Patent US4476198A successfully refreshed from Google Patents.
US4476198A
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Solid oxide fuel cell having monolithic core
Assignee: United States Department of Energy
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Filing: 1983-10-12
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Granted: 1984-10-09
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Expires: 2003-10-12
Abstract
Abstract A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.
Inventors
- 👤 John P. Ackerman
- 👤 John E. Young
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:17
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/24; H01M8/241; H01M8/2425; H01M8/2435; H01M8/02; H01M8/0202; H01M8/0258; H01M8/026; H01M8/10; H01M8/12; H01M8/1231; H01M8/2465; H01M8/2484; H01M8/2485; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
197 words
A fuel cell for electrochemically combining fuel and oxidant for generation of galvanic output, comprising the combination of a core having an array of electrolyte and interconnect walls, each electrolyte wall consisting of thin layers of cathode and anode materials respectively, sandwiching a thin layer of electrolyte material therebetween, each interconnect wall consisting of thin layers of the cathode and anode, respectively sandwiching a thin layer of interconnect material therebetween, whereby separate sections of said electrolyte wall are arranged between separate sections of adjacent interconnect walls operable to define a plurality of core passageways alternately arranged respectively where the inside faces thereof are formed either of only the anode material or of only the cathode material, each core passageway having the anode material on the inside being for the fuel and each core passageway having the cathode material on the inside being for the oxidant, means to direct the fuel and the oxidant for flow through the respective anode and cathode passageway, means to direct the galvanic output from the anode and cathode materials to an exterior circuit, and the electrolyte and interconnect walls being substantially devoid of any composite inert material and the core being monolithic.
Claim 2
Dependent Claim
197 words
A fuel cell for electrochemically combining fuel and oxidant for generation of galvanic output, comprising the combination of a core having an array of electrolyte and interconnect walls, each electrolyte wall consisting of thin layers of cathode and anode materials respectively, sandwiching a thin layer of electrolyte material therebetween, each interconnect wall consisting of thin layers of the cathode and anode, respectively sandwiching a thin layer of interconnect material therebetween, whereby separate sections of said electrolyte wall are arranged between separate sections of adjacent interconnect walls operable to define a plurality of core passageways alternately arranged respectively where the inside faces thereof are formed either of only the anode material or of only the cathode material, each core passageway having the anode material on the inside being for the fuel and each core passageway having the cathode material on the inside being for the oxidant, means to direct the fuel and the oxidant for flow through the respective anode and cathode passageway, means to direct the galvanic output from the anode and cathode materials to an exterior circuit, and the electrolyte and interconnect walls being substantially devoid of any composite inert material and the core being monolithic.
Claim 3
Dependent Claim
67 words
An electrochemical fuel cell according to claim 1, wherein said cathode is lanthanum manganite (LaMnO 3 ); said anode is cobalt yttria-stabilized zirconia cermet or mixture (Co+ZrO 3 Y 2 O 3 ); said electrolyte is yttria-stabilized zirconia (ZrO 2 +Y 2 O 3 ); and said interconnect is lanthanum chromite (LaCrO 3 ), the lanthanum manganite and lanthanum chromite being suitably doped to obtain electrical conductivity.
Claim 4
Dependent Claim
23 words
An electrochemical fuel cell according to claim 1, wherein the interconnect walls are somewhat planar and are disposed substantially parallel to one another.
Claim 5
Dependent Claim
46 words
An electrochemical fuel cell according to claim 3, wherein said electrolyte walls defining said passageways are generally planar and are angled relative to one another and relative to the interconnect walls, whereby the defined flow passageways are shaped in cross section somewhat as alternately inverted triangles.
Claim 6
Dependent Claim
67 words
An electrochemical fuel cell according to claim 4, wherein said cathode is lanthanum manganite (LaMnO 3 ); said anode is cobalt yttria-stabilized zirconia cermet or mixture (Co+ZrO 3 Y 2 O 3 ); said electrolyte is yttriastabilized zirconia (ZrO 2 +Y 2 O 3 ); and said interconnect is lanthanum chromite (LaCrO 3 ), the lanthanum manganite and lanthanum chromite being suitably doped to obtain electrical conductivity.
Claim 7
Dependent Claim
32 words
An electrochemical fuel cell according to claim 4, wherein the electrolyte and interconnect walls meet one another at junctures and wherein the junctures are spaced from and laterally offset from one another.
Claim 8
Dependent Claim
43 words
An electrochemical fuel cell according to claim 6, wherein each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick, and wherein each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick.
Claim 9
Dependent Claim
28 words
An electrochemical fuel cell according to claim 4, wherein the electrolyte and interconnect walls meet one another at junctures and wherein the junctures are paired opposite one another.
Claim 10
Dependent Claim
43 words
An electrochemical fuel cell according to claim 8, wherein each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick, and wherein each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick.
Claim 11
Dependent Claim
25 words
An electrochemical fuel cell according to claim 3, wherein said electrolyte walls defining said passageways are wavy and extended between adjacent pairs of interconnect walls.
Claim 12
Dependent Claim
22 words
An electrochemical fuel cell according to claim 10, wherein the wavy electrolyte walls are generally in the form of sinusoidally shaped waves.
Claim 13
Dependent Claim
47 words
An electrochemical fuel cell according to claim 1, wherein the cells defined between any adjacent pairs of interconnect walls generate electrical potential in parallel with one another, and wherein the cells defined on opposite sides of any interconnect wall generate electrical potential in series with one another.
Claim 14
Dependent Claim
25 words
An electrochemical fuel cell according to claim 1, wherein each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick.
Claim 15
Dependent Claim
25 words
An electrochemical fuel cell according to claim 1, wherein each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.
Claim 16
Dependent Claim
20 words
An electrochemical fuel cell according to claim 1, wherein each electrolyte wall is of the order of 0.006-0.11 cm thick.
Claim 17
Dependent Claim
20 words
An electrochemical fuel cell according to claim 1, wherein each interconnect wall is of the order of 0.006-0.11 cm thick.
Claim 18
Dependent Claim
32 words
An electrochemical fuel cell according to claim 1, wherein the electrolyte and interconnect walls meet one another at junctures and wherein the junctures are spaced from and laterally offset from one another.
Claim 19
Dependent Claim
28 words
An electrochemical fuel cell according to claim 1, wherein the electrolyte and interconnect walls meet one another at junctures and wherein the junctures are paired opposite one another.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-10-09 | 1988-04-09 | 1988-10-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-10-09 | 1992-04-09 | 1992-10-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-10-09 | 1996-04-09 | 1996-10-09 | $7700.00 | Window Closed / Lapsed |