US3859359A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Compound and method
Assignee: Ethyl Corp
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Filing: 1971-12-20
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Granted: 1975-01-07
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Expires: 1991-12-20
Abstract
Abstract Novel rhodium complexes having formula HRhCO(L(OR)3)3 are produced by reacting XRhCO(L(OR)3)2, L(OR)3 and a metal borohydride under controlled conditions. In the formulae, L is As, Sb or P; R is alkyl and/or aryl; X is a halogen. The complexes are rate improving hydroformylation catalysts.
Inventors
- 👤 Kestutis A Keblys
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 02:04
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/16; B01J31/18; B01J31/1845; B01J31/185; B01J31/1895; B01J31/20; B01J31/24; B01J31/2404; C; C07; C07C; C07C45/00; C07C45/49; C07C45/50; C07F; C07F15/00; C07F15/0006; C07F15/0073; C07F15/008; C07F9/00; C07F9/66; C07F9/68; C07F9/90; C07F9/902; B01J2231/00; B01J2231/30; B01J2231/32; B01J2231/321; B01J2231/50; B01J2231/52; B01J2531/00; B01J2531/80; B01J2531/82; B01J2531/822; B01J2540/00; B01J2540/20; B01J2540/22; B01J2540/225
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
106 words
A PROCESS FOR PREPRING ALDEHYDES WHICH CONSISTS ESSENTIALLY OF REACTING A. OLEFINIC ORGANIC COMPOUNDS HAVING TWO TO ABOUT 32 CARBON ATOMS AND AT LEAST ONE NON-AROMATIC CARBON-TOCARBON DOUBLE BOND, B. CARBON MONOXIDE, AND C. HYDROGEN. USING, AS CATALYSTS, PERFORMED COMPOUNDS HAVING THE FORMULA HRH(CO)(L(OR1)(OR2))3 WHEREIN L IS SELECTED FROM P, AS, AND SB AND R1, R2, R3 ARE IDEPENDENTLY SELECTED FROM THE GROUPS CONSISTING OF ALKYL AND ARYL, SAID GROUPS HAVING FROM ONE TO ABOUT 18 CARBON ATOMS, AT TEMPERATURES RANGING FROM ABOUT 0*C. TO ABOUT 50*C. AND AT PRESSURE RANGING FROM 1 ATMOSPHERE TO ABOUT 10 ATMOSPHERES, AND IN THE ABSENCE OF EXCESS LIGAND L(OR1)(OR2)(OR3).
Claim 2
Dependent Claim
106 words
A PROCESS FOR PREPRING ALDEHYDES WHICH CONSISTS ESSENTIALLY OF REACTING A. OLEFINIC ORGANIC COMPOUNDS HAVING TWO TO ABOUT 32 CARBON ATOMS AND AT LEAST ONE NON-AROMATIC CARBON-TOCARBON DOUBLE BOND, B. CARBON MONOXIDE, AND C. HYDROGEN. USING, AS CATALYSTS, PERFORMED COMPOUNDS HAVING THE FORMULA HRH(CO)(L(OR1)(OR2))3 WHEREIN L IS SELECTED FROM P, AS, AND SB AND R1, R2, R3 ARE IDEPENDENTLY SELECTED FROM THE GROUPS CONSISTING OF ALKYL AND ARYL, SAID GROUPS HAVING FROM ONE TO ABOUT 18 CARBON ATOMS, AT TEMPERATURES RANGING FROM ABOUT 0*C. TO ABOUT 50*C. AND AT PRESSURE RANGING FROM 1 ATMOSPHERE TO ABOUT 10 ATMOSPHERES, AND IN THE ABSENCE OF EXCESS LIGAND L(OR1)(OR2)(OR3).
Claim 3
Dependent Claim
20 words
The process of claim 1 wherein said olefinic organic compounds are olefins having at least one alpha carbon-to-carbon douBle bond.
Claim 4
Dependent Claim
11 words
The process of claim 2 wherein said olefins are alpha monoolefins.
Claim 5
Dependent Claim
22 words
The process of claim 1 wherein said catalysts have the formula HRhCO(P(OR1)(OR2)(OR3))3 and R1, R2, R3 are as defined in claim 1.
Claim 6
Dependent Claim
12 words
The process of claim 4 wherein R1, R2, R3 are the same.
Claim 7
Dependent Claim
33 words
The process of claim 5 wherein R1, R2, R3 are selected from hydrocarbon alkyl groups and substituted alkyl groups wherein the substituting groups are selected from halogen, C1-C4 alkoxy, cyano, nitro and phenyl.
Claim 8
Dependent Claim
37 words
The process of claim 5 wherein R1, R2, R3 are selected from phenyl and substituted phenyl groups wherein the substituting groups are selected from halogen, C1 -C4 alkoxy, C1 -C6 alkyl, cyano, C1-C6 haloalkyl, nitro and phenyl.
Claim 9
Dependent Claim
20 words
The process of claim 4 wherein said olefinic organic compounds are olefins having at least one alpha carbon-to-carbon double bond.
Claim 10
Dependent Claim
11 words
The process of claim 4 wherein said olefins are alpha monoolefins.
Claim 11
Dependent Claim
12 words
The process of claim 8 wherein R1, R2, R3 are the same.
Claim 12
Dependent Claim
20 words
The process of claim 5 wherein said olefinic organic compounds are olefins having at least one alpha carbon-to-carbon double bond.
Claim 13
Dependent Claim
20 words
The process of claim 6 wherein said organic olefinic compounds are olefins having at least one alpha carbon-to-carbon double bond.
Claim 14
Dependent Claim
20 words
The process of claim 7 wherein said olefinic organic compounds are olefins having at least one alpha carbon-to-carbon double bond.
Claim 15
Dependent Claim
16 words
The process of claim 2 wherein said temperature is from about 0* C. to about 30+C.
Claim 16
Dependent Claim
12 words
The process of claim 14 wherein said pressure is about 1 atmosphere.
Claim 17
Dependent Claim
11 words
The process of claim 13 wherein said catalyst is selected from
Claim 18
Dependent Claim
17 words
The process of claim 16 wherein said temperature is from about 0* C. to about 30* C.
Claim 19
Dependent Claim
12 words
The process of claim 17 wherein said pressure is about 1 atmosphere.
Claim 20
Dependent Claim
10 words
The process of claim 18 wherein said olefin is octene-1.
References Cited (Backward Citations)
US3527809A
Cited
US3641076A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-01-06 | 1978-07-08 | 1979-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-01-06 | 1982-07-08 | 1983-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-01-06 | 1986-07-08 | 1987-01-07 | $7700.00 | Window Closed / Lapsed |