Patent US4490495A successfully refreshed from Google Patents.
US4490495A
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US
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Composition and method for tinting plastic
Assignee: Aotec Inc
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Filing: 1982-11-15
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Granted: 1984-12-25
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Expires: 2002-11-15
Abstract
Abstract A solution for coating plastic material for tinting and the method of making said solution is described. The process for coating plastic material and for tinting the material is also described. This solution and process provides scratch resistance to the surface of the coated polycarbonate and CR-39 lenses, absorbs dye and permits the plastics to absorb the dye and adheres strongly to the plastic surface.
Inventors
- 👤 Hermann Weber
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 17:56
CPC Classifications
C; C09; C09D; C09D161/00; C09D161/20; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
158 words
A solution for coating plastic material for tinting comprising by volume, all percentages based upon the final concentrations: (a) a first mixture of: (1) 14.5% to 18.5% water reasonably free of dissolved solids whereby there is minimal precipitation of said solids upon addition of the other components, and (2) 31.5% to 51.5% of a component selected from the group consisting of n-butanol, 2-butoxyethanol, and a mixture in the range of 3:1 to 1:3 by volume of: (i) an alcohol selected from the group consisting of n-butanol and 2-butoxyethanol, and (ii) a silane compound selected from the group consisting of glycidoxypropyltrimethoxysilane and vinyltrimethylsilane (b) a second mixture of: (1) 7.5% to 17.5% alkyl titanate; (2) 11.5% to 21.5% methanol; (3) 1.7% to 2.3% of strong inorganic acid; (c) a third mixture of: (1) 3% to 9% hexamethoxymethylmelamine; and (2) 3% to 9% synthetic resin comprising urea-formaldehyde and melamine formaldehyde condensates; and (d) 25 to 83 parts per million surfactant.
Claim 2
Dependent Claim
158 words
A solution for coating plastic material for tinting comprising by volume, all percentages based upon the final concentrations: (a) a first mixture of: (1) 14.5% to 18.5% water reasonably free of dissolved solids whereby there is minimal precipitation of said solids upon addition of the other components, and (2) 31.5% to 51.5% of a component selected from the group consisting of n-butanol, 2-butoxyethanol, and a mixture in the range of 3:1 to 1:3 by volume of: (i) an alcohol selected from the group consisting of n-butanol and 2-butoxyethanol, and (ii) a silane compound selected from the group consisting of glycidoxypropyltrimethoxysilane and vinyltrimethylsilane (b) a second mixture of: (1) 7.5% to 17.5% alkyl titanate; (2) 11.5% to 21.5% methanol; (3) 1.7% to 2.3% of strong inorganic acid; (c) a third mixture of: (1) 3% to 9% hexamethoxymethylmelamine; and (2) 3% to 9% synthetic resin comprising urea-formaldehyde and melamine formaldehyde condensates; and (d) 25 to 83 parts per million surfactant.
Claim 3
Dependent Claim
60 words
The solution of claim 1 wherein said water is distilled deionized water, said alkyl titanate is selected from the group consisting of tetraisopropyl titanate and tetrabutyl titanate, said strong inorganic acid is selected from the group consisting of sulfuric acid, hydrochloric acid and nitric acid, and said surfactant is selected from the group consisting of silicone glycol and fluorocarbon surfactants.
Claim 4
Dependent Claim
21 words
The solution of claim 1 wherein said alcohol-silane mixture is a 3 to 1 mixture by volume of glycidoxypropyltrimethoxysilane and n-butanol.
Claim 5
Dependent Claim
25 words
The solution of claim 1 wherein said alkyl titanate is tetraisopropyl titanate, said strong inorganic acid is sulfuric acid, and said surfactant is silicone glycol.
Claim 6
Dependent Claim
81 words
A solution for coating polycarbonate material for tinting comprising by volume, all percentages based upon the final concentrations: (a) a first mixture of: (1) 10% n-butanol, and (2) 31.5% glycidoxypropyltrimethylsilane, (3) 16.5% distilled deionized water, (b) a second mixture of: (1) 12.5% tetraisopropyltitanate, (2) 16.5% methanol, and (3) 2.0% sulfuric acid, (c) a third mixture of: (1) 5.5% hexamethoxymethyl melamine, and (2) 5.5% synthetic resin composition comprising urea formaldehyde, and melamine formaldehyde condensates, and (d) 82 parts per million silicone glycol.
Claim 7
Dependent Claim
81 words
A solution for coating polycarbonate material for tinting comprising by volume, all percentages based upon the final concentrations: (a) a first mixture of: (1) 10% n-butanol, and (2) 31.5% glycidoxypropyltrimethylsilane, (3) 16.5% distilled deionized water, (b) a second mixture of: (1) 12.5% tetraisopropyltitanate, (2) 16.5% methanol, and (3) 2.0% sulfuric acid, (c) a third mixture of: (1) 5.5% hexamethoxymethyl melamine, and (2) 5.5% synthetic resin composition comprising urea formaldehyde, and melamine formaldehyde condensates, and (d) 82 parts per million silicone glycol.
