Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands

Claim 2

A process for producing aldehydes comprising of hydroformylating an olefinically unsaturated compound with carbon monoxide and hydrogen in a hydroformylation reaction medium containing a rhodium complex catalyst, free triarylphosphine ligand and free organic tertiary bisphosphine monooxide ligand having the general formula ##STR12## wherein Ar represents an identical or different substituted or unsubstituted aryl radical, each R 1 , R 2 and R 3 group represents an identical or different substituted or unsubstituted monovalent hydrocarbon radical and Y represents a divalent bridging group; and wherein the mole ratio of free triarylphosphine ligand to free bisphosphine monooxide ligand present in said reaction medium ranges from about 2:1 to about 30 to 1.

Claim 3

A process as defined in claim 1, wherein the hydroformylation reaction conditions are controlled to provide a temperature of from about 45° C. to about 200° C., a total gas pressure of hydrogen, carbon monoxide and olefinically unsaturated compound of less than about 500 psia., a carbon monoxide partial pressure of from about 1 to 50 psia., a hydrogen partial pressure of from about 20 to about 200 psia., and wherein said reaction medium contains at least about 10 moles of total free phosphorus ligand per mole of catalytically active rhodium metal in said medium.

Claim 4

A process as defined in claim 1, wherein the olefinically unsaturated compound contains from 2 to 20 carbon atoms selected from the group consisting of alpha olefinic compounds and internal olefinic compounds, the triarylphosphine ligand is triphenylphosphine, wherein the mole ratio of free triphenylphosphine ligand to free bisphosphine monooxide ligand ranges from about 5:1 to about 15:1, and wherein in the bisphosphine monooxide formula the Ar represents an identical or different substituted or unsubstituted aryl radical containing from 6 to 12 carbon atoms; each R 1 , R 2 and R 3 group represents an identical or different substituted or unsubstituted monovalent hydrocarbon radical containing from 1 to 30 carbon atoms and selected from the group consisting of alkyl, aryl, alkaryl, aralkyl and alicyclic radicals, and Y represents a divalent bridging group containing from 1 to 30 carbon atoms selected from the group consisting of hydrocarbon radicals, oxygen containing hydrocarbon radicals, sulfur containing hydrocarbon radicals and nitrogen containing hydrocarbon radicals.

Claim 5

A process as defined in claim 3, wherein R 1 , R 2 and R 3 represent a substituted or unsubstituted monovalent hydrocarbon radical selected from the group consisting of alkyl radicals having from 1 to 12 carbon atoms and aryl radicals having from 6 to 12 carbon atoms, and wherein Y contains from 1 to 12 carbon atoms.

Claim 6

A process as defined in claim 4, wherein Ar is an unsubstituted aryl radical; R 1 , R 2 and R 3 represent unsubstituted alkyl or aryl radicals, and Y is a divalent hydrocarbon radical.

Claim 7

A process as defined in claim 5, wherein said bisphosphine monooxide is a ligand having the formula ##STR13## wherein n is an integer of 2 to 8.

Claim 8

A process as defined in claim 6, where n is 2.