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US4495277A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic silver halide emulsion

Assignee: Agfa Gevaert AG
•
Filing: 1983-08-01
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Granted: 1985-01-22
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Expires: 2003-08-01
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Abstract

Abstract Surface-sensitized silver halide grains having a core/shell structure show improved properties.

Inventors

  • 👤 Manfred Becker
  • 👤 Sieghart Klotzer
  • 👤 Erik Moisar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:51
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/035; G03C2001/03535

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 213 words
A photographic silver halide emulsion containing silver halide grains which have a core/shell structure and which are chemically sensitised at the surface thereof to provide density and speed, wherein, in the silver halide grains, at least one layer contains at least 25 mole percent of silver chloride and wherein the total content of silver chloride amounts to less than 30 mole percent and wherein the emulsion is chemically ripened at its surface to such an extent that the ratio R of the density D r obtainable after surface ripening to the density D u obtainable with the as yet non-surface-ripened, but otherwise identical, emulsion amounts to at least 3, the ratio R being determined by applying the ripened emulsion and the unripened emulsion to a layer support in exactly the same way, exposing them and then developing them for 17 minutes at 20° C. in a developer of the following composition: ______________________________________ ascorbic acid 10 g p-methylaminophenol 2.4 g Na.sub.2 CO.sub.3 (sicc.) 10 g KBr 2.0 g water to 1000 ml ______________________________________ and D r being the value of 90% of the maximum density and D u being obtained by exposure of the as yet unripened emulsion to the extent which leads to the density D r in the case of ripened emulsion.
Claim 2
Dependent Claim 213 words
A photographic silver halide emulsion containing silver halide grains which have a core/shell structure and which are chemically sensitised at the surface thereof to provide density and speed, wherein, in the silver halide grains, at least one layer contains at least 25 mole percent of silver chloride and wherein the total content of silver chloride amounts to less than 30 mole percent and wherein the emulsion is chemically ripened at its surface to such an extent that the ratio R of the density D r obtainable after surface ripening to the density D u obtainable with the as yet non-surface-ripened, but otherwise identical, emulsion amounts to at least 3, the ratio R being determined by applying the ripened emulsion and the unripened emulsion to a layer support in exactly the same way, exposing them and then developing them for 17 minutes at 20° C. in a developer of the following composition: ______________________________________ ascorbic acid 10 g p-methylaminophenol 2.4 g Na.sub.2 CO.sub.3 (sicc.) 10 g KBr 2.0 g water to 1000 ml ______________________________________ and D r being the value of 90% of the maximum density and D u being obtained by exposure of the as yet unripened emulsion to the extent which leads to the density D r in the case of ripened emulsion.
Claim 3
Dependent Claim 27 words
A photographic silver halide emulsion as claimed in claim 1, wherein the preparation of the emulsion is carried out for a while at least under reducing conditions.
Claim 4
Dependent Claim 29 words
A photographic silver halide emulsion as claimed in claim 1, wherein a pAg of at most 7 is maintained for a while at least during preparation of the emulsion.
Claim 5
Dependent Claim 22 words
A photographic silver halide emulsion as claimed in claim 1, wherein the emulsion is monodisperse and the silver halide grains are regular.
Claim 6
Dependent Claim 48 words
A photographic silver halide emulsion as claimed in claim 1, wherein the silver halide grains contain a core which consists essentially of silver bromide, at least one layer containing at least 30 mole percent of silver chloride and at least one outer layer consisting essentially of silver bromide.
Claim 7
Dependent Claim 23 words
A photographic silver halide emulsion as claimed in claim 1, wherein the total silver chloride content amounts to at most 20 mole percent.
Claim 8
Dependent Claim 27 words
A photographic silver halide emulsion as claimed in claim 1, wherein at least one layer of the silver halide grains is precipitated at a pAg below 5.0.
Claim 9
Dependent Claim 26 words
A photographic silver halide emulsion as claimed in claim 1, wherein the silver halide grains are chemically ripened at the surface thereof using a sulphur sensitiser.
Claim 10
Dependent Claim 39 words
A photographic recording material comprising at least one layer support, at least one photosensitive silver halide emulsion layer and, optionally, other layers, wherein an emulsion of the type claimed in claim 1 is present in at least one layer.
Claim 11
Dependent Claim 24 words
A photographic recording material as claimed in claim 9, wherein a colour coupler is present in at least one layer of the recording material.

References Cited (Backward Citations)

GB1027146A Cited
US3317322A Cited
US3622318A Cited
US3850637A Cited
US3935014A Cited
US3957488A Cited
US4431730A Cited
US4431731A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-22 1988-07-23 1989-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-22 1992-07-23 1993-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-22 1996-07-23 1997-01-22 $7700.00 Window Closed / Lapsed

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