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Alumina-based aerogel supported transition metal catalyst useful as a Ziegler-Natta olefin polymerization catalyst and process for preparing same

Assignee: Honeywell International Inc
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Filing: 1982-09-24
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Granted: 1984-10-23
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Expires: 2002-09-24
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Abstract

Abstract A new polymerization catalyst system comprising an aluminum compound and a transition metal compound on an alumina-based aerogel support, a process for preparing the polymerization catalyst system and use of the catalyst system for polymerization and copolymerization of alpha-olefins are disclosed. A heat-activated alumina-based aerogel useful as a catalyst support and having a morphology by transmission electron microcopy comprising extremely thin folded film-like ribbons or plates and having a high BET surface area, high pore volume, and low bulk density is also disclosed.

Inventors

  • 👤 Anthony J. Fanelli
  • 👤 Alson K. Price

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 14:12
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 219 words
A process for the polymerization and copolymerization of alpha-olefins which comprises contacting an alpha-olefin at a temperature and at a pressure sufficient to initiate the polymerization and copolymerization with a catalytic amount of (a) a di(C 1 -C 18 alkyl) chloroaluminum compound or a tri(C 1 -C 18 alkyl) aluminum compound; and (b) a catalyst produced by the reaction of a transition metal compound formed from members selected from the group consisting of titanium, vanadium, hafnium, and zirconium and from members selected from the group consisting of chlorides, oxychlorides, alkoxychlorides and oxyalkoxychlorides with a heat-activated alumina based aerogel having a morphology by transmission electron microscopy comprising thin film-like structures and having a bulk density less than about 0.10 g/cm 3 , a BET surface area greater than about 300 m 2 /g and a pore volume greater than about 3 cm 3 /g and obtained by heating an alumina-based aerogel having a carbon content at a temperature of at least about 400° C., in the presence of oxygen, for a time sufficient to produce said heat activated alumina-based aerogel substantially free of carbon; said alumina-based aerogel being prepared by venting a C 1 -C 5 alcohol or mixture of same, under supercritical conditions, from a mixture comprising a hydrolyzable aluminum compound, water, and a C 1 -C 5 alcohol.
Claim 2
Dependent Claim 219 words
A process for the polymerization and copolymerization of alpha-olefins which comprises contacting an alpha-olefin at a temperature and at a pressure sufficient to initiate the polymerization and copolymerization with a catalytic amount of (a) a di(C 1 -C 18 alkyl) chloroaluminum compound or a tri(C 1 -C 18 alkyl) aluminum compound; and (b) a catalyst produced by the reaction of a transition metal compound formed from members selected from the group consisting of titanium, vanadium, hafnium, and zirconium and from members selected from the group consisting of chlorides, oxychlorides, alkoxychlorides and oxyalkoxychlorides with a heat-activated alumina based aerogel having a morphology by transmission electron microscopy comprising thin film-like structures and having a bulk density less than about 0.10 g/cm 3 , a BET surface area greater than about 300 m 2 /g and a pore volume greater than about 3 cm 3 /g and obtained by heating an alumina-based aerogel having a carbon content at a temperature of at least about 400° C., in the presence of oxygen, for a time sufficient to produce said heat activated alumina-based aerogel substantially free of carbon; said alumina-based aerogel being prepared by venting a C 1 -C 5 alcohol or mixture of same, under supercritical conditions, from a mixture comprising a hydrolyzable aluminum compound, water, and a C 1 -C 5 alcohol.
Claim 3
Dependent Claim 115 words
The process of claim 1 wherein the alumina-based aerogel is prepared by (a) forming a solution or suspension comprising an alcohol or mixture of alcohols selected from C 1 -C 5 alcohol and a hydrolyzable aluminum compound and at least about a stoichiometric amount of water required to hydrolyze said hydrolyzable aluminum compound; (b) heating the suspension or solution so formed in the presence of a C 1 -C 5 alcohol or mixture of same to a temperature above the critical temperature of said alcohol or said mixture; and (c) removing said alcohol or mixture of same under super-critical conditions to form an alumina-based aerogel having a carbon content greater than about 1 weight percent.
Claim 4
Dependent Claim 69 words
The process of claim 2 wherein the solution or suspension formed in step (a) comprises at least about 65 weight percent (basis Al 2 O 3 ) of a hydrolyzable aluminum compound and up to about 35 weight percent (basis metal oxide) of at least one member selected from the group consisting of hydrolyzable compounds of calcium, barium, magnesium, cerium, lanthanum, titanium, zirconium, chromium, zinc, gallium, silicon and antimony.
Claim 5
Dependent Claim 53 words
The process of claim 2 wherein the alumina-based aerogel is prepared by forming a suspension in the step (a) and wherein the C 1 -C 5 alcohol used in step (b) is methanol and wherein the carbon content of the alumina aerogel formed in step (c) is at least about 1-8 weight percent.
Claim 6
Dependent Claim 32 words
The process of claim 4 wherein the alcohol in steps (a) and (b) is methanol and wherein the carbon content of the alumina-based aerogel formed is at least about 1-8 weight percent.
Claim 7
Dependent Claim 43 words
The process of claim 2 wherein a solution of aluminum isopropoxide in isopropanol is formed in step (a) and wherein in step (b) methanol is added to the suspension formed in step (a) and wherein in step (c) methanol and isopropanol are removed.
Claim 8
Dependent Claim 28 words
The process of claim 1 wherein the transition metal compound is TiCl 4 and the ratio of Cl to Ti in the catalyst is no more than 4:1.
Claim 9
Dependent Claim 10 words
The process of claim 1 wherein the alpha-olefin is ethylene.
Claim 10
Dependent Claim 21 words
The process of claims 1 or 7 wherein the heat-activated alumina-based aerogel of the catalyst is substantially free of fluorinated alumina.
Claim 11
Dependent Claim 27 words
The process of claim 8 wherein the temperature is from about 50° C. to about 100° C. and the pressure is from about 450 to 650 psig.
Claim 12
Dependent Claim 17 words
The process of claim 8 wherein the polymerization and copolymerization are effected in the absence of hydrogen.
Claim 13
Dependent Claim 17 words
The process of claim 8 wherein the polymerization and copolymerization are effected in the presence of hydrogen.
Claim 14
Dependent Claim 28 words
The process of claim 12 wherein the ratio of the pressure of hydrogen to the pressure of ethylene is in the range of about 0.5:1 to about 5:1.
Claim 15
Dependent Claim 30 words
The process of claim 12 wherein the ratio of the pressure of hydrogen to the pressure of ethylene is in the range of about 0.5:1 to less than about 1.5:1.
Claim 16
Dependent Claim 30 words
The process of claim 12 wherein the ratio of the pressure of hydrogen to the pressure of ethylene is in the range of about 0.75:1 to less than about 1.0:1.
Claim 17
Dependent Claim 30 words
The process of claim 1 wherein the alpha olefins ethylene and wherein the temperature is at least about 50° C. and a pressure in the range of about 1000 psig.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-23 1988-04-23 1988-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-23 1992-04-23 1992-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-23 1996-04-23 1996-10-23 $7700.00 Window Closed / Lapsed

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