrogen, oxygen or sulfur heteroatoms which may be unsubstituted or substituted in the same manner as the aryl groups R 3 ; each R 2 is independently halogen, aryl or cyano, n has any value from 1 to 4, each of m and q has any value from 0 to 3 and p has any value from 0 to 4, while the sum of n+m and n+q in each case is 1 to 4 and q is only different from 0 if R 1 is a group of the formula ##STR48## and m is 0.
Claim 2
Dependent Claim
216 words
A phthalocyanine compound of the formula ##STR46## wherein MePc is the zinc or aluminum phthalocyanine ring system, M is hydrogen or the equivalent of a salt-forming cation, R 1 is M or a group of the formula ##STR47## wherein X is hydrogen or ammonium or the equivalent of a monovalent, divalent or trivalent metal ion, and R 3 is C 1 -C 8 -alkyl, unsubstituted or substituted by hydroxy, alkoxy, halogen, cyano, or carbalkoxy, aminocarbonyl or dialkylamino; aryl, unsubstituted or substituted by alkyl or alkoxy, nitro, haloalkyl, halogen, alkoxycarbonyl, cyano, alkylsulfonyl, acylamino, carboxy and derivatives thereof, sulfo and derivatives thereof, acyloxy, trifluoromethyl or dialkylamino, or an unsubstituted or substituted or fused 5- or 6-membered aromatic heterocyclic ring containing one or two nitrogen, oxygen or sulfur heteroatoms which may be unsubstituted or substituted in the same manner as the aryl groups R 3 ; each R 2 is independently halogen, aryl or cyano, n has any value from 1 to 4, each of m and q has any value from 0 to 3 and p has any value from 0 to 4, while the sum of n+m and n+q in each case is 1 to 4 and q is only different from 0 if R 1 is a group of the formula ##STR48## and m is 0.
Claim 3
Dependent Claim
10 words
A phthalocyanine compound of claim 1, wherein q is 0.
Claim 4
Dependent Claim
40 words
A phthalocyanine compound of claim 1, wherein M is hydrogen, an alkali metal ion, an ammonium ion or an amine salt ion, R 2 is a halogen atom or cyano and X is hydrogen, ammonium or an alkali metal atom.
Claim 5
Dependent Claim
94 words
A phthalocyanine compound of claim 3, wherein R 2 is a halogen atom and R 3 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 2 -C 6 alkoxyalkyl, C 1 -C 4 hydroxyalkyl, C 2 -C 5 cyanoalkyl, di(C 1 -C 4 )-alkylamino(C 1 -C 4 )alkyl or benzyl, phenyl or phenyl substituted by 1 to 3 substituents selected from the group consisting of halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, cyano, nitro, di(C 1 -C 4 )alkylamino, and sulfo and carboxy and the salts thereof.
Claim 6
Dependent Claim
80 words
A phthalocyanine compound of claim 4 of the formula ##STR49## wherein R 2 ' is chlorine, bromine or iodine, M' is hydrogen, sodium, potassium or ammonium, and R 1 ' is hydrogen, M' or a group of the formula ##STR50## wherein X' is hydrogen, sodium, potassium or ammonium, and R 3 ' is C 1 -C 4 alkyl, phenyl or C 1 -C 4 alkylphenyl, chlorophenyl or methoxyphenyl, and MePc, n, m and p are as defined in claim 4.
Claim 7
Dependent Claim
18 words
A phthalocyanine compound of claim 2, wherein R 1 is hydrogen or a group of the formula ##STR51##
Claim 8
Dependent Claim
12 words
A phthalocyanine compound of claim 5 wherein R 2 ' is chlorine.
Claim 9
Dependent Claim
16 words
A phthalocyanine compound of claim 2, wherein R 1 is a group of the formula ##STR52##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-05 | 1988-08-06 | 1989-02-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-05 | 1992-08-06 | 1993-02-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-05 | 1996-08-06 | 1997-02-05 | $7700.00 | Window Closed / Lapsed |