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US4492641A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the chip forming, cutting or abrasive working of metals

Assignee: Kali Chemie AG
•
Filing: 1983-11-30
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Granted: 1985-01-08
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Expires: 2003-11-30
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Abstract

Abstract A process for chip forming, cutting or abrasive treatment of metals using a fluorochlorohydrocarbon containing cooling lubricant is described. The lubricant contains esters of long chain carboxylic acids and monoalcohols having a total of 34 to 50 carbon atoms or derivatives of said esters. Also disclosed is a cooling lubricant to be used in the process and a process for the preparation of such a cooling lubricant.

Inventors

  • 👤 Hans Buchwald
  • 👤 Boleslaus Raschkowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 18:48
CPC Classifications
C; C10; C10M; C10M169/00; C10M169/04; C10M105/00; C10M105/50; C10M105/52; C10M129/00; C10M129/02; C10M129/68; C10M129/70; C10M135/00; C10M135/02; C10M135/06; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/284; C10M2211/00; C10M2211/02; C10M2211/0206; C10M2211/022; C10M2211/0225; C10M2211/024; C10M2211/0245; C10M2219/00; C10M2219/02; C10M2219/024

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 58 words
In a process for working of metals using a cooling lubricant containing a fluorochlorohydrocarbon, the improvement comprising said cooling lubricant comprising from about 0.5 to 25% by weight of an ester of a long chain carboxylic acid and a monoalcohol having a total of 34 to 50 carbon atoms, and/or a sulfochlorinated or sulfided derivative of said ester.
Claim 2
Dependent Claim 58 words
In a process for working of metals using a cooling lubricant containing a fluorochlorohydrocarbon, the improvement comprising said cooling lubricant comprising from about 0.5 to 25% by weight of an ester of a long chain carboxylic acid and a monoalcohol having a total of 34 to 50 carbon atoms, and/or a sulfochlorinated or sulfided derivative of said ester.
Claim 3
Dependent Claim 24 words
A process according to claim 1, wherein said fluorochlorohydrocarbon-containing cooling lubricant comprises from about 0.5 to 5% by weight of said ester and/or derivative.
Claim 4
Dependent Claim 36 words
A process according to claim 1, wherein the cooling lubricant comprises from about 99.5 to 75% by weight of a fluorochlorohydrocarbon having 1 or 2 carbon atoms and a boiling point greater than about 20° C.
Claim 5
Dependent Claim 36 words
A process according to claim 3, wherein the cooling lubricant comprises from about 99.5 to 95% by weight of a fluorochlorohydrocarbon having 1 or 2 carbon atoms and a boiling point greater than about 20° C.
Claim 6
Dependent Claim 35 words
A process according to claim 1, wherein the cooling lubricant comprises up to about 35% by weight of said fluorochlorohydrocarbon, of a toxicologically acceptable solvent which is capable of controlling evaporation of the cooling lubricant.
Claim 7
Dependent Claim 24 words
A process according to claim 5, wherein said solvent is present in an amount up to about 15% by weight based upon said fluorochlorohydrocarbon.
Claim 8
Dependent Claim 17 words
A process according to claim 5, wherein said solvent comprises ethanol, n-propanol, i-propanol or a mixture thereof.
Claim 9
Dependent Claim 18 words
A process according to claim 1, wherein said ester has an iodine number of less than about 95.
Claim 10
Dependent Claim 31 words
A process according to claim 1, wherein said cooling lubricant comprises up to about 10% by weight of the fluorochlorohydrocarbon of an agent suitable for controlling the solubility of said ester.
Claim 11
Dependent Claim 20 words
A process according to claim 9, wherein said solubility controlling agent comprises an aliphatic hydrocarbon or a higher aliphatic alcohol.
Claim 12
Dependent Claim 16 words
A process according to claim 10, wherein said aliphatic hydrocarbon forms an azeotrope with the fluorochlorohydrocarbon.
Claim 13
Dependent Claim 12 words
A process according to claim 11, wherein said aliphatic hydrocarbon comprises n-heptane.
Claim 14
Dependent Claim 19 words
A process according to claim 10, wherein said higher aliphatic alcohol has from about 16 to 24 carbon atoms.
Claim 15
Dependent Claim 25 words
A process according to claim 1, wherein said cooling lubricant further comprises up to about 1% by weight of said fluorochlorohydrocarbon of a corrosion inhibitor.
Claim 16
Dependent Claim 29 words
A process according to claim 14, wherein said cooling lubricant comprises up to about 10% of said fluorochlorohydrocarbon of an agent for controlling the solubility of said corrosion inhibitor.
Claim 17
Dependent Claim 33 words
A process according to claim 15, wherein said solubility controlling agent for said corrosion inhibitor comprises a lower aliphatic alcohol having 1 to 5 carbon atoms which forms an azeotrope with said fluorochlorohydrocarbon.
Claim 18
Dependent Claim 23 words
A process according to claim 16, wherein said solubility controlling agent for said corrosion inhibitor comprises ethanol, n-propanol, i-propanol or a mixture thereof.
Claim 19
Dependent Claim 53 words
A cooling lubricant for use in a process according to claim 1, comprising a fluorochlorohydrocarbon and from about 0.5 to 25% by weight of an ester of a long chain carboxylic acid and a monoalcohol having a total of 34 to 50 carbon atoms, and/or a sulfochlorinated or sulfided derivative of said ester.
Claim 20
Dependent Claim 61 words
Process for the preparation of a cooling lubricant according to claim 18, comprising the steps of extracting a vegetable material containing said esters with a fluorochlorohydrocarbon having 1 or 2 carbon atoms and a boiling point of more than about 20° C., and adjusting the extract containing the esters to an ester content of from about 0.5 to 25% by weight.
Claim 21
Dependent Claim 42 words
A process according to claim 19, wherein said extraction is carried out as a counter-flow extraction and further comprising the step of continuously adjusting the ester content by measuring at least one property of the extractant which is indicative of ester content.
Claim 22
Dependent Claim 22 words
A process according to claim 9, wherein said solubility controlling agent comprises a lower aliphatic alcohol having 1 to 5 carbon atoms.

References Cited (Backward Citations)

US3129182A Cited
US3909431A Cited
US4084737A Cited
US4428851A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-08 1988-07-09 1989-01-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-08 1992-07-09 1993-01-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-08 1996-07-09 1997-01-08 $7700.00 Window Closed / Lapsed

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