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US4474862A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat rechargeable iron battery system

Assignee: Westinghouse Electric Corp
•
Filing: 1983-11-10
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Granted: 1984-10-02
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Expires: 2003-11-10
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Abstract

Abstract The iron electrodes of a battery are recharged by removing them from the battery, heating them in a reducing gas atmosphere at over about 450° C., for a sufficient time to convert discharged iron compounds to charged iron compounds, and then cooling the charged electrodes.

Inventors

  • 👤 Edward S. Buzzelli
  • 👤 Jack T. Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:26
CPC Classifications
H; H01; H01M; H01M12/00; H01M12/04; H01M12/06; H01M12/065; B; B60; B60L; B60L50/00; B60L50/50; B60L50/60; B60L50/64; H01M10/00; H01M10/42; H01M10/44; H01M4/00; H01M4/02; H01M2004/024; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02T; Y02T10/00; Y02T10/60; Y02T10/70

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 83 words
A method of recharging an iron electrode from a battery, the battery comprising removable iron electrodes containing discharged iron compounds disposed in alkali electrolyte between electrode cathodes, all contained in a casing, comprising the steps of: (1) removing discharged iron electrodes from the battery; (2) heating the discharged iron electrodes in a reducing gas atmosphere at over about 450° C., for a time effective to convert discharged iron compounds to charged iron compounds in the electrodes; and (3) cooling the charged iron electrodes.
Claim 2
Independent Claim 83 words
A method of recharging an iron electrode from a battery, the battery comprising removable iron electrodes containing discharged iron compounds disposed in alkali electrolyte between electrode cathodes, all contained in a casing, comprising the steps of: (1) removing discharged iron electrodes from the battery; (2) heating the discharged iron electrodes in a reducing gas atmosphere at over about 450° C., for a time effective to convert discharged iron compounds to charged iron compounds in the electrodes; and (3) cooling the charged iron electrodes.
Claim 3
Dependent Claim 31 words
The method of claim 1, where the discharged iron electrode is heated at from about 450° C. to about 700° C. in hydrogen gas, and is washed of electrolyte before heating.
Claim 4
Independent Claim 103 words
A method of quickly recharging an iron-air battery, the battery comprising removable iron electrodes containing discharged iron compounds disposed in alkali electrolyte between two air electrodes, all contained in a casing having air inlet means, comprising the steps of: (1) removing discharged iron electrodes from an iron-air battery; (2) heating the discharged iron electrodes in a reducing gas atmosphere at from about 450° C. to about 700° C., for up to about 20 minutes, to convert discharged iron compounds to charged iron compounds in the electrodes; (3) cooling the charged iron electrodes; and (4) replacing the charged iron electrodes in an iron-air battery.
Claim 5
Independent Claim 103 words
A method of quickly recharging an iron-air battery, the battery comprising removable iron electrodes containing discharged iron compounds disposed in alkali electrolyte between two air electrodes, all contained in a casing having air inlet means, comprising the steps of: (1) removing discharged iron electrodes from an iron-air battery; (2) heating the discharged iron electrodes in a reducing gas atmosphere at from about 450° C. to about 700° C., for up to about 20 minutes, to convert discharged iron compounds to charged iron compounds in the electrodes; (3) cooling the charged iron electrodes; and (4) replacing the charged iron electrodes in an iron-air battery.
Claim 6
Dependent Claim 38 words
The method of claim 3, where the discharged iron electrode is heated in a gas selected from the group consisting of hydrogen, carbon monoxide, dissociated ammonia, reformed hydrocarbons, and mixtures thereof, and is washed of electrolyte before heating.
Claim 7
Dependent Claim 15 words
The method of claim 3, where the discharged iron electrode is heated in hydrogen gas.
Claim 8
Dependent Claim 30 words
The method of claim 3, where the discharged iron electrode contains iron compounds substantially as Fe(OH) 2 , and is heated at from about 500° C. to about 700° C.
Claim 9
Dependent Claim 21 words
The method of claim 3, where the charged iron electrode contains elemental iron, and is cooled in a nitrogen gas environment.
Claim 10
Dependent Claim 62 words
The method of claim 3, where the alkali electrolyte is an alkali hydroxide, the iron electrodes are removably attached to a removable support plate, the iron electrode comprises active material disposed within a porous fiber metal current collector, and the air electrode comprises an active material hydrophilic layer containing a current collector disposed next to electrolyte and bonded to a hydrophobic layer.
Claim 11
Dependent Claim 17 words
An iron-air battery recharged by the method of claim 3, which is also capable of electrical recharging.

References Cited (Backward Citations)

US2638182A Cited
US3457488A Cited
US3479226A Cited
US3849198A Cited
US4132547A Cited
US4152489A Cited
US4356101A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-02 1988-04-02 1988-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-02 1992-04-02 1992-10-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-02 1996-04-02 1996-10-02 $7700.00 Window Closed / Lapsed

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