Claim 8
Independent Claim
151 words
The method of making a solution for coating plastic material for tinting comprising the steps of: (1) mixing in a ratio of from 1:3 to 3:1 by volume an alcohol selected from the group n-butanol and 2-butoxyethanol and silane selected from the group consisting of glycidoxypropyltrimethoxysilane and vinyltrimethylsilane, (2) mixing together 31.5% to 51.5% of the mixture of the first step with 14.5% to 18.5% water; (3) mixing together 11.5% to 16.5% methanol, 1.7% to 2.3% of a strong acid and 7.5% to 17.5% alkyl titanate; (4) mixing together the mixtures of the second and third steps; (5) mixing together 3% to 9% hexamethoxymethylmelamine and 3% to 9% melamine formaldehyde resin solution; (6) mixing together the mixtures of the fourth and fifth steps; and (7) adding silicone glycol making a final concentration in the range of 25 to 83 parts per million, all percentages by volume based on the final concentration.
Claim 9
Independent Claim
151 words
The method of making a solution for coating plastic material for tinting comprising the steps of: (1) mixing in a ratio of from 1:3 to 3:1 by volume an alcohol selected from the group n-butanol and 2-butoxyethanol and silane selected from the group consisting of glycidoxypropyltrimethoxysilane and vinyltrimethylsilane, (2) mixing together 31.5% to 51.5% of the mixture of the first step with 14.5% to 18.5% water; (3) mixing together 11.5% to 16.5% methanol, 1.7% to 2.3% of a strong acid and 7.5% to 17.5% alkyl titanate; (4) mixing together the mixtures of the second and third steps; (5) mixing together 3% to 9% hexamethoxymethylmelamine and 3% to 9% melamine formaldehyde resin solution; (6) mixing together the mixtures of the fourth and fifth steps; and (7) adding silicone glycol making a final concentration in the range of 25 to 83 parts per million, all percentages by volume based on the final concentration.
Claim 10
Dependent Claim
59 words
The method of claim 6 wherein said water is distilled deionized water, said alkyl titanate is selected from the group consisting of tetraisopropyl titanate and tetrabutyl titanate, said strong inorganic acid is selected from the group consisting of sulfuric acid, hydrochloric acid and nitric acid, and said surfactant is selected from the group comprising silicone glycol and fluorocarbon surfactants.
Claim 11
Dependent Claim
21 words
The solution of claim 6 wherein said mixture of two components is a 3 to 1 mixture of glycidoxypropyltrimethoxysilane and n-butanol.
Claim 12
Dependent Claim
25 words
The solution of claim 6 wherein said alkyl titanate is tetraisopropyl titanate, said strong inorganic acid is sulfuric acid, and said surfactant is silicone glycol.
Claim 13
Dependent Claim
31 words
The method of claim 6 wherein the third step further comprises mixing tetraisopropyl titanate, methanol and sulfuric acid with a magnetic stirrer until said mixture is a single phase and clear.
Claim 14
Independent Claim
165 words
The method of making a solution for coating plastic material comprising the steps of: (1) mixing together n-butanol and glycidoxypropyltrimethoxysilane in a ratio of about 1:3, (2) mixing together the mixture of the first step with distilled deionized water in a a ratio of about 2.5:1, (3) mixing together tetraisopropyl titanate, methanol and 37% sulfuric acid in a ratio of about 6:8:1 with a stirring instrument whereby said mixture is a single phase and clear, (4) mixing together the mixture of the second step with the mixture of the third step in a ratio of about 2:1, (5) mixing together hexamethoxymethymelamine and melamine formaldehyde resin solution in a ratio of about 1:1, (6) mixing together the mixture of the fourth step with the mixture of resins from the fifth step in a ratio of about 8:1, (7) adding silicone glycol to the mixture of the prior step, said siloxane having a final concentration in the mixture of 0.082%, all ratios and percentages based on volume.
Claim 15
Independent Claim
165 words
The method of making a solution for coating plastic material comprising the steps of: (1) mixing together n-butanol and glycidoxypropyltrimethoxysilane in a ratio of about 1:3, (2) mixing together the mixture of the first step with distilled deionized water in a a ratio of about 2.5:1, (3) mixing together tetraisopropyl titanate, methanol and 37% sulfuric acid in a ratio of about 6:8:1 with a stirring instrument whereby said mixture is a single phase and clear, (4) mixing together the mixture of the second step with the mixture of the third step in a ratio of about 2:1, (5) mixing together hexamethoxymethymelamine and melamine formaldehyde resin solution in a ratio of about 1:1, (6) mixing together the mixture of the fourth step with the mixture of resins from the fifth step in a ratio of about 8:1, (7) adding silicone glycol to the mixture of the prior step, said siloxane having a final concentration in the mixture of 0.082%, all ratios and percentages based on volume.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-12-25 | 1988-06-25 | 1988-12-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-12-25 | 1992-06-25 | 1992-12-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-12-25 | 1996-06-25 | 1996-12-25 | $7700.00 | Window Closed / Lapsed |